Tibor Bedo

Fiber-reinforced composites are gaining more importance across different fields such as aeronautics, automotives, high-performance sporting equipment, etc., where decreasing weight while improving mechanical properties of polymers is fundamental. This article explores the mechanical behavior of fiber-reinforced polyester composite materials, highlighting their advantages and applications in various industrial fields. Usually, composite materials consist of a polyester matrix reinforced with different types of fibers, such as glass, carbon, or Kevlar, which provide superior mechanical characteristics. This study analyzed the tensile strength, bending resistance, and resilience of glass fiber composites, emphasizing the importance of proper fiber selection and manufacturing processes. These materials stand out for their excellent strength-to-weight ratio and are widely used in the fabrication of tanks in various industries. Experimental results demonstrated tensile strength (Rm) around 115 MPa, Shore D hardness values of 88 units, and impact toughness (resilience) of 2.7 J/cm². Based on the composite materials’ behavior in testing, the article further offers practical recommendations for the effective deployment of these composites in the fabrication of various types of industrial reservoirs.

From a scientific point of view, heat transfer is different in solar furnaces compared with classical ones and the influence of direct concentrated solar radiation on sintered parts needs to be studied in detail to determine the feasibility of solar furnaces in manufacturing small workpieces. This study was performed on cylindrical samples with controlled morphology obtained by a powder metallurgy 3D printing technique. All samples were heated with a heating rate of 120 ± 10 °C/minute, with 0, 1, 2, 3, 4 and 5 min holding times at 900 °C and 930 °C. The morphology of the samples was analyzed microscopically, the microhardness was determined before and after sintering, and the results were correlated with the sintering parameters (temperature, heating rate and holding time). The best results were obtained at 930 °C with 5 min holding time from the microhardness value and microstructure point of view.

The continuous development of modern industries rises the necessity for functionally graded materials. This research starts from the consideration that the incorporation of SiC particles in the molten aluminum alloy can be difficult due to the very low wettability of SiC particles. In order to increase their wettability, SiC particles were covered with a layer of metallic copper. The incorporation of SiC particles into the aluminum alloy mass was performed by centrifugal casting. The secondary hypoeutectic Al-Si alloy used in this study was elaborated within the crucible of a resistors heated furnace. The metallic coating of SiC particles, in addition to the effect of increasing their wettability by molten metal, also has a role in preventing the formation of aluminum carbide in case of heating above 700 °C. A great amount of attention was paid to the parameters used during the centrifugal casting process. The results showed that adjusting the proportion of SiC particles within the composite allows us to obtain values of the thermal expansion coefficient within previously established limits. The present work demonstrates that the coating of SiC particles covered with a thin layer of metallic Cu creates the conditions to easily incorporate them into the molten Al mass, thus obtaining FGMs with controlled properties.

The utilization of polymer-based materials is quickly expanding. The enterprises of today are progressively seeking techniques to supplant metal parts with polymer-based materials as a result of their light weight, simple support and modest costs. The ceaselessly developing requirement for composite materials with new or enhanced properties brings about the preparation of different polymer mixes with various arrangements, morphologies and properties. Fused filament fabrication processes such as 3D-printing are nowadays shaping the actual pathway to a full pallet of materials, from art–craft to biomaterials. In this study, the structural and mechanical behavior of three types of commercially available filaments comprised of synthetic poly(acrylonitrile-co-butadiene-co-styrene) (ABS), poly(lactic acid) (PLA) and poly(lactic acid)/polyhydroxyalkanoate reinforced with bamboo wood flour composite (PLA/PHA BambooFill) were assessed through mechanical testing and optical microscopy, aiming to understand how the modifications that occur in the printed models with internal architecture are influencing the mechanical properties of the 3D-printed material. It has been determined that the material printed from PLA presents the highest compression strength, three-point bending and shock resistance, while the ABS shows the best tensile strength performance. A probability plot was used to verify the normality hypothesis of data for the tensile strength, in conjunction with the Anderson–Darling statistic test. The results of the statistic indicated that the data were normally distributed and that there is a marked influence of the internal architecture of the 3D-printed models on the mechanical properties of the printed material.

This paper discusses the structure morphology and the thermal and swelling behavior of physically crosslinked hydrogels, obtained from applying four successive freezing–thawing cycles to poly (vinyl alcohol) blended with various amounts of κ-carrageenan. The addition of carrageenan in a weight ratio of 0.5 determines a twofold increase in the swelling degree and the early diffusion coefficients of the hydrogels when immersed in distilled water, due to a decrease in the crystallinity of the polymer matrix. The diffusion of water into the polymer matrix could be considered as a relaxation-controlled transport (anomalous diffusion). The presence of the sulfate groups determines an increased affinity of the hydrogels towards crystal violet cationic dye. A maximum physisorption capacity of up to 121.4 mg/g for this dye was attained at equilibrium.

