Jianjun Lu

Silicalite-1 nanosheets catalyst with a hierarchical architecture was hydrothermally synthesized using [C₁₈H₃₇-N⁺(CH₃)₂-C₆H₁₂-N⁺(CH₃)₂-C₆H₁₃](Br)⁻² as template. It has been studied systematically by investigating the influence of different synthesis parameters and crystallization kinetics under tumbling conditions. Highly crystalline silicalite-1 nanosheets with large external surface was obtained by regulating the crystallization time and the amount of water, template and the alkalinity. It was examined as catalyst for vapor-phase Beckmann rearrangement of cyclohexanone oxime to caprolactam and exhibited an excellent catalytic performance and long catalytic lifetime. This can be attributed to nest silanol groups located on the large external surface of the nanosheets. Furthermore, the high mesoporosity of nanosheets shorten the diffusion path length and reduce coking deposition, which remarkably improve catalyst stability.

Low-cost activated carbons were prepared from waste polyurethane foam by physical activation with CO₂ for the first time and chemical activation with Ca(OH)₂, NaOH, or KOH. The activation conditions were optimized to produce microporous carbons with high CO₂ adsorption capacity and CO₂/N₂ selectivity. The sample prepared by physical activation showed CO₂/N₂ selectivity of up to 24, much higher than that of chemical activation. This is mainly due to the narrower microporosity and the rich N content produced during the physical activation process. However, physical activation samples showed inferior textural properties compared to chemical activation samples and led to a lower CO₂ uptake of 3.37 mmol·g⁻¹ at 273 K. Porous carbons obtained by chemical activation showed a high CO₂ uptake of 5.85 mmol·g⁻¹ at 273 K, comparable to the optimum activated carbon materials prepared from other wastes. This is mainly attributed to large volumes of ultra-micropores (3·g⁻¹ and a high surface area of 1360 m²·g⁻¹. Furthermore, in consideration of the presence of fewer contaminants, lower weight losses of physical activation samples, and the excellent recyclability of both physical- and chemical-activated samples, the waste polyurethane foam-based carbon materials exhibited potential application prospects in CO₂ capture.

Polyphenylene sulfide (PPS) is easily oxidized at high temperature, which greatly limits its applications. In this study, a nano-SiO₂ compound antioxidant (SiO₂-g-AO) was prepared and incorporated into PPS by melt compounding to obtain PPS/SiO₂-g-AO composites. SiO₂-g-AO was prepared by reacting 3-(3,5-di-tert-butyl-4-hydroxyphenyl) (antioxidant AO) with an aminosilane coupling agent (KH792). Fourier transform infrared (FTIR) spectroscopy, energy dispersive spectroscopy (EDS) and thermogravimetric analysis (TGA) confirmed that the antioxidant AO was successfully immobilized on the surface of SiO₂ and the thermal stability was improved. Scanning electron microscopy (SEM) images showed that SiO₂-g-AO was uniformly dispersed in PPS. It has been found that the crystallinity and mechanical properties of PPS composites improved, and the dynamic oxidation induction temperature (OIT) increased in the range of 16.7°C–21.1°C. A synergistic anti-oxidation model of nanoparticles and antioxidants, namely a multi-stage antioxidant system, was established by comprehensive analysis of experimental results. The synergistic anti-oxidation model provides a new idea for the antioxidant modification of polymer composites.

More and more polyimide (PI) mixed matrix membranes (MMMs) have been reported for gas separation. In this study, a novel PI MMM, named as PI/SNW-1 and composed of PI and Schiff base network (SNW) type covalent organic frameworks (COFs) SNW-1, was used for gas permeation measurements of carbon dioxide (CO₂) and methane (CH₄). The prepared PI/SNW-1 was investigated by the Fourier transform infrared spectroscopy, the field emission scanning electron microscopy, and the thermal gravimetric analysis. The results indicated that PI/SNW-1 had maintained a high thermal stability and uniform distribution of filler. Compared with the pure PI membrane, MMMs showed an increment of 48.7% in ideal selectivity of CO₂/CH₄ and an enhancement of 106.4% in CO₂ permeability at 5 wt% SNW-1. The enhancement of permeability and selectivity was mainly attributed to the high porosity of SNW-1, the specific sorption affinity for CO₂, and the close interface interaction with the PI matrix. It can be seen that PI/SNW-1 has a great potential for actual gas separation.

An efficient tandem route to the synthesis of triazacyclopenta[cd]indenone derivatives of the cyclazine family has been developed. Target compounds were obtained in moderate to good yields by Groebke–Blackburn–Bienaymé reaction involving a potassium carbonate promoted intramolecular aminolysis. This in turn will set the stage for a wide application of this useful reaction for the synthesis of structurally diverse polyheterocyclic skeletons containing the imidazo[1,2‐a]pyridine ring.