Daniel P. Moriarty

We reexamine the relationship between pyroxene composition and near‐infrared absorption bands, integrating measurements of diverse natural and synthetic samples. We test an algorithm (PLC) involving a two‐part linear continuum removal and parabolic fits to the 1 and 2 μm bands—a computationally simple approach which can easily be automated and applied to remote sensing data. Employing a suite of synthetic pure pyroxenes, the PLC technique is shown to derive similar band centers to the modified Gaussian model. PLC analyses are extended to natural pyroxene‐bearing materials, including (1) bulk lunar basalts and pyroxene separates, (2) diverse lunar soils, and (3) HED meteorites. For natural pyroxenes, the relationship between composition and absorption band center differs from that of synthetic pyroxenes. These differences arise from complexities inherent in natural materials such as exsolution, zoning, mixing, and space weathering. For these reasons, band center measurements of natural pyroxene‐bearing materials are compositionally nonunique and could represent three distinct scenarios (1) pyroxene with a narrow compositional range, (2) complexly zoned pyroxene grains, or (3) a mixture of multiple pyroxene (or nonpyroxene) components. Therefore, a universal quantitative relationship between band centers and pyroxene composition cannot be uniquely derived for natural pyroxene‐bearing materials without additional geologic context. Nevertheless, useful relative relationships between composition and band center persist in most cases. These relationships are used to interpret M³ data from the Humboldtianum Basin. Four distinct compositional units are identified (1) Mare Humboldtianum basalts, (2) distinct outer basalts, (3) low‐Ca pyroxene‐bearing materials, and (4) feldspathic materials.

“Mafic Mound” is a distinctive and enigmatic feature 75 km across and 1 km high near the center of the vast South Pole‐Aitken Basin (SPA). Using several modern data sets, we characterize the composition, morphology, and gravity signature of the structure in order to assess its origin. Mafic Mound is found to exhibit a perched circular depression and a homogeneous high‐Ca pyroxene‐bearing composition. Several formation hypotheses based on known lunar processes are evaluated, including the possibilities that Mafic Mound represents (1) uplifted mantle, (2) SPA‐derived impact melt, (3) a basalt‐filled impact crater, or (4) a volcanic construct. Individually, these common processes cannot fully reproduce the properties of Mafic Mound. Instead, we propose a hybrid origin in which Mafic Mound is an edifice formed by magmatic processes induced by the formation and evolution of SPA. This form of nonmare volcanism has not previously been documented on the Moon.

Using high‐spectral and ‐spatial resolution Moon Mineralogy Mapper data, we investigate compositional variations across the central peak structures of four impact craters within the South Pole‐Aitken Basin (SPA). Two distinct causes of spectral diversity are observed. Spectral variations across the central peaks of Bhabha, Finsen, and Lyman are dominated by soil development, including the effects of space weathering and mixing with local materials. For these craters, the central peak structure is homogeneous in composition, although small compositional differences between the craters are observed. This group of craters is located within the estimated transient cavity of SPA, and their central uplifts exhibit similar mafic abundances. Therefore, it is plausible that they have all uplifted material associated with melts of the lower crust or upper mantle produced during the SPA impact. Compositional differences observed between the peaks of these craters reflect heterogeneities in the SPA subsurface, although the origin of this heterogeneity is uncertain. In contrast to these craters, Leeuwenhoek exhibits compositional heterogeneity across its central peak structure. The peak is areally dominated by feldspathic materials, interspersed with several smaller exposures exhibiting a mafic spectral signature. Leeuwenhoek is the largest crater included in the study and is located in a region of complex stratigraphy involving both crustal (feldspathic) and SPA (mafic melt and ejecta) materials. The compositional diversity observed in Leeuwenhoek's central peak indicates that kilometer‐scale heterogeneities persist to depths of more than 10 km in this region.