Ion Mitelea

Cavitation erosion is a phenomenon that causes the degradation of engineering components operating in fluids under oscillating pressure, and it occurs through the repeated implosion of cavitation bubbles adjacent to the solid surface. This complex phenomenon involves both the hydrodynamic factors of the liquid and the properties of the material being eroded. Cavitation erosion tests were performed using a vibratory apparatus with piezoceramic crystals, in accordance with the ASTM G32-2016 standard. As a reference material, a wrought aluminum-based alloy in the hot-rolled condition, EN AW-6082, was selected. For both alloys, mass losses were measured and erosion rates were calculated. The eroded surfaces were examined by X-ray diffraction (XRD), optical microscopy, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). The results indicate that the cavitation erosion resistance of the AZ 31B alloy in the hot-rolled condition is approximately 3.77 times lower than that of the reference material. This behavior is attributed to its lower hardness and heterogeneous microstructure, consisting of an α solid solution matrix with a hexagonal close-packed crystal structure and intermetallic particles of the Mg₁₇Al₁₂ type, which exhibit pronounced brittleness. Cavitation pits are observed mainly within the α-Mg solid solution grains and at the interfaces between the intermetallic phases and the α-Mg matrix.

The present work aims to investigate the microstructure and mechanical properties of laser beam spot welds in the superalloy Nimonic 80 A. Considering the importance of this innovative process in the manufacturing of engineering components for high-security industries, it is necessary to study the influence of the welding thermal cycle on the microstructure and mechanical properties of welded joints. The rapid heating/cooling, melting, and re-solidification phenomena that occur during welding modify the metallurgical characteristics of the weld compared with the microstructure of the base metal. Because the energy density is high and the process duration is very short, the microstructure obtained after solidification is fine dendritic in the central area of the joint and columnar in the weld–base metal transition zone. For the same reasons, the heat-affected zone (HAZ) is slightly extended. The increase in the size of the crystalline grains in the HAZ is negligible due to the low diffusivity of the nickel-based γ solid solution matrix, which inhibits the rapid migration of grain boundaries during the welding process. Metallographic analyses were performed using optical microscopy and scanning electron microscopy. The microhardness values, 152–168 HV0.05 in the weld and 180–190 HV0.05 in the base metal, together with the tensile–shear strength values (760–780 N/mm²) obtained at room temperature, demonstrate that the proposed welding process is appropriate and feasible for engineering applications involving Nimonic 80A superalloys.

Cavitation erosion is a critical problem for many engineering components, such as ship propellers, diesel engine exhaust valves, cylinder liners, pump impeller blades, hydraulic turbines, and bearings, which are exposed to high-velocity flowing fluids or to vibratory fluid motion. It represents a mechanical degradation of the surface caused by the continuous collapse of bubbles in the surrounding liquid, which seriously affects flow efficiency and component service life, increasing maintenance frequency and refurbishment costs. The intensity and evolution of the cavitation erosion phenomenon depend on the hydrodynamic conditions to which the component surface is exposed, the properties of the liquid, and the judicious selection of the most suitable material. This paper aims to modify the microstructure of a Ni-based superalloy by applying recrystallization annealing heat treatment in order to obtain surfaces resistant to cavitation erosion for components that handle fluids under local pressure fluctuations. Experimental tests are carried out using a vibratory apparatus with piezoceramic crystals operating at a frequency of 20 kHz and an amplitude of 50 µm. The cavitation erosion performance of the Ni-based superalloy INCONEL 625, heat treated by recrystallization annealing, are compared with that of austenitic stainless steel AISI 316L subjected to solution treatment. For both metallic alloys, based on mass loss measurements, the characteristic time-dependent curves of the mean cumulative erosion penetration depth, MDE(t), and the mean erosion rate, MDER(t), are determined. The comparison of these curves and of the parameters defined and recommended by the ASTM G32 standard demonstrates that, for the Inconel 625 superalloy, resistance to cavitation erosion increases by 77–81% compared to that of AISI 316L austenitic stainless steel. X-ray diffraction analyses (XRD) show that, in the microstructure of the Inconel 625 superalloy, in addition to austenite, MC-type carbides, M₂₃C₆ carbides, and intermetallic phases γ″ = Ni₃(Nb, Al, Ti) and δ = Ni₃(Nb, Mo) are also present.

