Kelly Morrison

In this article, we show the measurement of the magneto-thermoelectric effect (spin Seebeck and anomalous Nernst effects) of bulk composite pellets prepared from nanopowders of Fe3O4 and Pt. We compare structural, magnetic, and thermoelectric data as the Pt% is increased against a control series of pellets, where sintering temperature and time are varied and a 5 nm layer of Pt is sputtered onto the surface. We also compare the measured thermoelectric efficiency and figure of merit of the composite pellets to our control and a benchmark thin film, where we find an order-of-magnitude increase. This suggests that composite pellets could be a route forward in scaling up the spin Seebeck effect from thin film to bulk.

The NaZn₁₃ type itinerant magnet LaFe_13−xSi_x has seen considerable interest due to its unique combination of large magnetocaloric effect and low hysteresis. Here, this alloy with a combination of magnetometry, bespoke microcalorimetry, and inelastic neutron scattering is investigated. Inelastic neutron scattering reveals the presence of broad quasielastic scattering that persists across the magnetic transition, which is attributed to spin fluctuations. In addition, a quasielastic peak is observed at Q = 0.52 Å⁻¹ for x = 1.2 that exists only in the paramagnetic state in proximity to the itinerant metamagnetic transition and argue that this indicates emergence of a hidden mag the netic phase that drives the first‐order phase transition in this system.

In this study, we demonstrate an enhancement of the measured spin Seebeck coefficient in Fe3O4/Pt bilayer films due to an increase in Fe nanodroplets formed by pulsed laser deposition. Four bilayer films were deposited at the same time from a highly textured target, resulting in a general increase in droplet formation that was confirmed to be Fe rich by scanning electron microscope and transmission electron microscope-dispersive x-ray spectroscopy. Of these four films, there were two distinct groupings with differing density of α-Fe droplets, where the bilayer with higher droplet density exhibited a 64% increase in the measured spin Seebeck coefficient from 38 to 63 nV m/W.

The emergence of thin film CoFeB has driven research and industrial applications in the past decades, with the magnetic random access memory (MRAM) the most prominent example. Because of its beneficial properties, it fulfills multiple functionalities as information-storing, spin-filtering, and reference layer in magnetic tunnel junctions. In future, this versatility can be exploited beyond the traditional applications of spintronics by combining with advanced materials, such as oxide-based materials. Pulsed laser deposition (PLD) is their predominant growth-method, and thus the compatibility of CoFeB with this growth technique will be tested here. This encompasses a comprehensive investigation of the structural and magnetic propoperties. In particular, we find a substantial ‘dead’ magnetic layer and confirm that it is caused by oxidation employing the x-ray magnetic circular dichroism (XMCD) effect. The low damping encountered in vector network analyzer-based ferromagnetic resonance (VNA-FMR) renders them suitable for magnonics applications. These findings demonstrate that CoFeB thin films are compatible with emergent, PLD-grown materials, ensuring their relevance for future applications.

The spin Seebeck effect (SSE) has generated interest in the thermoelectric and magnetic communities for potential high efficiency energy harvesting applications and spintronic communities as a source of pure spin current. Understanding the underlying mechanisms requires characterization of potential materials across a range of temperatures; however, for thin films, the default measurement of an applied temperature gradient (across the sample) has been shown to be compromised by the presence of thermal resistances. Here, we demonstrate a method to perform low temperature SSE measurements where, instead of monitoring the temperature gradient, the heat flux passing through the sample is measured using two calibrated heat flux sensors. This has the advantage of measuring the heat loss through the sample as well as providing a reliable method to normalize the SSE response of thin film samples. We demonstrate this method with an SiO₂/Fe₃O₄/Pt sample where a semiconducting–insulating transition occurs at the Verwey transition, T_V, of Fe₃O₄ and quantify the thermomagnetic response above and below T_V.

The purpose of this study was to evaluate a bespoke spatial measurement methodology using Hall Effect Sensors (HES), i.e., utilizing inductance between a permanent magnet and sensor to indirectly measure the magnet position. The aim is to embed the magnet in a boot’s stud and use an array of sensors in the artificial turf. To evaluate the accuracy and applicability of a HES system in sports turf, two studies were carried out. To measure the spatial position vertically, a standard mechanical dynamic impact testing with the magnet embedded, and the sensors below the turf carpet, was compared to the gold standard optical reference measurement system (GOM UK Ltd.: Coventry, UK) . A second study evaluated the horizontal spatial accuracy for sensors in a variable array with a controlled incremental step movement of the magnet on a precise engineering workshop table.

Separation of the anomalous Nernst and spin Seebeck voltages in bilayer devices is often problematic when both layers are metallic, and the anomalous Nernst effect (ANE) becomes non-negligible. Co₂MnSi, a strong candidate for the spin generator in spin Seebeck devices, is a predicted half-metal with 100% spin polarisation at the Fermi energy, however, typically B2 or L2₁ order is needed to achieve this. We demonstrate the optimisation of thin film growth of Co₂MnSi on glass, where choice of deposition and annealing temperature can promote various ordered states. The contribution from the ANE is then investigated to inform future measurements of the spin Seebeck. A maximum ANE coefficient of 0.662 µV K⁻¹ is found for an A2 disordered polycrystalline Co₂MnSi film. This value is comparable to ordered Heusler thin films deposited onto single crystal substrates but obtained at a far lower fabrication temperature and material cost.

Whilst there have been several reports of the spin Seebeck effect to date, comparison of the absolute voltage(s) measured, in particular for thin films, is limited. In this letter we demonstrate normalization of the spin Seebeck effect for Fe$_3$O$_4$:Pt thin film and YIG:Pt bulk samples with respect to the heat flux J$_q$, and temperature difference $\Delta$T. We demonstrate that the standard normalization procedures for these measurements do not account for an unexpected scaling of the measured voltage with area that is observed in both bulk and thin film. Finally, we present an alternative spin Seebeck coefficient for substrate and sample geometry independent characterization of the spin Seebeck effect.

The spin Seebeck effect (SSE) has been widely studied as a potential mechanism for energy harvesting. However, the efficiency of such devices, utilizing the spin thermoelectric effect in thin film form, has not yet reached a sufficient value to make them economically viable. It is therefore imperative that advances are made to investigate means by which the thermoelectric signal can be enhanced. Multilayers of Co₂MnSi and Pt are fabricated and characterized in an attempt to observe enhanced voltages. We report that bilayers of ferromagnetic conductor/normal metal (FM/NM) exhibit a Longitudinal SSE response and that repetitive stacking of such bilayers results in an increased thermoelectric voltage that is highly dependent upon the quality of CMS/Pt and Pt/CMS interfaces.