Xun Shi

Xun Shi

*This is an algorithmically generated author record based on publicly available information.

Current Organizations / Institutes

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Xun Shi has a total of 13 co-authors. Here are the top co-authors by number of shared publications:


Latest Publications

  • Low thermal conductivity and high thermoelectric figure of merit in n-type BaxYbyCo4Sb12 double-filled skutterudites

    by X. Shi, H. Kong, C.-P. Li, C. Uher, J. Yang, J. R. Salvador, H. Wang, L. Chen, W. Zhang

    Filled skutterudites are one of the most promising thermoelectric materials for power generation applications. The choice and concentration of filler atoms are key aspects for achieving high thermoelectric figure of merit values. We report on the high temperature thermoelectric properties in the double-filled skutterudites BaxYbyCo4Sb12 . The combination of Ba and Yb fillers inside the voids of the skutterudite structure provides a broad range of resonant phonon scattering and consequently a strong suppression in the lattice thermal conductivity is observed. A dimensionless thermoelectric figure of merit of 1.36 at 800K is achievable for n -type BaxYbyCo4Sb12 .


  • Solid solubility of Ir and Rh at the Co sites of skutterudites

    by X. Shi, Z. Zhou, W. Zhang, L. D. Chen, J. Yang, C. Uher

    Phase diagrams for skutterudite solid solutions made by alloying at the Co site of CoSb3 skutterudite structure are studied by density functional theory. A limited solid solubility is observed for IrxCo1−xSb3 and RhxCo1−xSb3 , showing good agreement with experimental reports. A correlation between solubility and material preparation procedure is discussed. A simple method to synthesize skutterudite nanocomposites is proposed. Our calculations also demonstrate that IrxRh1−xSb3 is a compound with ordered structure rather than a random solid solution.


  • Enhanced Thermoelectric Figure of Merit in BaxYbyCo4Sb12 Skutterudites

    by Ctirad Uher, Xun Shi, Huijun Kong

    We report on the development of an efficient n-type skutterudite based on the double-filled structure of CoSb3. The chosen filler species Ba and Yb have a large phonon contrast and this combination is very effective in lowering the lattice thermal conductivity. The highest figure of merit in excess of 1.3 is obtained near 800K and the figure of merit greater than unity persists down to temperatures of about 550K. The compounds are synthesized with high purity Co (99.998%) and Sb (99.9999%). In order to reduce the cost of the materials, we have also prepared filled skutterudites of similar composition but using less pure Co (99.8%) and Sb (99.999%). The figure of merit of these lower purity compounds reaches ZT = 1 at 800K with the materials' cost dramatically reduced.