Nikolaos Kostoglou

Metal hydrides remain an intriguing alternative to gaseous and liquid hydrogen storage methods, offering high volumetric storage density and enhanced safety for hydrogen storage at ambient conditions. In this regard, TiFe is one of the most promising storage materials. However, its widespread application remains challenging due to the need for activation, slow initial kinetics, large hysteresis, and high material costs. Overcoming these limitations requires an in‐depth knowledge of the impact of structure and morphology on the sorption properties of TiFe. In this study, we devise a synthesis pathway to prepare nanoporous and ultrafine porous TiFe with controlled grain and ligament sizes, thereby allowing us to correlate these microstructures with their respective sorption properties. We observe that the oxide layers drastically affect sorption properties, particularly in nanoporous TiFe. The detailed analysis of possible mechanisms indicates that a confinement effect becomes relevant, suppressing hydride formation in nanoscale TiFe. These results are supported by an analytical model that allows the calculation of the absorption pressure as a function of microstructure‐dependent elastic stresses. This study lays the groundwork for the systematic study of the processing‐structure‐properties relations in metal hydrides and TiFe in particular, thereby paving the way to cost‐effective and efficient hydrogen storage solutions.

Metal hydrides remain an intriguing alternative to conventional gaseous and liquid hydrogen storage methods, offering high volumetric storage density and enhanced hydrogen storage safety at ambient conditions. In this regard, the intermetallic compound FeTi is one of the most promising storage materials. However, its widespread industrial application remains challenging due to the need for activation, slow initial kinetics, large hysteresis, and high material costs.In this study, we aim to overcome these limitations by devising an alternative synthesis pathway to prepare nanoporous and ultra-fine porous FeTi with controlled grain and ligament sizes, allowing us to study the obtained well-defined microstructures in detail. In particular, we observe the confinement of the FeTi phase by surface oxides, which can be correlated with the hydrogen sorption properties of the respective material. These experimental results are further supported by an analytical model allowing the calculation of the absorption pressure as a function of microstructure-dependent elastic stresses. Additionally, we show that such stresses also influence the absorption-desorption hysteresis.This study lays the groundwork for the controlled and systematic study of the processing-structure-properties relations in metal hydrides and FeTi in particular, thereby paving the way to cost-effective and efficient hydrogen storage solutions based on metal hydrides.

“Quasi-solid-state” conversion mechanisms using sparingly solvating electrolytes (SPSEs) bridge the gap between traditional solid–liquid–solid and solid-state sulfur conversion in lithium–sulfur (Li–S) batteries. Although these terms are commonly used, their precise distinctions and impacts on key performance metrics, such as rate capability, energy density, and capacity fading, remain poorly understood. In this work, we employ operando small- and wide-angle X-ray scattering alongside cryogenic transmission electron microscopy (cryo-TEM) to compare Li–S batteries in sparingly solvating and solvating ether-based electrolytes. We find that, unlike solvating electrolytes, SPSEs lead to an extended presence of lithium sulfide during cycling, coexisting with sulfur at a 50% state of charge and beyond. In the charged state, solid sulfur is present in its amorphous form inside the carbon black nanopores. These findings indicate that the limited solubility confines polysulfides in regions near the carbon surface, where these polysulfides enable conversion between the coexisting solid discharge and charge product.

The increasing demand for sustainable construction materials has driven research into the reuse of plastic waste for renewable building applications. This study introduces a new lightweight insulating mortar for floor and roof systems, utilizing recycled rigid polyurethane (PU) foam as the primary aggregate. The binder mainly consists of Portland cement, with no added sand, and includes minor additives to enhance mechanical, physical, and thermal properties. Initial tests demonstrated that key performance metrics—density, compressive strength, and thermal conductivity—are significantly influenced by the PU content. As the proportion of PU increased, all three parameters decreased. The optimized formulation, comprising 92.25 vol.% PU foam, 6.75 vol.% cement, and 1 vol.% additives, achieved a low bulk density of 420 kg/m³, a compressive strength of 1 MPa, and a thermal conductivity of 0.07 W/m·K. A pilot-scale production system with a capacity of 1500 L/h (equivalent to 20 bags of 75 L) was subsequently designed, implemented, and validated. These findings underscore the potential of PU-based lightweight insulating mortars to reduce environmental impact and support the development of sustainable construction practices globally.

Increasing global energy demand and the need for sustainable energy solutions have sparked significant interest in carbon-based materials for energy conversion and storage