Henrika Granbohm

In the published article “Control of the Size of Silver Nanoparticles and Release of Silver in Heat Treated SiO₂-Ag Composite Powders” [1] a reference was omitted in the caption of Figure 4b.

Titania nanotube (TNT) powder was prepared by rapid breakdown anodization (RBA) in a perchloric acid electrolyte. The photocatalytic efficiency of the as-prepared and powders annealed at temperatures between 250 and 550 °C was tested under UV and natural sunlight irradiation by decolorization of both anionic and cationic organic dyes, i.e., methyl orange (MO) and rhodamine B (RhB), as model pollutants. The tubular structure of the nanotubes was retained up to 250 °C, while at 350 °C and above, the nanotubes transformed into nanorods and nanoparticles. Depending on the annealing temperature, the TNTs consist of anatase, mixed anatase/brookite, or anatase/rutile phases. The bandgap of the as-prepared nanotubes is 3.04 eV, and it shifts towards the visible light region upon annealing. The X-ray photoelectron spectroscopy (XPS) results show the presence of titania and impurities including chlorine on the surface of the TNTs. The atomic ratio of Ti/O remains unchanged for the annealed TNTs, but the concentration of chlorine decreases with temperature. The photoluminescence (PL) indicate high electron-hole recombination for the as-prepared TNTs, probably due to the residual impurities, low crystallinity, and vacancies in the structure, while the highest photocurrent was observed for the TNT sample annealed at 450 °C. The TNTs induce a small degradation of the dyes under UV light; however, contrary to previous reports, complete decolorization of dyes is observed under sunlight. All TNT samples showed higher decolorization rates under sunlight irradiation than under UV light. The highest reaction rate for the TNT samples was obtained for the as-prepared TNT powder sample under sunlight using RhB (κ1 = 1.29 h−1). This is attributed to the bandgap, specific surface area and the crystal structure of the nanotubes. The as-prepared TNTs performed most efficiently for decolorization of RhB and outperformed the reference anatase powder under sunlight irradiation. This could be attributed to the abundance of reactive sites, higher specific surface area, and degradation mechanism of RhB. These RBA TNT photocatalyst powders demonstrate a more efficient use of the sunlight spectrum, making them viable for environmental remediation.

Tunable core-shell Ag@Mesoporous SiO₂ spheres were synthesized via an in situ modified Stöber approach by varying the amount of ethanol (EtOH) expanding their potentials in many applications. Mesoporous silica was generated by adding tetraethyl orthosilicate (TEOS) to the mixture of colloidal Ag particles prepared by reducing silver nitrate (AgNO₃) with L-ascorbic acid and using hexadecyltrimethylammonium bromide (CTAB) as a template at the presence of ethanol and sodium hydroxide (NaOH) at pH 10 as a catalyst. The average sizes of the Ag cores at the three increasing volumes of ethanol were ~47 ± 6, 36 ± 4, and 11 ± 5 nm, while the silica particle size and the thickness of the silica shells increased, resulting in a blueshift of localized surface plasmon resonances (LSPR) of the Ag NPs. The corresponding specific surface areas of silica particles were 356 ± 10, 419 ± 20 and 490 ± 25 m² g⁻¹, and average pore diameters varied from 5.7, 5.0 to 3.3 nm according to BET and BJH analyses. TEM studies confirmed the core-shell structure, pore sizes and shapes of mesoporous shells. The dissolution tests demonstrated that the release of Ag from the powder samples is pH-sensitive and time-dependent.

Infected superficial wounds were traditionally controlled by topical antibiotics until the emergence of antibiotic-resistant bacteria. Silver (Ag) is a kernel for alternative antibacterial agents to fight this resistance quandary. The present study demonstrates a method for immobilizing small-sized (~5 nm) silver nanoparticles on silica matrix to form a nanosilver–silica (Ag–SiO₂) composite and shows the prolonged antibacterial effects of the composite in vitro. The composite exhibited a rapid initial Ag release after 24 h and a slower leaching after 48 and 72 h and was effective against both methicillin-resistant Staphylococcus aureus (MRSA) and Escherichia coli (E. coli). Ultraviolet (UV)-irradiation was superior to filter-sterilization in retaining the antibacterial effects of the composite, through the higher remaining Ag concentration. A gauze, impregnated with the Ag–SiO₂ composite, showed higher antibacterial effects against MRSA and E. coli than a commercial Ag-containing dressing, indicating a potential for the management and infection control of superficial wounds. Transmission and scanning transmission electron microscope analyses of the composite-treated MRSA revealed an interaction of the released silver ions with the bacterial cytoplasmic constituents, causing ultimately the loss of bacterial membranes. The present results indicate that the Ag–SiO₂ composite, with prolonged antibacterial effects, is a promising candidate for wound dressing applications.