Juan Pablo Paz

We present the exact theory of quantum engines whose working medium is a network of driven oscillators performing an arbitrary cyclic process while coupled to thermal and nonthermal reservoirs. We show that when coupled to a single reservoir work cannot be extracted unless there is population inversion, and prove that the ratio between the heat flowing out and into the working medium cannot be arbitrarily small, satisfying a form of Clausius inequality. We use such identity to prove that the efficiency of linear quantum engines satisfies a generalized bound, which coincides with the Carnot limit for thermal reservoirs. The previous results enable us to estimate the cost of preparing nonthermal reservoirs, which, if available, could be used to violate the Carnot limit.

We study intraenvironmental classical and quantum correlations in a thermal machine, which is modeled as a driven quantum system coupled with thermal reservoirs. We compute the mutual information, the quantum discord, and the entanglement between two parts of the environment formed by oscillators centered around two different frequencies. We show that there are only two processes that generate time-extensive correlations in the long-time limit. First, there is a resonant process which is responsible for the transport of excitations between different environmental modes due to the absorption (or emission) of energy from (or into) the driving field. Second, there is a nonresonant process that transforms the energy from the external driving into pairs of excitations in two environmental modes. We show that there is a regime when the mutual information and the quantum discord between the parts of the environment correlated by these two processes grow quadratically in time, while entanglement production is time extensive.

We study intraenvironmental classical and quantum correlations in a thermal machine, which is modeled as a driven quantum system coupled with thermal reservoirs. We compute the mutual information, the quantum discord, and the entanglement between two parts of the environment formed by oscillators centered around two different frequencies. We show that there are only two processes that generate time-extensive correlations in the long-time limit. First, there is a resonant process which is responsible for the transport of excitations between different environmental modes due to the absorption (or emission) of energy from (or into) the driving field. Second, there is a nonresonant process that transforms the energy from the external driving into pairs of excitations in two environmental modes. We show that there is a regime when the mutual information and the quantum discord between the parts of the environment correlated by these two processes grow quadratically in time, while entanglement production is time-extensive.

Work is an essential concept in classical thermodynamics, and in the quantum regime, where the notion of a trajectory is not available, its definition is not trivial. For driven (but otherwise isolated) quantum systems, work can be defined as a random variable, associated with the change in the internal energy. The probability for the different values of work captures essential information describing the behaviour of the system, both in and out of thermal equilibrium. In fact, the work probability distribution is at the core of “fluctuation theorems” in quantum thermodynamics. Here we present the design and implementation of a quantum work meter operating on an ensemble of cold atoms, which are controlled by an atom chip. Our device not only directly measures work but also directly samples its probability distribution. We demonstrate the operation of this new tool and use it to verify the validity of the quantum Jarzynksi identity.

We study the decoherence process for an open quantum system that is classically chaotic (a quartic double well with harmonic driving coupled to a sea of harmonic oscillators). We carefully analyze the time dependence of the rate of entropy production showing that it has two relevant regimes: For short times it is proportional to the diffusion coefficient (fixed by the system-environment coupling strength); for longer times (but before equilibration) it is fixed by dynamical properties of the system (and is related to the Lyapunov exponent). The nature of the transition time between both regimes is investigated and the issue of quantum to classical correspondence is addressed. Finally, the impact of the interaction with the environment on coherent tunneling is analyzed.

Determining the state of a system and measuring properties of its evolution are two of the most important tasks a physicist faces. For the first purpose one can use tomography, a method that after subjecting the system to a number of experiments determines all independent elements of the density matrix. For the second task, one can resort to spectroscopy, a set of techniques used to determine the spectrum of eigenvalues of the evolution operator. In this letter, we show that tomography and spectroscopy can be naturally interpreted as dual forms of quantum computation. We show how to adapt the simplest case of the well-known phase estimation quantum algorithm to perform both tasks, giving it a natural interpretation as a simulated scattering experiment. We show how this algorithm can be used to implement an interesting form of tomography by performing a direct measurement of the Wigner function of a quantum system. We present results of such measurements performed on a system of three qubits using liquid state NMR quantum computation techniques in a sample of trichloroethylene. Remarkable analogies with other experiments are discussed.

We study the decoherence process for an open quantum system which is classically chaotic (a quartic double well with harmonic driving coupled to a sea of harmonic oscillators). We analyze the time dependence of the rate of entropy production showing that it has two relevant regimes: For short times it is proportional to the diffusion coefficient (fixed by the system--environment coupling strength). For longer times (but before equilibration) it is fixed by dynamical properties of the system (and is related to the Lyapunov exponent). The nature of the transition time between both regimes is investigated and the issue of quantum to classical correspondence is addressed. Finally, the impact of the interaction with the environment on coherent tunneling is analyzed.