Methyltrioxorhenium as Catalyst for Olefin Metathesis
Authors:
- 1 December 1991
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 30 (12) , 1636-1638
Abstract
No cocatalysts are needed as additives when methyltrioxorhenium (MTO) supported on acidic carriers is employed to catalyze the metathesis of functionalized olefins. A typical system is MTO/Al2O3−SiO2, which is active, for instance, in the metathesis of ally1 halides, allylsilanes, unsaturated carboxylates, and nitriles. MTO in combination with RnAlCl3‐n is a homogeneous catalyst in ring‐opening polymerizations (RCH3, C2H5; n = 1,2).Keywords
This publication has 11 references indexed in Scilit:
- Multiple bonds between main-group elements and transition metals. 86. Methyltrioxorhenium(VII) and trioxo(.eta.5-pentamethylcyclopentadienyl)rhenium(VII): structures, spectroscopy and electrochemistryJournal of the American Chemical Society, 1991
- Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, XC. Selektive Bildung von Alkylrheniumoxiden aus Glykolat‐KomplexenEuropean Journal of Inorganic Chemistry, 1991
- Organoosmium Oxides: Efficient Syntheses and StructuresAngewandte Chemie International Edition, 1990
- Organoosmiumoxide — gezielte Synthesen und StrukturenAngewandte Chemie, 1990
- Raman spectroscopic studies of the effects of tin promotion on a rhenium/alumina dismutation catalystJournal of the Chemical Society, Faraday Transactions, 1990
- Mehrfachbindungen zwischen Hauptgruppenelementen und ÜbergangsmettalenJournal of Organometallic Chemistry, 1989
- High Oxidation State Organometallic Chemistry, A Challenge—the Example of RheniumAngewandte Chemie International Edition, 1988
- Organometallchemie in hohen Oxidationsstufen, eine Herausforderung – das Beispiel RheniumAngewandte Chemie, 1988
- Methylrhenium Oxides: Synthesis from R2O7 and Catalytic Activity in Olefin MetathesisAngewandte Chemie International Edition, 1988
- Methylrheniumoxide: Synthese aus Re2O7 und Katalyseaktivität in der Olefin‐MetatheseAngewandte Chemie, 1988