Marjetka Conradi

Magnesium and its alloys have emerged as promising materials for biomedical applications due to their light weight, mechanical compatibility with bone, biodegradability, and excellent biocompatibility. However, their rapid degradation in physiological environments remains a critical challenge. To address this, a range of surface-modification techniques have been explored to tailor the surface properties while preserving the bulk characteristics of magnesium. This paper provides an overview of surface-engineering methods aimed at enhancing the corrosion resistance, mechanical performance and bioactivity of magnesium. Three key surface-modification approaches are presented: plasma treatment, laser texturing and sandblasting. Plasma treatment resulted in the formation of a stable, protective oxide layer with significantly improved corrosion resistance and hydrophilicity. Laser texturing generated hierarchical microstructures yielding superhydrophobic surfaces with an enhanced hardness, though slightly reduced corrosion resistance. Sandblasting led to an increased surface roughness and mechanical stiffness, but also introduced microstructural defects that are detrimental to the corrosion stability. Overall, the study demonstrates how tailored surface modifications can effectively balance the mechanical integrity and degradation behavior of magnesium, paving the way for its optimized use in biomedical applications.

Magnesium and its alloys, valued for their lightweight and durable characteristics, have garnered increasing attention for biomedical applications due to their exceptional biocompatibility and biodegradability. This work introduces a comparison of advanced and basic methods—laser texturing and sandblasting—on magnesium surfaces to enhance bioactivity for biomedical applications. Employing a comprehensive analysis spanning surface morphology, hardness, wettability, tribological performance, and corrosion behavior, this study elucidates the intricate relationship between varied surface treatments and magnesium’s performance. Findings reveal that both laser texturing and sandblasting induce grain refinement. Notably, sandblasting, particularly with a duration of 2 s, demonstrates superior wear resistance and reduced corrosion rates compared to untreated magnesium, thereby emerging as a promising approach for enhancing magnesium bioactivity in biomedical contexts. This investigation contributes to a deeper understanding of the nuanced interactions between diverse surface treatments and their implications for magnesium implants in chloride-rich environments, offering valuable insights for prospective biomedical applications.

Friction and wear requirements in the aerospace/space industry or in biomedical applications are governed by life-limiting challenges: the wide range of contact stresses and sliding speeds in movable parts and operating conditions such as extreme temperature changes, humidity and abrasive wear caused by electrostatically attracted dust. Surface modification by laser texturing has been introduced to adjust the surface characteristics of the base material to overcome its tribological limitations of use via different surface topographies, allowing for the ability of lubricant retention. Laser surface texturing is therefore effective in enhancing the tribological performance of materials via controllable surface topographies acting as traps for wear debris and lubricant reservoirs, leading to reduced abrasion. This paper reviews the tribological behaviour of a laser-textured Ti6Al4V alloy with different textures: lines, crosshatch and dimples. The fiction and wear characteristics for dry sliding are discussed and compared.

Laser texturing with a dimple pattern was applied to modify a Ti6Al4V alloy at the micro level, aiming to improve its friction and wear resistance in combination with oil lubrication to optimize the performance in demanding industrial environments. The tribological analysis was performed on four different dimple-textured surfaces with varying dimple size and dimple-to-dimple distance and under lubrication with three different oils, i.e., T9, VG46, and VG100, to reflect the oil viscosity’s influence on the friction/wear of the laser-textured Ti6Al4V alloy. The results show that the surfaces with the highest texture density showed the most significant COF reduction of around 10% in a low-viscosity oil (T9). However, in high-viscosity oils (VG46 and VG100), the influence of the laser texturing on the COF was less pronounced. A wear analysis revealed that the laser texturing intensified the abrasive wear, especially on surfaces with a higher texture density. For low-texturing-density surfaces, less wear was observed for low- and medium-viscosity oils (T9 and VG46). For medium-to-high-texturing densities, the high-viscosity oil (VG100) provided the best contact conditions and wear results. Overall, reduced wear, even below the non-texturing case, was observed for sample 50–200 in VG100 lubrication, indicating the combined effect of oil reservoirs and increased oil-film thickness within the dimples due to the high viscosity.

