Caroline Fayt

Pollutants information can be retrieved from visible (VIS) and ultraviolet (UV) diffuse solar spectra exploiting Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) instruments. In May 2021, the Italian research institute CNR-ISAC acquired and deployed a MAX-DOAS system SkySpec-2D. It is located in the “Giorgio Fea” observatory in San Pietro Capofiume (SPC), in the middle of the Po Valley, where it has constantly acquired zenith and off-axis diffuse solar spectra since the 1st October 2021. This work presents the retrieved tropospheric NO₂ and aerosol extinction profiles (and their columns) derived from the MAX-DOAS measurements using the newly developed DEAP retrieval code. The code has been validated both using synthetic differential Slant Column Densities (dSCDs) from the Fiducial Reference Measurements for Ground-Based DOAS Air-Quality Observations (FRM4DOAS) project and real measured data. For this purpose, DEAP results are compared with the ones obtained with three state-of-the-art retrieval codes. In addition, an inter-comparison with satellite products from Sentinel-5P TROPOMI, for the tropospheric NO₂ Vertical Column Densities (VCDs), and MODIS-MAIAC for the tropospheric Aerosol Optical Depth (AOD), is performed. We find a bias of −0.6 × 10¹⁵ molec/cm² with a standard deviation of 1.8 × 10¹⁵ molec/cm² with respect to Sentinel-5P TROPOMI for NO₂ tropospheric VCDs and of 0.04 ± 0.08 for AOD with respect to MODIS-MAIAC data. The retrieved data show that the SPC measurement site is representative of the background pollution conditions of the Po Valley. For this reason, it is a good candidate for satellite validation and scientific studies over the Po Valley.

The UV–Visible Working Group of the Network for the Detection of Atmospheric Composition Changes (NDACC) focuses on the monitoring of air-quality-related stratospheric and tropospheric trace gases in support of trend analysis, satellite validation and model studies. Tropospheric measurements are based on MAX-DOAS-type instruments that progressively emerged in the years 2010 onward. In the interest of improving the overall consistency of the NDACC MAX-DOAS network and facilitating its further extension to the benefit of satellite validation, the ESA initiated, in late 2016, the FRM4DOAS project, which aimed to set up the first centralised data processing system for MAX-DOAS-type instruments. Developed by a consortium of European scientists with proven expertise in measurements, data extraction algorithms and software design specialities, the system has now reached pre-operational status and has demonstrated its ability to deliver a set of quality-controlled atmospheric composition data products with a latency of one day. The processing system has been designed using a highly modular approach, making it easy to integrate new tools or processing updates. It incorporates advanced algorithms selected by community consensus for the retrieval of total ozone, lower tropospheric and stratospheric NO₂ vertical profiles and formaldehyde profiles. The ozone and NO₂ products are currently generated from a total of 22 stations and delivered daily to the NDACC rapid delivery (RD) repository, with an additional mirroring to the ESA Validation Data Centre (EVDC). Although it is still operated in a pre-operational/demonstrational mode, FRM4DOAS was already used for several validation and science studies, and it was also deployed in support of field campaigns for the validation of the TROPOMI and GEMS satellite missions. It recently went through a CEOS-FRM self-assessment process aiming at assessing the level of maturity of the service in terms of instrumentation, operations, data sampling, metrology and verification. Based on this evaluation, it falls under class C, which is a good rating but also implies that further improvements are needed to reach full compliance with FRM standards, i.e., class A.

In this paper we present a new method for retrieving tropospheric NO₂ Vertical Column Density (VCD) from zenith-sky Differential Optical Absorption Spectroscopy (DOAS) measurements using mobile observations. This method was used during three days in the summer of 2011 in Romania, being to our knowledge the first mobile DOAS measurements peformed in this country. The measurements were carried out over large and different areas using a mobile DOAS system installed in a car. We present here a step-by-step retrieval of tropospheric VCD using complementary observations from ground and space which take into account the stratospheric contribution, which is a step forward compared to other similar studies. The detailed error budget indicates that the typical uncertainty on the retrieved NO₂tropospheric VCD is less than 25%. The resulting ground-based data set is compared to satellite measurements from the Ozone Monitoring Instrument (OMI) and the Global Ozone Monitoring Experiment-2 (GOME-2). For instance, on 18 July 2011, in an industrial area located at 47.03°N, 22.45°E, GOME-2 observes a tropospheric VCD value of (3.4 ± 1.9) × 10¹⁵ molec./cm², while average mobile measurements in the same area give a value of (3.4 ± 0.7) × 10¹⁵ molec./cm². On 22 August 2011, around Ploiesti city (44.99°N, 26.1°E), the tropospheric VCD observed by satellites is (3.3 ± 1.9) × 10¹⁵ molec./cm² (GOME-2) and (3.2 ± 3.2) × 10¹⁵ molec./cm² (OMI), while average mobile measurements give (3.8 ± 0.8) × 10¹⁵ molec./cm². Average ground measurements over “clean areas”, on 18 July 2011, give (2.5 ± 0.6) × 10¹⁵ molec./cm² while the satellite observes a value of (1.8 ± 1.3) × 10¹⁵ molec./cm².