John H. Prueger

A network of eddy covariance (EC) and micrometeorological flux (METFLUX) stations over corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] canopies was established as part of the Soil Moisture–Atmosphere Coupling Experiment (SMACEX) in central Iowa during the summer of 2002 to measure fluxes of heat, water vapor, and carbon dioxide (CO2) during the growing season. Additionally, EC measurements of water vapor and CO2 fluxes from an aircraft platform complemented the tower-based measurements. Sensible heat, water vapor, and CO2 fluxes showed the greatest spatial and temporal variability during the early crop growth stage. Differences in all of the energy balance components were detectable between corn and soybean as well as within similar crops throughout the study period. Tower network–averaged fluxes of sensible heat, water vapor, and CO2 were observed to be in good agreement with area-averaged aircraft flux measurements.

Pesticide volatilization is a significant loss pathway that may have unintended consequences in nontarget environments. Field-scale pesticide volatilization involves the interaction of a number of complex variables. There is a need to acquire pesticide volatilization fluxes from a location where several of these variables can be held constant. Accordingly, soil properties, tillage practices, surface residue management, and pesticide formulations were held constant while fundamental information regarding metolachlor volatilization (a pre-emergent pesticide) was monitored over a five-year period as influenced by meteorological variables and soil water content. Metolachlor vapor concentrations were measured continuously for 120 h after each application using polyurethane foam plugs in a logarithmic profile above the soil surface. A flux gradient technique was used to compute volatilization fluxes from metolachlor concentration profiles and turbulent fluxes of heat and water vapor (as determined from eddy covariance measurements). Differences in meteorologi cal conditions and surface soil water contents resulted in variability of the volatilization losses over the years studied. The peak volatilization losses for each year occurred during the first 24 h after application with a maximum flux rate in 2001 (1500 ng m^-2 s^-1) associated with wet surface soil conditions combined with warm temperatures. The cumulative volatilization losses for the 120-hour period following metolachlor application varied over the years from 5 to 25% of the applied active ingredient, with approximately 87% of the losses occurring during the first 72 h. In all of the years studied, volatilization occurred diurnally and accounted for between 43 and 86% during the day and 14 and 57% during the night of the total measured loss. The results suggest that metolachlor volatilization is influenced by multiple factors involving meteorological, surface soil, and chemical factors.

Nitrogen (N) loss from agricultural systems raises concerns about the potential impact of farming practices on environmental quality. N is a critical input to agricultural production. However, there is little understanding of the interactions among crop water use, N application rates, and soil types. This study was designed to quantify these interactions in corn (Zea mays L.) grown in production-size fields in central Iowa on the Clarion-Nicollet-Webster soil association. Seasonal water use varied by soil type and N application rate. Yield varied with N application rate, with the highest average yield obtained at 100 kg ha^-1. N use efficiency (NUE) decreased with increasing N application rates, having values around 50%. Water use efficiency (WUE) decreased as N fertilizer rates increased. Analysis of plant growth patterns showed that in the low organic matter soils (lower water-holding capacities), potential yield was not achieved because of water deficits during the grain-filling period. Using precipitation data coupled with daily water use throughout the season, lower organic matter soils showed these soils began to drain earlier in the spring and continued to drain more water throughout the season. The low NUE in these soils together with increased drainage lead to greater N loss from these soils. Improved management decisions have shown that it is possible to couple water use patterns with N application to increase both WUE and NUE.

Volatilization of pesticides has been considered to be a large part of the loss from fields after application; however, there have been relatively few studies conducted to quantify the amount lost to the atmosphere. This study was designed to evaluate volatilization rates of a preemergent herbicide Dual [a.i. metolachlor 2.24 kg ha⁻¹ (2‐chloro‐N‐(2‐ethyl‐6‐methylphenyl)‐N‐(2‐methoxy‐1‐methylethyl)‐acetamide)] from two fields (175 and 45 ha) in central Iowa under contrasting tillage operations and pesticide application scenarios. Metolachlor vapor was trapped using polyurethane foam plugs at six heights on a profile mast. Average concentrations were measured at each height every 2 h for the first 4 d after application, then every 4 h thereafter. Volatilization rates were calculated with a flux‐gradient technique using data from Bowen ratio and eddy correlation measurements. Flux profile concentrations of metolachlor were large during the first 24 h and quickly declined for the duration of the study. There was approximately a threefold greater cumulative volatilization loss of applied metolachlor from the broadcast (22%) treatment than from the banded treatment (6%) for the 10‐d study period. Metolachlor volatilization was affected by residue cover, spatial concentration on the surface, and timing of precipitation.