Cavitation-induced degradation of metallic materials presents a significant challenge for engineers and users of equipment operating with high-velocity fluids. For any metallic material, the mechanical strength and ductility characteristics are controlled by the mobility of dislocations and their interaction with other defects in the crystal lattice (such as dissolved foreign atoms, grain boundaries, phase separation surfaces, etc.). The increase in mechanical properties, and consequently the resistance to cavitation erosion, is possible through the application of heat treatments and cold plastic deformation processes. These factors induce a series of hardening mechanisms that create structural barriers limiting the mobility of dislocations. Cavitation tests involve exposing a specimen to repeated short-duration erosion cycles, followed by mass loss measurements and surface morphology examinations using optical microscopy and scanning electron microscopy (SEM). The results obtained allow for a detailed study of the actual wear processes affecting the tested material and provide a solid foundation for understanding the degradation mechanism. The tested material is the Ni-based alloy INCONEL 625, subjected to stress-relief annealing heat treatment. Experiments were conducted using an ultrasonic vibratory device operating at a frequency of 20 kHz and an amplitude of 50 µm. Microstructural analyses showed that slip bands formed due to shock wave impacts serve as preferential sites for fatigue failure of the material. Material removal occurs along these slip bands, and microjets result in pits with sizes of several micrometers.

Lamellar graphite pearlitic grey cast irons are frequently used in the manufacturing of components that operate under cavitation erosion conditions. Their poor performance regarding cavitation erosion limits their use in intense cavitation environments. The physical modification of the surface layer offers a flexible and cost-effective way to combat cavitation attacks without altering the core properties. This paper comparatively analyzes the effects of four technological processing methods on the cavitation erosion resistance of grey cast irons. Cavitation erosion tests were conducted on a vibrating device with piezoceramic crystals in accordance with the ASTM G32-2016 standard. Surface hardness tests were carried out using a Vickers hardness tester, while roughness measurements were performed using a Mitutoyo device. The microstructures generated by the applied technologies and the surface wear mechanisms were analyzed using optical microscopy and scanning electron microscopy (SEM). The results indicated that the TIG local surface remelting process provides the most significant improvement in cavitation erosion resistance.

This paper explores the enhancement of cavitation and corrosion resistance in cast stainless steel through laser beam surface remelting. The influence of laser treatment on material properties was assessed by analyzing the microstructure using optical microscopy, electron microscopy, and X-ray diffraction. Cavitation erosion was evaluated in tap water using an ultrasonic vibration setup, following ASTM G32—2016 standards. Results show that local remelting of the surface with a laser beam causes a reduction in material loss and cavitation erosion rate. Potentiodynamic polarization tests revealed a significant improvement in corrosion resistance, indicated by a reduced corrosion current density in the laser-treated surface. The observed improvements in cavitation and corrosion resistance are attributed to microstructural hardening, characterized by grain refinement and a uniform, homogeneous structure with finely dispersed, small precipitate particles.

