Yang Liu

Dimensionality tuning is an important method to modify the electronic states of quantum materials. However, the mechanism of such tuning in heavy fermion systems and its connection with transport properties remain largely unexplored. Here by combining molecular beam epitaxy, angle-resolved photoemission spectroscopy and transport measurements, we study the electronic states of the heavy-fermion compound CeSi 2 as a function of film thickness. In three-dimensional thick films, our measurements reveal a dispersive Kondo peak at the Fermi level ( E F ) and satellite peaks originating from crystal electric field (CEF) excitations, characteristic of heavy-fermion systems. For two-dimensional ultrathin films, the CEF satellites are largely suppressed while the ground-state Kondo peak at E F remains strong, although it develops at lower temperatures. Simultaneously, the maximum temperature T max of the magnetic resistivity, ρ m ( T ) , changes from ≈ 100 K in thick films to ≈ 35 K in ultrathin films. This can be attributed to the dimensionality-driven reduction of CEF excitations during the Kondo process, in good agreement with spectroscopic results. Our work provides direct insight to understand the quantum confinement effects on strongly correlated 4 f -electron systems and opens up new opportunities to explore emergent phenomena in two-dimensional heavy-fermion materials.

Combining superconductivity with spintronics provides exciting opportunities to realize low-dissipation quantum devices. Here we report the synthesis, characterization and magnetotransport measurements of the Pb/Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ (BSCCO) superconducting heterostructures, where an insulating PbO$_{x}$ layer spontaneously forms at the interface. Non-volatile switching between superconducting (logical "0") and normal ("1") states in Pb films by an external field, i.e., infinite magnetoresistance (IMR), can be realized and are attributed to the strong trapping and pinning of vortices in BSCCO. Furthermore, butterfly-shaped hysteresis loops in magnetoresistance, pronounced resistance dips/jumps and thermal reset to superconducting states can be observed and are direct manifestations of the peculiar vortex dynamics in BSCCO and vortex coupling across the Pb/BSCCO interface. Our work demonstrates a simple and effective way to realize IMR through superconducting vortices and opens up new opportunities to study the vortex interactions across the superconducting interfaces.

The negative thermal expansion (NTE) effect has been found generally combined with structural phase transitions. However, the charge and orbital freedoms of the NTE has not been well studied. This study employs angle-resolved photoemission spectroscopy and first-principles calculations to elucidate the charge and orbital kinetics of the anomalous two-step negative thermal expansion structural phase transitions in PbTa2Se4. As the temperature decreases, each transition undergoes a similar block-layer sliding, although the charge transfer behaviors differ significantly. During the first transition, charge is mainly transferred from the Pb 6pz orbital to an M-shaped band below the Fermi level, barely altering the Fermi surface. In contrast, the second transition involves modifications to both the Fermi surface and charge-transfer orbitals, with charge selectively transferred from Pb 6px/py orbitals to Ta 5dz2 orbitals and a decrease of the Fermi pockets formed by Pb 6px/py orbitals. Furthermore, a small pressure can easily tune the base structure phase among the three phases and the corresponding superconductivity. Therefore, our findings reveal that the orbital-selective charge transfer drives the unusual structure transition in PbTa2Se4, offering new insights into the NTE mechanisms and providing a unique window to study the pressure-tuned superconductivity in this metal-intercalated transition chalcogenides.