John J. Cowan

This review of the rapid-neutron-capture (i.e. r-) process starts with determining the Solar System r-abundance pattern via first obtaining (and subtracting) the contribution from the slow-neutron capture (s-) process. We emphasize the extensive work in this area by our late colleague Roberto Gallino and continue in an overview, concentrating on attempts to reproduce the solar r-process pattern with historical site-independent approaches, based on nuclear physics far from stability. In a second step we address the existing proposals for astrophysical sites. Among stellar observations we start with available observations of individual events before analyzing low-metallicity stars, which witness r-process contributions in the early Galaxy. We conclude with a comparison of observations and model predictions, focusing on our present ability to identify the responsible individual astrophysical sites by their imprint in Galactic evolution.

We have derived new detailed abundances of Mg, Ca, and the Fe-group elements Sc through Zn (Z = 21−30) for 37 main-sequence turnoff very metal-poor stars ([Fe/H] ≲−2.1). We analyzed Keck HIRES optical and near-UV high signal-to-noise spectra originally gathered for a Be abundance survey. Using typically ∼400 Fe-group lines with accurate laboratory transition probabilities for each star, we have determined accurate LTE metallicities and abundance ratios for neutral and ionized species of the 10 Fe-group elements as well as α elements Mg and Ca. We find good neutral/ion abundance agreement for the six elements that have detectable transitions of both species in our stars in the 3100–5800 Å range. Earlier reports of correlated Sc−Ti−V relative overabundances are confirmed, and appear to slowly increase with decreasing metallicity. To this element trio we add Zn; it also appears to be increasingly overabundant in the lowest-metallicity regimes. Co appears to mimic the behavior of Zn, but issues surrounding its abundance reliability cloud its interpretation.

We have derived new detailed abundances of Mg, Ca, and the Fe-group elements Sc through Zn (Z = 21-30) for 37 main sequence turnoff very metal-poor stars ([Fe/H] <= -2.1). We analyzed Keck HIRES optical and near-UV high signal-to-noise spectra originally gathered for a beryllium abundance survey. Using typically about 400 Fe-group lines with accurate laboratory transition probabilities for each star, we have determined accurate LTE metallicities and abundance ratios for neutral and ionized species of the 10 Fe-group elements as well as alpha elements Mg and Ca. We find good neutral/ion abundance agreement for the 6 elements that have detectable transitions of both species in our stars in the 3100-5800 Angstrom range. Earlier reports of correlated Sc-Ti-V relative overabundances are confirmed, and appear to slowly increase with decreasing metallicity. To this element trio we add Zn; it also appears to be increasingly overabundant in the lowest metallicity regimes. Co appears to mimic the behavior of Zn, but issues surrounding its abundance reliability cloud its interpretation.

We report new measurements of branching fractions for 20 UV and blue lines in the spectrum of neutral silicon (Si i) originating in the 3s ²3p4s ³P^o _1,2,¹P^o ₁, and 3s3p ^{3 1}D^o _1,2 upper levels. Transitions studied include both strong, nearly pure LS multiplets as well as very weak spin-forbidden transitions connected to these upper levels. We also report a new branching fraction measurement of the ⁴P_1/2–²P^o _1/2,3/2 intercombination lines in the spectrum of singly ionized silicon (Si ii). The weak spin-forbidden lines of Si i and Si ii provide a stringent test on recent theoretical calculations, to which we make comparison. The branching fractions from this study are combined with previously reported radiative lifetimes to yield transition probabilities and log(gf) values for these lines. We apply these new measurements to abundance determinations in five metal-poor stars.

The goals of this study are (1) to test the best theoretical transition probabilities for Ca i (a relatively light alkaline earth spectrum) from a modern ab initio calculation using configuration interaction plus many-body perturbation theory against the best modern experimental transition probabilities and (2) to produce as accurate and comprehensive a line list of Ca i transition probabilities as is currently possible based on this comparison. We report new Ca i radiative lifetime measurements from a laser-induced fluorescence experiment and new emission branching fraction measurements from a 0.5 m focal length grating spectrometer with a detector array. We combine these data for upper levels that have both a new lifetime and new branching fractions to report log(gf) values for two multiplets consisting of nine transitions. Detailed comparisons are made between theory and experiment, including the measurements reported herein and a selected set of previously published experimental transition probabilities. We find that modern theory compares favorably to experimental measurements in most instances where such data exist. A final list of 202 recommended transition probabilities is presented, which covers lines of Ca i with wavelengths ranging from 2200 to 10000 Å. These are mostly selected from theory but are augmented with high-quality experimental measurements from this work and from the literature. The recommended transition probabilities are used in a redetermination of the Ca abundance in the Sun and in the metal-poor star HD 84937.

