Roland Gredel

Astronomy & Astrophysics (A&A) is an international journal which publishes papers on all aspects of astronomy and astrophysics

(Abridged) We carried out a comprehensive far-ultraviolet (UV) survey of ^12CO and H_2 column densities along diffuse molecular Galactic sight lines in order to explore in detail the relationship between CO and H_2. We measured new CO abundances from HST spectra, new H_2 abundances from FUSE data, and new CH, CH^+, and CN abundances from the McDonald and European Southern Observatories. A plot of log N(CO) versus log N(H_2) shows that two power-law relationships are needed for a good fit of the entire sample, with a break located at log N(CO, cm^-2) = 14.1 and log N(H_2) = 20.4, corresponding to a change in production route for CO in higher-density gas. Similar logarithmic plots among all five diatomic molecules allow us to probe their relationships, revealing additional examples of dual slopes in the cases of CO versus CH (break at log N = 14.1, 13.0), CH^+ versus H_2 (13.1, 20.3), and CH^+ versus CO (13.2, 14.1). These breaks are all in excellent agreement with each other, confirming the break in the CO versus H_2 relationship, as well as the one-to-one correspondence between CH and H_2 abundances. Our new sight lines were selected according to detectable amounts of CO in their spectra and they provide information on both lower-density (< 100 cm^-3) and higher-density diffuse clouds. The CO versus H_2 correlation and its intrinsic width are shown to be empirically related to the changing total gas density among the sight lines of the sample. We employ both analytical and numerical chemical schemes in order to derive details of the molecular environments. In the low-density gas, where equilibrium-chemistry studies have failed to reproduce the abundance of CH^+, our numerical analysis shows that nonequilibrium chemistry must be employed for correctly predicting the abundances of both CH^+ and CO.Comment: 40 pages in emulateapj style, to appear in the Astrophysical Journa

(Abridged) We carried out a comprehensive far-ultraviolet (UV) survey of ^12CO and H_2 column densities along diffuse molecular Galactic sight lines in order to explore in detail the relationship between CO and H_2. We measured new CO abundances from HST spectra, new H_2 abundances from FUSE data, and new CH, CH^+, and CN abundances from the McDonald and European Southern Observatories. A plot of log N(CO) versus log N(H_2) shows that two power-law relationships are needed for a good fit of the entire sample, with a break located at log N(CO, cm^-2) = 14.1 and log N(H_2) = 20.4, corresponding to a change in production route for CO in higher-density gas. Similar logarithmic plots among all five diatomic molecules allow us to probe their relationships, revealing additional examples of dual slopes in the cases of CO versus CH (break at log N = 14.1, 13.0), CH^+ versus H_2 (13.1, 20.3), and CH^+ versus CO (13.2, 14.1). These breaks are all in excellent agreement with each other, confirming the break in the CO versus H_2 relationship, as well as the one-to-one correspondence between CH and H_2 abundances. Our new sight lines were selected according to detectable amounts of CO in their spectra and they provide information on both lower-density (< 100 cm^-3) and higher-density diffuse clouds. The CO versus H_2 correlation and its intrinsic width are shown to be empirically related to the changing total gas density among the sight lines of the sample. We employ both analytical and numerical chemical schemes in order to derive details of the molecular environments. In the low-density gas, where equilibrium-chemistry studies have failed to reproduce the abundance of CH^+, our numerical analysis shows that nonequilibrium chemistry must be employed for correctly predicting the abundances of both CH^+ and CO.

Astronomy & Astrophysics (A&A) is an international journal which publishes papers on all aspects of astronomy and astrophysics

We examine 20 diffuse and translucent Galactic sight lines and extract the column densities of the ^12CO and ^13CO isotopologues from their ultraviolet A--X absorption bands detected in archival Space Telescope Imaging Spectrograph data with lambda/Deltalambda geq 46,000. Five more targets with Goddard High-Resolution Spectrograph data are added to the sample that more than doubles the number of sight lines with published Hubble Space Telescope observations of ^13CO. Most sight lines have 12-to-13 isotopic ratios that are not significantly different from the local value of 70 for ^12C/^13C, which is based on mm-wave observations of rotational lines in emission from CO and H_2CO inside dense molecular clouds, as well as on results from optical measurements of CH^+. Five of the 25 sight lines are found to be fractionated toward lower 12-to-13 values, while three sight lines in the sample are fractionated toward higher ratios, signaling the predominance of either isotopic charge exchange or selective photodissociation, respectively. There are no obvious trends of the ^12CO-to-^13CO ratio with physical conditions such as gas temperature or density, yet ^12CO/^13CO does vary in a complicated manner with the column density of either CO isotopologue, owing to varying levels of competition between isotopic charge exchange and selective photodissociation in the fractionation of CO. Finally, rotational temperatures of H_2 show that all sight lines with detected amounts of ^13CO pass through gas that is on average colder by 20 K than the gas without ^13CO. This colder gas is also sampled by CN and C_2 molecules, the latter indicating gas kinetic temperatures of only 28 K, enough to facilitate an efficient charge exchange reaction that lowers the value of ^12CO/^13CO.Comment: 1-column emulateapj, 23 pages, 9 figure

Integral-field spectroscopy of molecular hydrogen in the optical wavelength region and complementary long-slit near-infrared spectroscopy are presented towards HH91A.The detection of some 200 H_2 lines arising from ro-vibrational levels up to v'=8 ranging between 7700A and 2.3 microns is reported. The emission arises from thermally excited gas where the bulk of the material is at 2750 K and where 1% is at 6000 K. The total column density of shocked gas is N(H_2) = 10^{18} cm^{-2}. Non-thermal excitation scenarios such as UV-fluorescence do not contribute to the excitation of H_2 towards HH91A. The emission is explained in terms of a slow non-dissociative J-shock which propagates into a low-density medium which has been swept-up by previous episodes of outflows which have occurred in the evolved HH90/91 complex.

