Reversible changes of epitaxial thin films from perovskite LaNiO3 to infinite-layer structure LaNiO2
- 23 February 2009
- journal article
- conference paper
- Published by AIP Publishing in Applied Physics Letters
- Vol. 94 (8) , 082102
Abstract
An infinite-layer-structure epitaxial thin film of was prepared by low-temperature reduction with from a epitaxial thin film grown on a substrate. The oxygen content changed reversibly from the perovskite to the infinite-layer without losing the structural framework and the topotactic relationship. Consequently, the oxidation state of Ni ions in the film changed from trivalent to divalent to monovalent.
Keywords
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