The production of about half of the heavy elements found in nature is assigned to a specific astrophysical nucleosynthesis process: the rapid neutron capture process (r-process). Although this idea has been postulated more than six decades ago, the full understanding faces two types of uncertainties/open questions: (a) The nucleosynthesis path in the nuclear chart runs close to the neutron-drip line, where presently only limited experimental information is available, and one has to rely strongly on theoretical predictions for nuclear properties. (b) While for many years the occurrence of the r-process has been associated with supernovae, more recent studies have cast substantial doubts on this environment. Alternative scenarios include the mergers of neutron stars, neutron-star black hole mergers, but possibly also rare classes of supernovae as well as hypernovae/collapsars with polar jet ejecta and also accretion disk outflows related to the collapse of fast rotating massive stars with high magnetic fields. Stellar r-process abundance observations, have provided insights into, and constraints on the frequency of and conditions in the responsible stellar production sites. One of them, neutron star mergers, was just identified and related to the Gravitational Wave event GW170817. High resolution observations, increasingly more precise due to improved experimental atomic data, have been particularly important in defining the heavy element abundance patterns of the old halo stars, and thus determining the extent, and nature, of the earliest nucleosynthesis in our Galaxy. Combining new results and important breakthroughs in the related nuclear, atomic and astronomical fields of science, this review attempts to provide an answer to the question "How Were the Elements from Iron to Uranium Made?" (Abridged)

We have obtained new detailed abundances of the Fe-group elements Sc through Zn (Z=21-30) in three very metal-poor ([Fe/H] $\approx -3$) stars: BD 03 740, BD -13 3442 and CD -33 1173. High-resolution ultraviolet HST/STIS spectra in the wavelength range 2300-3050\AA\ were gathered, and complemented by an assortment of optical echelle spectra. The analysis featured recent laboratory atomic data for number of neutral and ionized species for all Fe-group elements except Cu and Zn. A detailed examination of scandium, titanium, and vanadium abundances in large-sample spectroscopic surveys indicates that they are positively correlated in stars with [Fe/H]<-$2. The abundances of these elements in BD 03 740, BD -13 3442 and CD -33 1173 and HD 84937. (studied in a previous paper of this series) are in accord with these trends and lie at the high end of the correlations. Six elements have detectable neutral and ionized features, and generally their abundances are in reasonable agreement. For Cr we find only minimal abundance disagreement between the neutral (mean of [Cri/Fe]=+0.01) and ionized species (mean of [Crii/Fe]=+0.08), unlike most studies in the past. The prominent exception is Co, for which the neutral species indicates a significant overabundance (mean of [Co/H]=-2.53), while no such enhancement is seen for the ionized species (mean of [Coii/H]=-2.93). These new stellar abundances, especially the correlations among Sc, Ti, and V, suggest that models of element production in early high-mass metal-poor stars should be revisited.

The development of tunable dye lasers and a simple atomic and ionic beam source for all elements were critical in establishing a reliable absolute scale for atomic transition probabilities in the optical to near UV regions. The laboratory astrophysics program at the University of Wisconsin - Madison (UW) concentrates on neutral and singly-ionized species transitions that are observable in astronomical spectra of cool stars, emphasizing the rare earth n(eutron)-capture elements and the Fe-group elements that are important inputs to early Galactic nucleosynthesis studies. The UW program is one of several productive efforts on atomic transition probabilities. These programs generally use time-resolved laser-induced-fluorescence (TR-LIF) to accurately measure total decay rates and data from high resolution Fourier transform spectrometers (FTSs) to determine emission branching fractions (BFs). The UW laboratory results almost always are directly linked to astronomical chemical composition efforts. There are good opportunities to extend similar research to other wavelength regions.