Diogo Henrique de Bem

Corrosion is one of the causes of failure in reinforced concrete structures, and forming a passive film on the steel is essential for protection. Although several studies have looked at passive film formation in concrete pore solutions, few have considered its formation in hardened concrete and the influence of silica fume (SF) in the binder composition. This study aims to evaluate the influence of the SF content on passive film formation time in concrete. Periodic measurements assessed the electrical resistivity and corrosion current density of concrete samples containing 5%, 10%, 15%, and 20% SF. The alkalinity of the mixtures and the kinetics of the pozzolanic reaction were also monitored by XRD and titration tests. The control mixtures exhibited susceptibility to corrosion, regardless of the curing age evaluated. In contrast, the partial replacement of cement with SF accelerated the formation of the passive film on the steel surface, suggesting a delayed onset of corrosion due to modifications in the physical properties of the concrete. Also, the portlandite content and pH can predict passive film formation, with SF significantly accelerating this process.

Purpose: The purpose of this paper is to verify the influence of superplasticizer and air entrainment admixtures (AEs) in the electrical resistivity of concrete. Design/methodology/approach: Ten different types of concrete have been studied. Three levels of superplasticizer and air AEs have been used (0.20, 0.35 and 0.50 per cent). Concrete samples were cast and the electrical resistivity was monitored at the ages of 28, 63 and 91 days. Compressive strength and density tests have also been executed. Findings: The superplasticizer admixture presented an optimal level of 0.35 per cent that significantly increased the electrical resistivity. The air AEs at the same dosage caused a considerable decrease in the electrical resistivity. The concrete with air AEs showed highest resistivity/MPa ratio. Research limitations/implications: The results should be carefully extrapolated for other materials and admixtures. Practical implications: The usage of chemicals admixture in concrete is extremely common nowadays. However, only a few authors have studied the impact of such materials on the concrete’s electrical resistivity. Since many other researchers have already correlated electrical resistivity with other concrete’s properties, such as strength, setting time and corrosion probability, it is important to better understand how superplasticizers and air-entraining agents, for instance, impact the resistivity. Originality/value: The vast majority of studies only tested the resistivity of cement paste or mortar and usually for short period of time (up to 28 days), which seems not to be adequate since the cement reaction continues after that period. This paper fills this gap and studied the impact of admixture on concrete and for a period of 91 days.