Robert J. Agnew

Personal protective equipment (PPE) is designed to protect firefighters from hazards encountered on the fire scene, including heat and products of combustion. Decontamination practices for firefighter turnout gear have been developed to remove combustion products and other contaminants from the fabric of structural firefighting ensembles (i.e., turnout or bunker gear). Chronic exposures to residual polycyclic aromatic hydrocarbons (PAH) are a contributing cause of firefighter cancers. To identify and quantify residual contamination of PAH, samples were taken from two individual decommissioned structural firefighting ensembles and analyzed by layer (outer canvas shell, moisture barrier, and the thermal protective liner) for (1) textile integrity via field emission scanning electron microscopy and (2) quantity of PAH contamination by high-pressure liquid chromatography with ultraviolet/fluorescence detection. The results of these analyses show the presence of the PAH compounds pyrene (35% of the total mass of PAH), phenanthrene (21%), benzo(a)pyrene (14%), and benzo(a)anthracene (14%) which present a risk for dermal absorption. The data also revealed that PAH penetration through the layers of the firefighting ensemble was strongly inhibited by the moisture barrier layer.

Portable X-ray fluorescence has successfully been used to effectively evaluate occupational exposure to airborne and surface metal contaminants non-destructively. Traditional methods of assessing metal surface contamination involve the costly, time-consuming collection and laboratory analysis of wipe samples, making portable X-ray fluorescence an attractive alternative method for screening worksites by reducing delays in risk assessment decision-making. Existing research into this use of portable X-ray fluorescence has primarily been centered on the analysis of airborne and surface lead contamination. The extant literature is sparse on the use of portable X-ray fluorescence with other metals for surface contamination with respect to occupational exposure. The present study evaluated the use of portable X-ray fluorescence in the screening of cadmium surface contamination to determine if the effectiveness of decontamination measures can be ascertained by this technique. Wipe samples were collected and screened with portable X-ray fluorescence before being sent to the laboratory for definitive analysis to assess the correlation between portable X-ray fluorescence readings in percent mass with laboratory results in μg/ft². Portable X-ray fluorescence readings demonstrated a strong linear correlation with laboratory results, as indicated by the R² value of 0.993. Therefore, this technique may be further developed and deployed as a screening tool for wipe samples used for evaluating contamination and decontamination of metal-contaminated areas.

Quick drying is one of the most crucial factors in the comfort and performance of active sportswear clothing. It helps to keep the wearer dry and comfortable by effectively wicking away sweat and moisture from the body. In the light of this, a substantial number of previous researchers have identified fabric properties and types that have a significant impact on fabric drying performance. Studies have also been conducted to examine the impact of fabric drying on human physiology during sports-related activities. However, there are still some technical knowledge gaps in the existing literature related to the drying performance of active sportswear fabrics. This review article provides a critical analysis of the literature on the impact of various fabric attributes as well as the physiological and environmental factors on moisture management and drying performance. The key issues in this field are determined so that future research can be directed and this scientific field can advance in order to improve the overall performance of active sportswear fabrics.

Absorption and transportation of moisture from sweat are the crucial properties of the fabrics used in performance clothing. Sweat moisture is a significant factor that may cause discomfort to the wearer. The majority of the injuries and fatalities that happen to the high-risk sector workers in their line of duty may be caused by inadequate comfort provided by the protective uniform. The purpose of this study is to scientifically investigate the sweat drying performance of the different protective fabrics used in high-risk sectors’ workers’ clothing. Firstly, this study experimentally analyzed the sweat drying of protective fabrics with different attributes under various ambient environments and wearers’ internal physiology. Secondly, this study explained the phenomena of sweat drying in protective fabric through the theory of heat and mass transfer. Sweat drying performance of the fabrics used in functional clothing mainly depends on the evaporative resistance regardless of the presence of water and oil repellent coating on the fabric surface. The drying performance increases with the increased wetted area and increased air flow. The wetted area depends on the absorption and wicking properties of the fabrics. The findings of this research will advance the field by developing knowledge on sweat drying performance of fabrics used in protective clothing; in turn, this could provide better comfort and safety to high-risk sectors’ workers.

