Pradip Bhattacharyya

Highly porous biochar (BC) structures have been prepared from inexpensive biomasses like rice straw, bamboo, sugarcane waste, and corn cob via a slow pyrolysis technique in nitrogenous atmosphere. A surface engineering technique has been applied to enhance the surface-to-volume ratio of each biochar sample and finally compared its characteristics through standard surface and elemental characterization techniques, viz. CHN (carbon, hydrogen, and nitrogen), FTIR (Fourier transform infrared spectroscopy), BET (Brunauer–Emmett–Teller), and SEM (scanning electron microscopy). All the biochar samples were observed to be highly carbonized and aromatized. Exfoliated structures were found to contain more elemental carbon (34.14–77.32%) than its native form (30.92–74.46%). Aromatic hydrocarbon, aromatic C=C, aromatics, aliphatic C–O, aliphatic hydrocarbon, and H-bonded OH groups were found to predominate in the surface of biochar structures independent of their precursor composition and extent of exfoliation. SEM micrographic images clearly ensured about the unoriented sheets like the morphology of different biochar samples. Although no significant structural difference was found to exist depending on their precursor compositions, quantitative enhancement of porosity was found to be observed after exfoliation. Both native (240.65 m²/g) and exfoliated (712.89 m²/g) biochars derived from sugarcane wastes were observed to have a maximum surface area in comparison to the biochars derived from rice straw (native, 22.08 m²/g; exfoliated, 29.92 m²/g), bamboo (native, 42.08 m²/g; exfoliated, 248.38 m²/g), and corn cob (native, 136.62 m²/g; exfoliated, 221.71 m²/g). Exfoliated biochars were found to be consistently more potent in comparison to its native form as per our comparative characterizations performed so far.

The spatial distribution of theaflavin and thearubigin fractions and their impact on black tea quality were investigated using multivariate and geostatistics techniques. Black tea samples were collected from tea gardens of six geographical regions of Assam and West Bengal, India. Total theaflavin (TF) and its four fractions of upper Assam, south bank and North Bank teas were higher than the other regions. Simple theaflavin showed highest significant correlation with tasters’ quality. Low molecular weight thearubigins of south bank and North Bank were significantly higher than other regions. Total thearubigin (TR) and its fractions revealed significant positive correlation with tasters’ organoleptic valuations. Tea tasters’ parameters were significantly and positively correlated with each other. The semivariogram for quality parameters were best represented by gaussian models. The nugget/sill ratio indicated a strong/moderate spatial dependence of the studied parameters. Spatial variation of tea quality parameters may be used for quality assessment in the tea growing areas of India.

We studied the suitability of Panchgavya (five products of cow), new organic amendment, application on seed germination, plant growth, and soil health. After characterization, Panchgavya was mixed with water to form different concentration and was tested for seed germination, germination index, and root and shoot growth of different seedlings. Four percent solution of Panchgavya was applied to different plants to test its efficacy. Panchgavya and other two organic amendments were incorporated in soil to test the change of soil chemical and microbiological parameters. Panchgavya contained higher nutrients as compared to farm yard manure (FYM) and vermicompost. Its application on different seeds has positively influenced germination percentage, germination index, root and shoot length, and fresh and dry weight of the seedling. Water-soluble macronutrients including pH and metal were positively and negatively correlated with the growth parameters, respectively. Four percent solution of Panchgavya application on some plants showed superiority in terms of plant height and chlorophyll content. Panchgavya-applied soil had higher values of macro and micronutrients (zinc, copper, and manganese), microbial activity as compared to FYM, and vermicompost applied soils. Application of Panchgavya can be gainfully used as an alternative organic supplement in agriculture.

Maintenance of tropical soil quality for crop production without damaging the environment is a challenge and thus the development of an efficient nutrient-management technique is important. Soil amendment by organic manures has been widely accepted as an efficient nutrient-management technique in tropical agriculture. In this study, a long-term laboratory experiment was conducted to investigate the influence of organic manures of different sources (e.g. cattle manure, poultry manure, vermicompost and oil cakes) on changes in pH, electrical conductivity, organic C and nutrient content (mineral N, available phosphorous and potassium) in tropical alluvial soil. Applications of organic amendments in this study indicated considerable changes in the basic soil physico-chemical properties and different nutrient levels. Soil pH declined slightly, whereas organic C and all the other nutrients increased distinctly, due to the application of organic manures. Thus, the magnitude of changes in the soil properties was dependent on the nature of the organic manure.