The appropriate selection of implant materials is very important for the long-term success of the implants. A modified composition of AISI 316 stainless steel was treated using solar energy in a vertical axis solar furnace and it was subjected to a hyper-hardening treatment at a 1050 °C austenitizing temperature with a rapid cooling in cold water followed by three variants of tempering (150, 250, and 350 °C). After the heat treatment, the samples were analyzed in terms of hardness, microstructure (performed by scanning electron microscopy), and corrosion resistance. The electrochemical measurements were performed by potentiodynamic and electrochemical impedance spectroscopy in liquids that simulate biological fluids (NaCl 0.9% and Ringer’s solution). Different corrosion behaviors according to the heat treatment type have been observed and a passivation layer has formed on some of the heat-treated samples. The samples, heat-treated by immersion quenching, exhibit a significantly improved pitting corrosion resistance. The subsequent heat treatments, like tempering at 350 °C after quenching, also promote low corrosion rates. The heat treatments performed using solar energy applied on stainless steel can lead to good corrosion behavior and can be recommended as unconventional thermal processing of biocompatible materials.

The development of novel Ti-based amorphous or β-phase nanostructured metallic materials could have significant benefits for implant applications, due to improved corrosion and mechanical characteristics (lower Young’s modulus, better wear performance, improved fracture toughness) in comparison to the standardized α+β titanium alloys. Moreover, the devitrification phenomenon, occurring during heating, could contribute to lower input power during additive manufacturing technologies. Ti-based alloy ribbons were obtained by melt-spinning, considering the ultra-fast cooling rates this method can provide. The titanium alloys contain in various proportions Zr, Nb, and Si (Ti₆₀Zr₁₀Si₁₅Nb₁₅, Ti₆₄Zr₁₀Si₁₅Nb₁₁, Ti₅₆Zr₁₀Si₁₅Nb₁₉) in various proportions. These elements were chosen due to their reported biological safety, as in the case of Zr and Nb, and the metallic glass-forming ability and biocompatibility of Si. The morphology and chemical composition were analyzed by scanning electron microscopy and energy-dispersive X-ray spectroscopy, while the structural features (crystallinity, phase attribution after devitrification (after heat treatment)) were assessed by X-ray diffraction. Some of the mechanical properties (hardness, Young’s modulus) were assessed by instrumented indentation. The thermal stability and crystallization temperatures were measured by differential thermal analysis. High-intensity exothermal peaks were observed during heating of melt-spun ribbons. The corrosion behavior was assessed by electrocorrosion tests. The results show the potential of these alloys to be used as materials for biomedical applications.

Rapid solidification with high cooling rates of metal alloys determines both the improvement of mechanical properties, due to the finishing of the structure, as well as obtaining metastable structures in the form of supersaturated or amorphous/nano solid solutions, which could potentially confer the material outstanding properties. It is of particular interest to use the energies released during the heating stage for these materials, due to the potentially lower input energy required to melt/fuse these materials. This phenomenon could add to the development and diversification of additive manufacturing technologies. The paper presents results concerning the structural development and phase transformation of metastable structures from Al–Si–Ni-based alloys, obtained by melt spinning and atomization techniques. It was observed that the structural transformations occurring during the heating process, starting from metastable structures, generate significant amounts of energy. This is of practical importance in the use of metallic powders in additive manufacturing technology, due to potentially reduced energy input.

Three‐dimensional (3D) printing processes are nowadays leading the charge in transforming traditional art, engineering, and manufacturing processes. In this study, the structural and thermal behavior of commercially available filaments composed of synthetic poly(acrylonitrile‐co‐butadiene‐co‐styrene) thermoplastic as well as poly(lactic acid) and poly(lactic acid)/polyhydroxyalcanoate reinforced with bamboo (Bambusa sp.) wood flour composite biothermoplastics were assessed by differential scanning calorimetry and infrared spectroscopy, aiming to understand the modifications that occur at the molecular level during their 3D printing. It has been determined that the biothermoplastic materials undergo both molecular reorientations related to tacticity increase and crystallinity decrease when submitted to 3D printing extrusion, while the synthetic thermoplastic undergoes crosslinking due to its butadiene component. All of the studied materials present good water stability (with water uptake values between 0.8% and 24%), and the water absorption follows a pseudo‐Fickian mechanism. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2019.