Fine particulate matter (PM) and sulfur trioxide (SO₃) from coal-fired flue gas pose significant environmental and health risks. While low-low temperature electrostatic precipitators (LLT-ESPs) enhance PM and SO₃ removal by cooling flue gas below the acid dew point, their efficiency is limited by incomplete agglomeration. This study proposes integrating turbulent agglomeration technology into LLT-ESP systems to improve collision and adhesion between droplets and particles. Experiments were conducted under three conditions: flue gas containing SO₃ alone, fly ash alone, and their mixture. Particle size distributions, mass concentrations, and removal efficiencies were analyzed using ELPI⁺ and PM samplers. Results showed that turbulent agglomeration reduced the number concentration of sulfuric acid droplets by 21.4% from 1.59 × 10⁷ cm⁻³ to 1.25 × 10⁷ cm⁻³ (SO₃-only case) and fine fly ash particles by 19.5% from 5.79 × 10⁶ cm⁻³ to 4.66 × 10⁶ cm⁻³ (fly-ash-only case). Although LLT-ESP combined with turbulent agglomeration has a certain removal effect in the case of individual pollutants, the overall effect is not unsatisfactory, especially for SO₃, whose mass-based removal efficiency was merely 16.2%. The value of the fly-ash-only case was 92.1%. Synergistic effects in the coexistence scenario (fly ash and SO₃) significantly enhanced agglomeration, increasing SO₃ and PM removal efficiencies to 82.9% and 97.6%, respectively, compared to 69.7% and 90.1% without turbulent agglomeration. The mechanism behind the efficiency improvement involved droplet–particle collisions, sulfate deposition, and improved particle charging. This work demonstrates that turbulent agglomeration optimizes multi-pollutant control in LLT-ESP systems, offering a feasible strategy for achieving ultra-low emissions in coal-fired power plants.

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