The hydropneumograph is a new technique for analyzing aquifer discharge dynamics for bubbling springs that increases the accuracy of gas derived groundwater parameters.

Firefighters are intermittently exposed to complex, mixed pollutants in random settings. Of those pollutants, PAHs (polycyclic aromatic hydrocarbons) are the most commonly studied and best understood. PAH exposure can occur via multiple routes; therefore, the levels of hydroxylated metabolites of PAHs in urine have been used as a biomonitoring tool for risk assessment. We performed a systematic review and meta-analysis of the literature to estimate the levels of urinary hydroxylated PAH (OHPAH) among firefighters, determine risk attributions, and, finally, evaluate the scope of preventive efforts and their utility as diagnostic tools. The meta-regression confirmed increases in OHPAH concentrations after fire activities by up to 1.71-times (p-values: Standard on Comprehensive Occupational Medical Program for Fire Departments lists various health examinations, including a urinalysis for occupational chemical exposure if indicated and medical screening for cancers and cardiovascular diseases. Biomonitoring is a valuable screening tool for assessing occupational exposure and the results of this meta-analysis support their inclusion in regular health screenings for firefighters.

More than 60,000 firefighters’ injuries were reported by the National Fire Protection Association in the U.S. in 2019. Inadequate protection by bunker gear could be a reason for most of the injuries. Firefighters repeatedly encounter thermal hazards due to their job responsibilities. Degradation could occur on bunker gear fabric during thermal exposure. It has been found that the presence of moisture affects performance as well, which may come from wearers’ sweat. Proper evaluation of the tensile strength of the fabrics used in bunker gear could provide information essential for maintenance the overall integrity of the gear. An evaluation of the tensile strength of fabrics when exposed to 10, 15, and 20 kW/m² radiant heat flux in the presence of moisture is reported. In each fabric system, a total of sixty-four different samples were prepared for four different types of fabric and four levels of moisture which were exposed to three different radiant heat flux for five minutes. Heat flux and moisture levels have significant impact on tensile strength. The effect of moisture on tensile strength in a three-layered fabric system is higher than that for a single layer fabric. An understanding of the impact of heat and moisture on fabric strength has been achieved.

Most of the fatalities and injuries of oilfield workers result from inadequate protection and comfort by their clothing under various work hazards and ambient environments. Both the thermal protective performance and thermo-physiological comfort performance of textile fabrics used in clothing significantly contribute to the mitigation of workers’ skin burns and heat-stress-related deaths. This study aimed to apply the ANN modeling approach to analyze clothing performance considering the wearers’ sweat moisture and the microclimate air gap that is generated in between their body and clothing. Firstly, thermal protective and thermo-physiological comfort performance of fire protective textiles used in oilfield workers’ clothing were characterized. Different fabric properties (e.g., thickness, weight, fabric count), thermal protective performance, and thermo-physiological comfort performance were measured. The key fabric property that affects thermal protective and thermo-physiological performance was identified as thickness by statistical analysis. The ANN modeling approach could be successfully implemented to analyze the performance of fabrics in order to predict the performance more conveniently based on the fabric properties. It is expected that the developed models could inform on-duty oilfield workers about protective and thermo-physiological comfort performance and provide them with occupational health and safety.

In 2017, more than 60,000 firefighters and oilfield-workers injuries and fatalities occurred while they were working under various thermal hazards such as flame, radiant heat, steam, etc., or due to their significant heat stress related discomfort. The majority of these burn injuries and fatalities results from an inadequate protection and comfort provided by firefighters’ and oilfield-workers’ fire protective polymeric textile materials used in their workwear. Hence, both the thermal protective and thermo-physiological comfort performance of fabrics used in workwear significantly contribute to limit firefighters’ and oilfield-workers’ skin burns and heat stress. Considering this, previous studies have focused on characterizing and developing empirical models to predict the protective and comfort performance based on physical properties of the fabrics. However, there are still some technical knowledge gaps in the existing literature related to this. This paper critically reviewed the literature on characterization and modeling of thermal protective and thermo-physiological comfort performance of fire protective textile fabric materials. The key issues in this field have been indicated in order to provide direction for the future research and advance this scientific field for better protection and comfort of the firefighters and oilfield-workers.