Cavitation erosion, as a mechanical effect of destruction, constitutes a complex and critical problem that affects the safety and efficiency of the functioning of engineering components specific to many fields of work, the most well-known being propellers of ships and maritime and river vessels, seawater desalination systems, offshore oil and gas drilling platforms (including drilling and processing equipment), and the rotors and blades of hydraulic machines. The main objective of the research conducted in this paper is to experimentally investigate the phenomenology of this surface degradation process of maritime ships and offshore installations operating in marine and river waters. To reduce cavitation erosion of maritime structures made from Duplex stainless steels, the study used the deposition by welding of layers of metallic alloys with a high capacity for work hardening. The cavitation tests were conducted in accordance with the American Society for Testing and Materials standards. The response of the deposited metal under each coating condition, compared to the base metal, was investigated by calculating the erosion penetration rate (MDER) through mass loss measurements over the cavitation duration and studying the degraded zones using scanning electron microscopy (SEM), the energy-dispersive X-ray analysis, and hardness measurements. It was revealed that welding hardfacing with austenitic manganese alloy contributes to an approximately 8.5–10.5-fold increase in cavitation erosion resistance. The explanation is given by the increase in surface hardness of the coated area, with 2–3 layers of deposited alloy reaching values of 465–490 HV5, significantly exceeding those specific to the base metal, which range from 260–280 HV5. The obtained results highlighted the feasibility of forming hard coatings on Duplex stainless-steel substrates.

Duplex stainless steels are materials with high performance under mechanical stress and stress corrosion in chloride ion environments. Despite being used in many new applications such as components for offshore drilling platforms as well as in the chemical and petrochemical industry, the automotive industry, etc., they face issues of wear and hardness that limit current applications and prevent the creation of new use opportunities. To address these shortcomings, it is proposed to develop a hardfacing process by a special welding technique using a universal TIG source adapted for manual welding with a pulsed current, and a manganese austenitic alloy electrode as filler material. The opportunity to deposit layers of manganese austenitic steel through welding creates advantages related to the possibility of achieving high mechanical characteristics of this steel exclusively in the working area of the part, while the substrate material will not undergo significant changes in chemical composition. As a result of the high strain hardening rate, assisted mainly by mechanical twinning, manganese austenitic alloys having a face-centered cubic crystal lattice (f.c.c) and low stacking fault energy (SFE = 20–40 mJ/m²) at room temperature, exhibit high wear resistance and exceptional toughness. Following cold deformation, the hardness of the deposited metal increases to 465 HV5–490 HV5. The microstructural characteristics were investigated through optical microscopy (OM), scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), X-ray diffraction (XRD), and Vickers hardness measurements (HV). The obtained results highlighted the feasibility of forming hard coatings on duplex stainless steel substrates.

Fe-Mn-Cr-Ni alloys like Citomangan, delivered in the form of powders, tubular wires, and coated electrodes, are intended for welding deposition operations to create wear-resistant layers. Their main characteristic is their high capacity for surface mechanical work-hardening under high shock loads, along with high toughness and wear resistance. In order to increase the resistance to cavitation erosion, hardfacing of Duplex stainless steel X2CrNiMoN22-5-3 with Citomangan alloy was performed using a new welding technique, namely one that uses a universal TIG source adapted for manual welding with a coated electrode in pulsed current. Cavitation tests were conducted in accordance with the requirements of ASTM G32—2016 standard. Comparing the characteristic cavitation erosion parameters of the manganese austenitic layer, deposited by this new welding technique, with those of the reference steel, highlights an 8–11 times increase in its resistance to cavitation erosion. Metallographic investigations by optical microscopy and scanning electron microscopy (SEM), as well as hardness measurements, were carried out to understand the cavitation phenomena.

Fe-based coatings reinforced with TiC particles exhibit outstanding properties and are widely recognized as highly promising coatings or components with superior performance. In the present study, composite materials using a powder mixture of AISI 316 stainless steel and TiC particles were deposited by vacuum plasma spraying onto a S235 low alloyed steel substrate. The coating and the base material were characterized in terms of microstructure and surface properties. The metallographic analysis of the deposited coating revealed the uniform distribution of the TiC into the stainless steel matrix. The results show that the presence of tungsten carbide particles improved the hardness and tribological properties of the composite coating compared with the S235 base material. The wear resistance of the coating was approximately seven times higher than that of the low alloyed steel substrate. The electrochemical corrosion resistance of the coating in chloride media was much higher than that of the base material.