Iodine‐Catalysed Dissolution of Elemental Gold in Ethanol

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Abstract
Gold is a scarce element in the Earth's crust but indispensable in modern electronic devices. New, sustainable methods of gold recycling are essential to meet the growing eco‐social demand of gold. Here, we describe a simple, inexpensive, and environmentally benign dissolution of gold under mild conditions. Gold dissolves quantitatively in ethanol using 2‐mercaptobenzimidazole as a ligand in the presence of a catalytic amount of iodine. Mechanistically, the dissolution of gold begins when I2 oxidizes Au0 and forms a [AuII2]− species, which undergoes subsequent ligand‐exchange reactions and forms a stable bis‐ligand AuI complex. H2O2 oxidizes free iodide and regenerated I2 returns back to the catalytic cycle. Addition of a reductant to the reaction mixture precipitates gold quantitatively and partially regenerates the ligand. We anticipate our work will open a new pathway to more sustainable metal recycling with the utilization of just catalytic amounts of reagents and green solvents.
Funding Information
  • Helsingin Yliopisto
  • The Slovenian Research and Innovation Agency (P1-0230 and P1-0201)

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