Florian Vercruysse

Quenching and Partitioning (Q&P) steels are, due to their excellent combination of strength and ductility, seen as good candidates for the third generation advanced high strength steels (AHSS). Although the TRIP effect is beneficial for the overall mechanical behaviour of these steels it potentially can have detrimental effects when strained in a hydrogenenriched environment. The solubility of hydrogen is high in austenite but low in high carbon martensite. Martensite is even in the absence of hydrogen already a possible damage initiation spot. The effect of hydrogen under static and dynamic tensile loading was evaluated in a Q&P and a Nb micro-alloyed Q&P steel. Experiments were carried out under a strain rate ranging from 0.03 s^-1 till 500 s^-1 and correlated with the hydrogen uptake characterised via thermal desorption spectroscopy (TDS). The presence of Nb resulted in a 25% increase in the hydrogen uptake capacity. A higher susceptibility to hydrogen was observed in the Nb steel partially due to the high hydrogen fraction, but also because of the larger fraction of low stability austenite. However, when tested under dynamic conditions the hydrogen susceptibility is minor and even improved in the micro-alloyed Q&P steel compared to the standard Q&P steel.

Because of their excellent combination of strength and ductility, quenching and partitioning (Q & P) steels have a great chance of being added to the third generation of advanced high strength steels. The large ductility of Q & P steels arises from the presence of 10% to 15% of retained austenite which postpones necking due to the transformation induced plasticity (TRIP) effect. Moreover, Q & P steels show promising forming properties with favourable Lankford coefficients, while their planar anisotropy is low due to a weak texture. The stability of the metastable austenite is the key to obtain tailored properties for these steels. To become part of the newest generation of advanced high strength steels, Q & P steels have to preserve their mechanical properties at dynamic strain rates and over a wide range of temperatures. Therefore, in the present study, a low-Si Q & P steel was tested at temperatures from −40 °C to 80 °C and strain rates from 0.001 s⁻¹ to 500 s⁻¹. Results show that the mechanical properties are well-preserved at the lowest temperatures. Indeed, at −40 °C and room temperature, no significant loss of the deformation capacity is observed even at dynamic strain rates. This is attributed to the presence of a large fraction of austenite that is so (thermally) stable that it does not transform in the absence of deformation. In addition, the high stability of the austenite decreases the elongation at high test temperatures (80 °C). The additional adiabatic heating in the dynamic tests causes the largest reduction of the uniform strain for the samples tested at 80 °C. Quantification of the retained austenite fraction in the samples after testing confirmed that, at the highest temperature and strain rate, the TRIP effect is suppressed.

Advanced high strength steels (HSSs), such as dual phase steels, are widely used in the automotive industry due to their excellent combination of strength and ductility. In certain applications, they might be exposed to hydrogen (H) which is known to be detrimental for the deformation. H embrittlement (HE) is still not fully understood. It might drastically reduce the energy absorbed in a crash event and limits the use of HSSs in car bodies. Although H diffusion is a highly time dependent phenomenon, so far, the combined effect of dynamic strain rates and electrochemical H pre-charging has not been studied. Therefore, a reproducible methodology has been developed. Tensile specimens were electrochemically H pre-charged and immediately tested in a split Hopkinson tensile bar setup. To distinguish between the effect of strain rate and HE, static tests have been conducted using the same procedure. Results show that the HE resistance decreased due to higher H amounts in the sample for all strain rates. The HE increased when slower strain rates were applied due to higher probability of H to diffuse to regions of stress concentration ahead of a crack tip and as such accelerating failure. At the highest strain rate considered (900 s-1), the material still lost about 10% of its ductility.

Ultra-fast annealing (UFA) is a viable alternative for processing of 3rd generation advanced high strength steels (AHSS). Use of heating rates up to 1000°C/s shows a significant grain refinement effect in low carbon steel (0.1 wt.%), and creates multiphase structures containing ferrite, martensite, bainite and retained austenite. This mixture of structural constituents is attributed to carbon gradients in the steel due to limited diffusional time during UFA treatment. Quasi-static (strain rate of 0.0033s-1) and dynamic (stain rate 600s-1) tensile tests showed that tensile strength of both conventional and UFA sample increases at high strain rates, whereas the elongation at fracture decreases. The ultrafast heated samples are less sensitive to deterioration of elongation at high strain rates then the conventionally heat treated ones. Based on metallographic studies was concluded that the presence of up to 5% of retained austenite together with a lower carbon martensite/bainite fraction are the main reason for the improved tensile properties. An extended stability of retained austenite towards higher strain values was observed in the high strain rate tests which is attributed to adiabatic heating. The extension of the transformation induced plasticity (TRIP) effect towards higher strain values allowed the UFA-samples to better preserve their deformation capacity resulting in expected better crashworthiness.