Alexander
Research Subjects
Research Interests
Alexander has a total of 2 co-authors. Here are the top co-authors by number of shared publications:
- Reginald E. Mitchell
Mechanical Engineering Department, Stanford University, 94305 Stanford, California, United States
1 shared publication - Turgut M. Gür
Stanford University
1 shared publication
Latest Publications
- Open Access
- 1 January 2011
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 158 (5) , B505-B513
Steam-Carbon Fuel Cell Concept for Cogeneration of Hydrogen and Electrical Power
This study describes and presents the results of a new electrochemical approach to co-production of hydrogen and electric power using a steam-carbon fuel cell, within which carbon-containing species are kept physically separate from the hydrogen stream by a solid oxide electrolyte membrane. The fuel cell used for this purpose consists of H2, H2O(g)/Pt/YSZ/Pt/C(s),CO,CO2 and measurements are taken between 600 and 900°C. Peak electrical power generated at 900°C is 8 mW/cm2 at a current density of 40.5 mA/cm2 corresponding to simultaneous production of carbon-free hydrogen at a rate of 354 g H2/m2 day. Electrochemical behavior and cell loss mechanisms are studied using impedance spectroscopy in different cell arrangements operating in steam-carbon and air-carbon modes. Exchange current densities extracted from these measurements indicated activation energies of 80.3 ± 7.9 kJ/mol for oxygen reduction, 132 ± 12 kJ/mol for CO oxidation, and 189 ± 35 kJ/mol for steam reduction. These results indicate that steam reduction is the dominant loss mechanism with significant contribution from CO oxidation kinetics. Modeling results for the carbon bed indicate that a bed height of 7 mm is capable of supporting cell current densities of 700 mA/cm2 at 85% effective char utilization, allowing for high performing steam-carbon fuel cells for the simultaneous production of hydrogen and electrical work.
- 1 January 2011
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 158 (5) , B505-B513
Open AccessSteam-Carbon Fuel Cell Concept for Cogeneration of Hydrogen and Electrical Power
This study describes and presents the results of a new electrochemical approach to co-production of hydrogen and electric power using a steam-carbon fuel cell, within which carbon-containing species are kept physically separate from the hydrogen stream by a solid oxide electrolyte membrane. The fuel cell used for this purpose consists of H2, H2O(g)/Pt/YSZ/Pt/C(s),CO,CO2 and measurements are taken between 600 and 900°C. Peak electrical power generated at 900°C is 8 mW/cm2 at a current density of 40.5 mA/cm2 corresponding to simultaneous production of carbon-free hydrogen at a rate of 354 g H2/m2 day. Electrochemical behavior and cell loss mechanisms are studied using impedance spectroscopy in different cell arrangements operating in steam-carbon and air-carbon modes. Exchange current densities extracted from these measurements indicated activation energies of 80.3 ± 7.9 kJ/mol for oxygen reduction, 132 ± 12 kJ/mol for CO oxidation, and 189 ± 35 kJ/mol for steam reduction. These results indicate that steam reduction is the dominant loss mechanism with significant contribution from CO oxidation kinetics. Modeling results for the carbon bed indicate that a bed height of 7 mm is capable of supporting cell current densities of 700 mA/cm2 at 85% effective char utilization, allowing for high performing steam-carbon fuel cells for the simultaneous production of hydrogen and electrical work.