Thiolates endow metal nanoclusters with stability while sometimes inhibit the catalytic activity due to the strong M−S interaction (M: metal atom). To improve the catalytic activity and keep the stability to some extent, one strategy is the partial phosphorization of thiolated metal nanoclusters. This is demonstrated by successful partial phosphorization of Au₂₃(SC₆H₁₁)₁₆ and by revealing that the products Au₂₂(SC₆H₁₁)₁₄(PPh₃)₂ and Au₂₂(SC₆H₁₁)₁₂(PPh₃)₄, with varied degree of phosphorization, both show excellent activity in the photocatalytic oxidation of thioanisole without notable reduction of stability. Furthermore, Au₂₂(SC₆H₁₁)₁₂(PPh₃)₄ exhibits better photoluminescence performance than the mother nanocluster Au₂₃(SC₆H₁₁)₁₆, indicating that partial phosphorization can also improve some other performance(s) except for the catalytic performance. The intermediates Au_22‐xCu_x(SC₆H₁₁)₁₂(PPh₃)₄ (x=1, 2) in the transformation from Au₂₃(SC₆H₁₁)₁₆ (Au₂₂(SC₆H₁₁)₁₄(PPh₃)₂) to Au₂₂(SC₆H₁₁)₁₂(PPh₃)₄ were captured and identified by mass spectrometry and single crystal X‐ray diffraction, which throws light on the understanding of the non‐alloyed anti‐galvanic reaction.

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