Luís Teixeira de Lemos

Cork Liquefaction for Polyurethane Foam Production

Modelling adsorption and desorption processes and equilibrium moisture content of dead fine fuels below fibre saturation is required to provide an accurate prediction of their drying and wetting processes within the range where flammability increases rapidly with decreasing moisture content. Data from laboratory tests on sorption processes and equilibrium moisture content isotherms of dead Pinus pinaster (Ait.) needles were used to evaluate several models applicable to fine forest fuels and agricultural and food products. Laboratory and field data were used to assess model accuracy in predicting drying and wetting curves and equilibrium moisture content isotherms showing a medium to high predictive ability for almost all cases. The best fitting combinations were obtained with the application of agricultural and food products models for drying and wetting phases and fine forest fuel models for equilibrium moisture content determination.

To study the feasibility of co-composting poultry manure with low quantities of high-value, carbon-rich materials experiments to characterize three pilot-scale piles were carried out. The piles comprised poultry manure (pile 1), poultry manure and straw (pile 2) and poultry manure and sawdust (pile 3), using wood chips as bulking agent. Pile 1 presented the highest losses of organic matter and nitrogen contents (≥ 92.9% and 92.0%, respectively). Although a thermophilic phase (temperature > 40 °C) was not verified for this pile, the final compost was stable (class IV) and free of pathogen indicator micro-organisms but it was the most phytotoxic, and presented a humic and fulvic acids ratio (HA/FA) that was less than 1. In contrast, piles 2 and 3 sustained thermophilic phases and produced stable (class V) and mature (HA/FA > 1) composts. Pile 2 showed the lowest loss in nitrogen content (88.9%) and produced the final compost with the highest C/N ratio (14.7) and the lowest value of electrical conductivity (3.9 mS cm^—1). This study showed that it is possible to reduce the costs of poultry manure composting, namely the costs associated with the use of carbon-rich materials, given that the final co-composts presented parameters within the range of those recommended by the Second Draft Proposal for compost quality.