The risks of heavy metal accumulation and the dynamics related to roadside pond sediment application in comparison to control of winter wheat (Triticum aestivum L.) were investigated in field experiments. Selective sequential extraction procedures revealed that application of pond sediment in soil increases the labile pools of the studied heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn). Risk assessment codes concluded that Cu and Pb were in the high-risk zone in both pond sediment and soil amended with pond sediment, whereas Zn and Cu were found in the medium-risk zone for control soil. Heavy metal accumulation by wheat straw and grain (39.38, 1.18, 23.73, 0.36, 0.18, and 16.8 mg kg^-1 for Zn, Cd, Cu, Cr, Ni, and Pb, respectively, for wheat grain) was significantly increased through application of pond sediment. However, metal accumulation did not thwart the enhancement of wheat yield when pond sediment was applied. Health risk indexes of analyzed heavy metals were found to be within the Indian permissible limit for foodstuffs. Pond sediments help to fortify wheat grain by increasing the concentration of Zn and Cu as a source of micronutrients in the diet. However, a significant increase of Pb in wheat grain through pond sediment could be a health concern for its long-term application. Therefore, pond sediment would be a valuable resource for agriculture as an alternative organic supplement, but long-term use may require the cessation of the excavated sediment as agricultural landfill in order to restrict heavy metal contamination through it.

Soils developed on various physiography at the foothills of Chhotanagpur Plateau were studied to characterize, classify and evaluate their suitability for existing crops. The soils in general were moderately deep (78 cm) to deep (120 cm), well drained to poorly drained, greyish in colour (hue 7.5 YR to 2.5Y) with redoximorphic features, loam to clay loam in surface texture, slightly acidic to neutral (pH 5.3 – 6.7) in reaction with low content of organic carbon. These soils are classified as Udic Haplustalfs, Udic Paleustalfs and Typic Endoaqualfs. The major limitations of these soils were slight to moderate erosion and low soil fertility in terms of organic carbon. Soil-site suitability evaluation revealed that in general, existing crops, such as rice (Oryza sativa), wheat (Triticum aestivum L.), pea (Pisum sativum L.), mustard (Brassica juncea L.), sesame (Sesamum indicum L.) and groundnut (Arachis hypogea L.) were only moderately to marginally suitable. Maize (Zea mays L.), Bengal gram (Cicer arietinum L.) and lentil (Lens culinaris) were suggested as alternate crops where as plantation of fruit trees (Mangifera indica, Psidium guijava and Artocarpus heterophyllus) and introduction of aromatic grasses (Cymbopogon wintcriamus, Pandanus odoratissimus L. and Cymbopigon flexuosus Stapt) were suggested in fallow lands.

The field study was conducted to evaluate the effect of municipal solid waste compost (MSWC) as a soil amendment on L-asparaginase (LA) and L-glutaminase (LG) activities. Experiments were conducted during the wet seasons of 1997, 1998 and 1999 on rice grown under a submerged condition, at the Agriculture Experimental Farm, Calcutta University at Baruipur, West Bengal, India. The treatments consisted of control, no input; MSWC, at 60 Kg N ha^{− 1}; well-decomposed cow manure (DCM), at 60 Kg N ha^{− 1}; MSWC (30 Kg N ha^{− 1}) + Urea (U) (30 Kg N ha^{− 1}); DCM (30 Kg N ha^{− 1}) + U (30 Kg N ha^{− 1}) and Fertilizer, (at 60:30:30 NPK kg ha^{− 1}) through urea, single superphosphate and muriate of potash respectively). LA and LG activities alone and their ratio with organic-C (ratio index value, RIV), straw and grain yield were higher in DCM than MSWC-treated soils, due to higher amount of biogenic organic materials like water-soluble organic carbon, carbohydrate and mineralizable nitrogen in the former. The studied parameters were higher when urea was integrated with DCM or MSWC, compared to their single applications. The heavy metals in MSWC did not detrimentally influence the above-measured activities of soil. In the event of long term MSWC application, changes in soil quality parameters should be monitored regularly, since heavy metals once entering into soil persist over a long period.