Vincent J. van Hinsberg

Records of volcanic activity are a key resource in volcano monitoring and hazard mitigation. The time period for which such records are available and the level of detail vary widely among volcanic centers and there is, therefore, a need for supplementary sources of this information. Here, we use growth-zoned gypsum as a mineral archive of the activity of Kawah Ijen volcano in East-Java, Indonesia. Gypsum precipitates where water seeps from the crater lake and hydrothermal system, and it has formed a 100 m long cascading plateau. A 19 cm plateau cross-section was analysed for minor and trace elements using laser-ablation ICP-MS. Absolute ages were assigned to this transect based on ²¹⁰Pb dating. This ²¹⁰Pb age model was corrected for variations in the ²¹⁰Pb₀ resulting from fluctuations in the volcanic radon flux by using ⁸⁴Kr/³⁶Ar and ¹³²Xe/³⁶Ar. The age model indicates that the transect covers a period from 1919 ± 12 to 2008 ± 0.2. Gypsum-fluid partition coefficients (D) permit the gypsum compositions to be converted to the concentrations in the fluid from which each growth zone grew. The D-values also show the compatibility of the elements in the gypsum structure, and identify the LREE, Sr, Pb, Tl, Ni, Co, Cu, Zn, Cd, Sb, Th, and Mo as least susceptible to contamination from rock fragment and mineral inclusions, and therefore as most reliable elements of the gypsum record. Compositional variability in the timeseries correlates with known element behavior in the Kawah Ijen system and shows three element groups: the LREE, Sr, and Pb that represent rock-leaching; Cu, Zn, and Cd, which have previously been linked to immiscible sulfide destabilization in a deep-seated basalt; and Sb, Tl, and As which point to a contribution from the shallow system and evolved magma. Moreover, the gypsum record shows that episodes of unrest and quiescence have a distinct compositional signature in Kawah Ijen seepage fluids, and can be distinguished. Thus, we show that gypsum is a sensitive recorder of volcanic activity and can provide detailed information on the state of the magmatic-hydrothermal system in the past.

Alteration in magmatic-hydrothermal systems leads to distinct changes in rock texture and mineralogy, and a strong redistribution of elements between fluid and rock. Here, we experimentally interacted andesite scoria with hyperacidic, high-sulfidation style fluids from Kawah Ijen volcano (Indonesia) at 25 and 100 °C, seeking to reproduce the textures observed in natural samples from this volcano, and to understand the element fluxes that accompany alteration. The susceptibility to alteration in the experiments is Cu–Fe-sulphide > calcic plagioclase > pyroxene > titano-magnetite > sodic plagioclase, with complete preservation of glass. Silicate minerals alter to opaline silica, and gypsum, barite and a Zr-phase precipitate. The selective alteration of the phenocryst minerals results in a preferential release of compatible elements, as the glass is the main incompatible element host. The experiments reproduce the alteration textures of the natural samples, including the preservation of glass, but the predicted compatible over incompatible element enrichment in the alteration element flux is not observed in the natural setting. This suggests that alteration at Kawah Ijen is dominated by lithologies that lack abundant glass, in particular lava flows where the glass has devitrified, despite these lava flows having a lower surface area compared to scoria.

The Tartoq greenstone belt of southwest Greenland represents a well-preserved section through >3 Ga old oceanic crust and has the potential to provide important constraints on the composition and geodynamics of the Archaean crust. Based on a detailed structural examination, it has been proposed that the belt records an early style of horizontal convergent plate tectonics where elevated temperatures, compared to the modern-day, led to repeated aborted subduction and tonalite–trondhjemite–granodiorite (TTG) type melt formation. This interpretation hinges on pressure–temperature (P–T) constraints for the belt, for which only preliminary estimates are currently available. Here, we present a detailed study of the pressure–temperature conditions and metamorphic histories for rocks from all fragments of the Tartoq belt using pseudosection modelling and geothermobarometry. We show that peak conditions are predominantly amphibolite facies, but range from 450 to 800 °C at up to 7.5 kbar; reaching anatexis with formation of TTG-type partial melts in the Bikuben segment. Emplacement of the Tartoq segments into the host TTG gneisses took place at approximately 3 Ga at 450–500 °C and 4 kbar as constrained from actinolite–chlorite–epidote–titanite–quartz parageneses, and was followed by extensive hydrothermal retrogression related to formation of shear zone-hosted gold mineralisation. Tourmaline thermometry and retrograde assemblages in mafic and ultramafic lithologies constrain this event to 380 ± 50 °C at a pressure below 1 kbar. Our results show that the convergent tectonics recorded by the Tartoq belt took place at a P–T gradient markedly shallower than that of modern-day subduction, resulting in a hot, weak and buoyant slab unable to generate and transfer ‘slab pull’, nor sustain a single continuous downgoing slab. The Tartoq belt suggests that convergence was instead accomplished by under-stacking of slabs from repeated aborted subduction. The shallow P–T path combined with thermal relaxation following subduction stalling subsequently resulted in partial melting and formation of TTG melts.