Jörg Maier

With the increasing global emphasis on renewable energy, the generation of biomass fly ash is anticipated to rise substantially in the coming years. This trend highlights the urgent need for effective strategies to manage and utilize this byproduct sustainably. This study reviews and classifies selected types of biomass ashes, treating them as representative examples that illustrate the wide variability in chemical compositions and physical properties across different biomass sources. These include ashes derived from woody biomass, agricultural residues, animal-origin biomass, and sewage sludge. Biomass ashes exhibit significant heterogeneity compared to coal ashes, which makes understanding their chemical composition—particularly the major components such as calcium (Ca), silicon (Si), and phosphorus (P)—critical for identifying suitable industrial applications. Special categories of ashes with elevated heavy metals and chlorine (Cl) levels are also identified and discussed. This approach enables the identification of sustainable utilization pathways, ranging from traditional uses, such as agricultural fertilizers and construction materials, to emerging applications in advanced engineering materials. Additionally, this paper addresses the assessment and mitigation of potential risks related to hazardous metals in biomass ashes.

The ignition characteristics of coal dust is of high importance for the flame stability in coal-fired power plants. We investigate the ignitability of six lignite dust qualities and one hard coal using dust explosion tests and an ignitability characteristic number. The paper aims to identify the degree of impact of the properties of coals, such as the moisture content, the ash content etc., on the ignition characteristics and ultimately to compare the identified relevant ignition parameters to the ignition performance of the dust qualities in an industrially relevant environment. The minimum cloud ignition temperature (MCIT), the maximum rate of pressure rise ((dp/dt)_max), the maximum explosion pressure (p_max), the deflagration index (K_st-value) and the modified ignitability characteristic number (ZWZ_mod.) were determined and were attributed to the moisture content, the ash content and the median particle size. The MCIT was largely influenced by the volatile content, whereas the variations of moisture and ash contents within the range of 10% to 20% did not have a significant impact on the MCIT. The maximum explosion pressure did not differ considerably and stayed in a narrow range among the tested dust qualities. The deflagration index showed a higher sensitivity to the dust properties. The deflagration index and the modified ignitability characteristics number dropped as the moisture content increased and the volatile content reduced. The K_st and ZWZ_mod. values showed the highest susceptibility to the coal dust properties. Hence, they were used as representative parameters for further comparison with the ignition performance of coal dust in a pilot-scale testing. The results showed that both parameters predicted the ignition performance relatively well and can be used as indicators for the prediction of the ignition performance.

The need for flexible power generation is growing worldwide as the energy transition is altering the operational regimes of thermal power plants. Plasma ignition systems, as an alternative technology to the conventional start-up method with natural gas or oil firing, offer a cost- and energy-efficient start-up process in pulverized fuel power stations. The application of plasma ignition systems for cold start-ups using different qualities of pre-dried lignite is investigated in a pilot-scale combustion facility. A plasma integrated swirl burner is developed and validated using highly ignitable lignite dust. Eight pre-dried lignite qualities with a moisture content of up to 30% and a broad particle size distribution are investigated for this application to determine the applicability and limitations of the plasma ignition system with regard to the fuel quality. The performance of lignites for cold start-up in the plasma ignition system are categorized based on their ignition and combustion performance. All lignite qualities were ignited under the cold-start-up condition with a plasma power of 4 kW to 7 kW. Lignite qualities with a moisture content of up to 20% and a median particle size of below 450 μm form a self-sustained flame with short-time plasma-supported combustion, while flame blow-out is observed for lignites with lower qualities.

Nowadays, the high share of electricity production from renewables drives coal-fired power plants to adopt a more flexible operation scheme and, at the same time, maintain flue gas emissions within respective standards. A 500 kWth pulverized coal furnace was used to study pre-dried lignite combustion or co-combustion as an available option for these plants. Bituminous coal from Czech Republic and pre-dried lignite from Greece were blended for the experiments. Particle emissions measurements with a heated Electrical Low Pressure Impactor (ELPI+) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS) analyses were performed. The effect of the pre-dried lignite proportions in the fuel feed and the combustion conditions regarding the combustion air staging were the two parameters selected for this study. Skeletal density values were measured from the cyclone prior to the impactor. Results are depicted with respect to the aerodynamic and Stokes diameter for impactor stages. The presence of pre-dried lignite in the fuel blend lowers the particle matter (PM) PM_2.5, PM₁ and PM_0.1 emissions, thus having a positive impact on ESP’s fractional and overall efficiency. The staged combustion air feed reduces the particle emissions in all cases. Sulfur content follows a pattern of higher concentration values for finer particles.

The lignite boilers are designed for lower quality fuels, and often the ash is not utilized. This work assessed the impact of combustion of an herbaceous biomass with a low-quality Greek lignite on the quality of the resulting fly ash. Test results were compared with those of fly ash samples from an industrial facility using the same fuel qualities. Inductively coupled plasma-optical (ICP) emission spectroscopy, X-ray powder diffraction (XRD), and scanning electron microscope (SEM) analyses were performed on the collected samples. Despite the significantly higher contents of K, Na and S in the biomass, at a 50% co-firing thermal share, the major and minor oxides in the fly ash were comparable to the lignite fly ash quality. This is attributed to the high ash content of the lignite, the low ash content of the biomass, and the much higher heating value of the biomass. There were improvements in fly ash performance characteristics with the herbaceous biomass in the fuel blend. The initial setting time and volume stability evaluations were improved with the biomass in the fuel blend. The work supports efforts of good practices in ash management, social responsibility, a circular economy, power plant renewable energy operations, and co-firing herbaceous biomass fuels in lignite power plants.