Edisson Morgado

Free –NH ₂ groups can be optimized by proper APTES-grafting on the titanate nanotube surface, increasing CO ₂ adsorption capacity under DAC conditions.

Hybrid perovskites, materials composed of metals and organic substances in their structure, have emerged as potential materials for the new generation of photovoltaic cells due to a unique combination of optical, excitonic and electrical properties. Inspired by sensitization techniques on TiO₂ substrates (DSSC), CH₃NH₃PbBr₃ and CH₃NH₃PbI₃ perovskites were studied as a light-absorbing layer as well as an electron–hole pair generator. Photovoltaic cells based on per-ovskites have electron and hole transport layers (ETL and HTL, respectively), separated by an ac-tive layer composed of perovskite itself. Major advances subsequently came in the preparation methods of these devices and the development of different architectures, which resulted in an efficiency exceeding 23% in less than 10 years. Problems with stability are the main barrier to the large-scale production of hybrid perovskites. Partially or fully inorganic perovskites appear promising to circumvent the instability problem, among which the black perovskite phase CsPbI₃ (α-CsPbI₃) can be highlighted. In more advanced studies, a partial or total substitution of Pb by Ge, Sn, Sb, Bi, Cu or Ti is proposed to mitigate potential toxicity problems and maintain device efficiency.

The improvement of photocatalytic activity of TiO₂-based nanomaterials is widely investigated due to the tentative of their industrialization as environmental photocatalysts and their inherently low solar spectrum sensitivity and rapid recombination of charge carriers. Coupling of oxygen-based bidentate diketone to nanocrystalline TiO₂ represents a potential alternative for improving the holdbacks. Formation of TiO₂-acetylacetone charge transfer complex (CTC) by sol-gel route results in a hybrid semiconductor material with photodegradation activity against toxic NO_x gas. In this research, the influence of the chelating agent acetylacetone (ACAC) content on the CTC photocatalytic efficiency under visible light was evaluated. A high content of ACAC in the CTC is not a decisive factor for efficiency of photocatalytic reactions. In fact, the highest efficiency for NO_x degradation (close to 100%, during 1 h of visible light exposure) was reported for the material calcined in air at 300 °C with the content of strongly bonded acetylacetone not higher than 3 wt.%. Higher calcination temperature (400 °C) left TiO₂ almost completely depleted in ACAC, while at the highest applied temperature (550 °C) a portion of anatase was transformed into rutile and the sample is free of ACAC. The analyses pointed out that superoxide anion radical (O₂⁻) plays an active role in photo-oxidation of NO_x. Our findings indicate that this CTC has both high visible light spectral sensitivity and photocatalytic efficiency.

H-trititanate nanotubes obtained by alkali hydrothermal treatment of TiO(2) followed by proton exchange were compared to their bulk H(2)Ti(3)O(7) counterpart with respect to their thermally induced structural transformation paths. As-synthesized and heat-treated samples were characterized by XRD, TEM/SAED, DSC and spectroscopy techniques, indicating that H(2)Ti(3)O(7) nanotubes showed the same sequence of structural transformations as their bulk counterpart obtained by conventional solid state reaction. Nanostructured H(2)Ti(3)O(7) converts into TiO(2)(B) via multistep transformation without losing its nanotubular morphology. The transformation occurs between 120 and 400 degrees C through topotactic mechanisms with the intermediate formation of nanostructured H(2)Ti(6)O(13) and H(2)Ti(12)O(25), which are more condensed layered titanates eventually rearranging to TiO(2)(B). Our results suggest that the intermediate tunnel structure H(2)Ti(12)O(25) is the final layered intermediate phase, on which TiO(2)(B) nucleates and grows. The conversion of nanostructured TiO(2)(B) into anatase is completed at a much lower temperature than its bulk counterpart and is accompanied by loss of the nanotubular morphology.