We examine 20 diffuse and translucent Galactic sight lines and extract the column densities of the ^12CO and ^13CO isotopologues from their ultraviolet A--X absorption bands detected in archival Space Telescope Imaging Spectrograph data with lambda/Deltalambda geq 46,000. Five more targets with Goddard High-Resolution Spectrograph data are added to the sample that more than doubles the number of sight lines with published Hubble Space Telescope observations of ^13CO. Most sight lines have 12-to-13 isotopic ratios that are not significantly different from the local value of 70 for ^12C/^13C, which is based on mm-wave observations of rotational lines in emission from CO and H_2CO inside dense molecular clouds, as well as on results from optical measurements of CH^+. Five of the 25 sight lines are found to be fractionated toward lower 12-to-13 values, while three sight lines in the sample are fractionated toward higher ratios, signaling the predominance of either isotopic charge exchange or selective photodissociation, respectively. There are no obvious trends of the ^12CO-to-^13CO ratio with physical conditions such as gas temperature or density, yet ^12CO/^13CO does vary in a complicated manner with the column density of either CO isotopologue, owing to varying levels of competition between isotopic charge exchange and selective photodissociation in the fractionation of CO. Finally, rotational temperatures of H_2 show that all sight lines with detected amounts of ^13CO pass through gas that is on average colder by 20 K than the gas without ^13CO. This colder gas is also sampled by CN and C_2 molecules, the latter indicating gas kinetic temperatures of only 28 K, enough to facilitate an efficient charge exchange reaction that lowers the value of ^12CO/^13CO.

Astronomy & Astrophysics (A&A) is an international journal which publishes papers on all aspects of astronomy and astrophysics

We discuss the abundances of interstellar CH, CH+, and CN in the Magellanic Clouds, derived from spectra of seven SMC and 13 LMC stars obtained (mostly) with the VLT UVES. CH and/or CH+ have now been detected toward three SMC and nine LMC stars; CN is detected toward Sk 143 (SMC) and Sk -67 2 (LMC). These data represent nearly all the optical detections of these molecular species in interstellar media beyond the Milky Way. In the LMC, the CH/H2 ratio is comparable to that found for diffuse Galactic molecular clouds in four sight lines but is lower by factors of 2.5-4.0 in two others. In the SMC, the CH/H2 ratio is comparable to the local Galactic value in one sight line but is lower by factors of 10-15 in two others. The abundance of CH in the Magellanic Clouds thus appears to depend on local physical conditions and not just on metallicity. In both the SMC and the LMC, the observed relationships between the column density of CH and those of CN, CH+, Na I, and K I are generally consistent with the trends observed in our Galaxy. Using existing data for the rotational populations of H2 in these sight lines, we estimate temperatures, radiation field strengths, and local hydrogen densities for the diffuse molecular gas. The inferred temperatures range from about 45 to 90 K, the radiation fields range from about 1 to 900 times the typical local Galactic field, and the densities (in most cases) lie between 100 and 600 cm-3. Densities estimated from the observed N(CH), under the assumption that CH is produced via steady state gas-phase reactions, are considerably higher than those derived from H2. Much better agreement is found by assuming that the CH is made via the (still undetermined) process(es) responsible for the observed CH+. A significant fraction of the CH and CH+ in diffuse molecular material in the SMC and LMC may be produced in photon-dominated regions. The excitation temperature obtained from the populations of the two lowest CN rotational levels toward Sk -67 2 is quite consistent with the temperature of the cosmic microwave background radiation measured with COBE. Toward most of our targets, the UVES spectra also reveal absorption at velocities corresponding to the Magellanic Clouds ISM from several of the strongest of the diffuse interstellar bands (DIBs; at 5780, 5797, and 6284 Å). On average, the three DIBs are weaker by factors of 7-9 (LMC) and about 20 (SMC), compared to those typically observed in Galactic sight lines with similar N(H I), presumably due to the lower metallicities and stronger radiation fields in the LMC and SMC. The three DIBs are also weaker (on average, but with some exceptions), by factors of order 2-6, relative to E(B-V), N(Na I), and N(K I) in the Magellanic Clouds. The detection of several of the so-called C2 DIBs toward Sk 143 and Sk -67 2 with strengths similar to those in comparable Galactic sight lines, however, indicates that no single, uniform scaling factor (e.g., one related to metallicity) applies to all DIBs (or for all sight lines) in the Magellanic Clouds.