In the present work, the functionalisation of austenitic stainless steel, AISI 316L surfaces via nanosecond Nd:YAG laser texturing in order to modify the surface morphology with crosshatch and dimple patterns is presented. A tribological analysis under lubrication with sunflower and jojoba oil with and without the addition of a solid lubricant, MoS₂ nanotubes, was performed. In conjunction with friction/wear response laser-textured surface wettability, oil spreadability and oil retention capacity were also analysed. It was shown that the crosshatch pattern generally exhibited lower friction than the dimple pattern, with the addition of MoS₂ nanotubes not having any significant effect on the coefficient of friction under the investigated contact conditions. This was found in addition to the better oil spreadability and oil retention capacity results of the crosshatch-textured surface. Furthermore, texturing reduced the wear of the stainless-steel surfaces but led to an approximately one order of magnitude larger wear rate of the steel counter-body, primarily due to the presence of hard bulges around the textured patterns. Overall, the crosshatch pattern showed better oil retention capacity and lower friction in combination with different vegetable oils, thus making it a promising choice for improving tribological performance in various environmentally friendly applications.

We present functionalization of AISI 316L surfaces by nanosecond Nd:YAG laser texturing in order to modify the surface morphology with crosshatch and dimple patterns. We performed tribological analysis under lubrication with sunflower and jojoba oil with and without addition of solid lubricant, MoS2 nanotubes. In connection to friction/wear response we analysed laser-textured surface wettability, oil spreadability and oil retention capacity. We have shown, that the crosshatch pattern generally exhibited lower friction than the dimples pattern, with the addition of MoS2 nanotubes not having any significant effect on the coefficient of friction under the investigated contact conditions. This was additionally with better oil spreadability and oil retention capacity results of crosshatch textured surface. Furthermore, texturing reduced wear of the stainless steel surfaces but led to approximately one order of magnitude larger wear rate of the steel counter-body, primarily due to the presence of hard bulges around the textured patterns. Overall, the crosshatch pattern showed better oil retention capacity and lower friction in combination with different vegetable oils, thus making it a promising choice for improving tribological performance in various environmentally friendly applications.

In our study, plasma surface modification was employed to tailor the surface properties of magnesium in terms of surface chemistry, topography, and wettability. For two sets of samples, the plasma treatment involved two steps using two different gases (hydrogen and oxygen), while one set of samples was treated with one step only using oxygen. X-ray photoelectron spectroscopy (XPS) was applied to determine the surface composition, oxidation state of the elements, and the thickness of the surface oxide layer on the Mg samples after different plasma treatments. The surface morphology was characterised using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The wettability was analysed by measuring the static water-contact angles and the corrosion was evaluated using potentiodynamic measurements. The interaction of the live cells with the differently modified Mg surfaces was evaluated in terms of biocompatibility using MG-63 cells (human bone osteosarcoma cells). We have shown that a plasma surface treatment significantly decreased the carbon content and the formation of a 15–20-nm-thick MgO layer was observed. This improves the corrosion resistance, while the biocompatibility was retained, compared to the untreated Mg. A plasma surface treatment is therefore an important step in the development of novel surfaces with improved corrosion resistance for magnesium in biomedical applications.

The scope of the Special Issue entitled “Mechanical, Corrosion Resistance, and Antibacterial Properties of Metallic Materials” includes research regarding the latest developments in materials’ mechanical properties and characterization, pure/applied corrosion phenomena, and advanced understanding of bacterial adhesion and the induced antibacterial properties of metallic materials

A Nd-YAG laser was used for texturing the Ti6Al4V surface with dimples of diameter 50 and 100 µm and centre-to-centre distance 100, 200 and 400 µm, defining the surface texture density. The tribological evaluation was conducted to analyse and compare the behaviour of un-textured and laser-textured samples under water in comparison to oil (PAO6) lubrication without and with the addition of MoS₂ nanotubes into the lubricant. MoS₂ nanotubes had a positive effect on friction in both media for laser-textured Ti6Al4V. Evaluation of friction and wear in water and PAO6 showed a comparable tribological response in water to oil for specific laser-textured configurations, proving the novel concept of green tribology for laser texturing in combination with MoS₂ nanotubes/water lubrication.

The total cost and environmental consequences of corrosion problems have become a major challenge to engineers