F. J. Himpsel

This work explores the possibility of obtaining a mass gap in Yang-Mills theories via the intrinsic gauge bosons, without invoking a separate Higgs boson or fermion-antifermion pairs. Instead, pairs of gauge bosons in the spin and isospin singlet state form a pair of composite Higgs bosons which can be viewed as the simplest possible glueball of Yang-Mills gauge theories. Quadratic and quartic gauge boson self-interactions form a potential that leads to a finite expectation value of the gauge boson amplitude. Transverse polarization ensures Lorentz invariance of the vacuum after averaging over all possible polarization vectors. But the scalar pair products exhibit a finite vacuum expectation value which breaks the gauge symmetry dynamically. Compatibility with the standard Higgs potential determines the quadratic and quartic coupling constants.

This work is motivated by the long-standing question about the internal stability of the electron. While one cannot investigate internal properties of a point-like particle, it is fair to analyze the response of the Dirac sea to an electron. For this purpose the concept of an exchange hole is generalized from the Fermi sea of condensed matter physics to the Dirac sea of quantum electrodynamics. In order to conserve charge and angular momentum, an exchange electron is added to the exchange hole, forming a neutral exchange exciton. Consequently, the pair correlation defining the exchange hole is generalized to a three-fermion correlation. An approximation by sequential pair correlations provides analytic results for charge densities, average distances, and force densities of the exchange hole and electron. The analysis is supported by analogies to the negative ion of positronium.

This study addresses the effect of the magnetic hyperfine interaction on the relativistic H1s wave functions. These are used to calculate the electric, magnetic, and confinement force densities acting on the 1s electron. The magnetic field couples Dirac equations for different angular momenta. These are solved numerically for the hyperfine singlet and triplet, as well as for a classical magnetic dipole. In the singlet ground state the hyperfine interaction shifts the electron density toward the proton. A similar shift is found for the classical dipole, and an opposite shift for the triplet. The cross-over between charge accumulation and depletion occurs at 1.325 times the Bohr radius. The behavior of the wave functions is investigated down to distances smaller than the proton radius, including the incorporation of virtual positrons. The force densities are determined and balanced against each other.

The atomic‐scale origin of the unusually high performance and long‐term stability of wurtzite p‐GaN oriented nanowire arrays is revealed. Nitrogen termination of both the polar top face and the nonpolar side faces of the nanowires is essential for long‐term stability and high efficiency. Such a distinct atomic configuration ensures not only stability against (photo) oxidation in air and in water/electrolyte but, as importantly, also provides the necessary overall reverse crystal polarization needed for efficient hole extraction in p‐GaN.

Motivated by the long-debated question about the internal stability of the electron, the force densities acting on the charge density of the 1s electron in the H atom are investigated. The problem is mapped onto the canonical formalism for a classical Dirac field coupled to the electric field of an external point charge. An explicit calculation shows that the attractive Coulomb force density is balanced exactly at every point in space by the repulsive confinement force density. The latter requires evaluating the divergence of the stress tensor for the 1s solution of the Dirac equation. Such a local force balance goes beyond the global stability criteria that are usually given for the H atom. This concept is extended to the internal stability of any charged particle by investigating the force densities acting on its surrounding vacuum polarization. At large distances one has to consider only the charge density of virtual electrons and positrons, induced by a point charge in the vacuum of quantum electrodynamics.

The internal stability of the electron has been debated for a century at both the classical and the quantum level. Recently, a local force density balance was established for the 1s electron in the H atom, based on the energy-momentum tensor of the classical Dirac field. This methodology is now extended to quantum fields by considering the force densities acting on the vacuum polarization induced by a point charge. Such a model is applicable to any charged particle at large distances, since the only vestige of its internal structure is the electric Coulomb field together with the vacuum polarization induced by it. While the polarization charge density is attracted to the point charge, it is kept from collapsing by repulsive forces due to confinement and degeneracy. It is shown analytically that the corresponding force densities are balanced for every filled shell of mj states at a given angular momentum j. The force densities are then summed over all single-electron states in the Dirac sea and renormalized by subtracting singular terms. In leading order of alpha, the force densities remain balanced. This result establishes a local force balance for a prototypical manybody system.

It is proposed to replace the Higgs boson of the standard model by a Lorentz- and gauge-invariant combination of SU(2) gauge bosons. A pair of Higgs bosons is identified with pairs of gauge bosons by setting their mass Lagrangians equal to each other. That immediately determines the mass of the composite Higgs boson. It becomes simply half of the vacuum expectation value of the standard Higgs boson, which matches the observed mass with tree-level accuracy (2%). The two parameters of the standard Higgs potential are replaced by five one-loop self-interactions of the SU(2) gauge bosons, derived from the fundamental gauge couplings. The Brout-Englert-Higgs mechanism of spontaneous symmetry breaking is generalized from scalars to vectors. Their transverse components acquire finite vacuum expectation values which generate masses for both gauge bosons and the Higgs boson. This concept leads beyond the standard model by enabling calculations of the Higgs mass and its potential without adjustable parameters. It can be applied to non-abelian gauge theories in general, such as grand unified models and supersymmetry.

Recently, single-walled carbon nanotubes as well as graphene functionalized with azobenzene chromophores have drawn attention for applications in optoelectronics due to their ability to undergo cis–trans isomerization when exposed to light. The electronic properties of the nanocarbon materials at these unconventional interfaces can be tailored by gaining structural insight into the organic monolayers at the molecular level. In this work, we use polarization-dependent X-ray absorption spectroscopy to probe the orientation of three chromophores on graphene, all identical except for their terminal groups. All three terminal groups (methyl, nitro, and nitrile) are well-oriented, with a tilt angle of about 30° from the substrate for the shared azobenzene group. Density functional theory calculations are in good agreement with experimental results and give two similar, stable configurations for the orientation of these molecules on graphene.