Lydia J. Hallis

Hydrous apatite in the nakhlite group of martian meteorites shows evidence of Cl-rich fluid incorporation into the magma prior to apatite crystallisation. Thus, nakhlite apatite D/H ratios should reflect a mixture between the parental magma and this crustally derived fluid. Here we present the volatile content and D/H ratios of apatite within the nakhlite Lafayette (δD 137 to 352‰), suggesting mixing between a crustally derived Cl-rich fluid and an intermediate D/H ratio (δD ≈ 400‰) and a magma with a low D/H ratio (δD ≈ −100‰). This martian mantle D/H ratio is similar to that of Earth’s upper mantle, but is higher than recent D/H ratios measured within a number of other inner Solar System materials. Thus, D/H ratio heterogeneity in these materials points towards multiple sources of hydrogen during the formation of rocky planetary bodies in the inner Solar System.

The Mighei‐like carbonaceous (CM) chondrites have been altered to various extents by water–rock reactions on their parent asteroid(s). This aqueous processing has destroyed much of the primary mineralogy of these meteorites, and the degree of alteration is highly heterogeneous at both the macroscale and nanoscale. Many CM meteorites are also heavily brecciated juxtaposing clasts with different alteration histories. Here we present results from the fine‐grained team consortium study of the Winchcombe meteorite, a recent CM chondrite fall that is a breccia and contains eight discrete lithologies that span a range of petrologic subtypes (CM2.0–2.6) that are suspended in a cataclastic matrix. Coordinated multitechnique, multiscale analyses of this breccia reveal substantial heterogeneity in the extent of alteration, even in highly aqueously processed lithologies. Some lithologies exhibit the full range and can comprise nearly unaltered coarse‐grained primary components that are found directly alongside other coarse‐grained components that have experienced complete pseudomorphic replacement by secondary minerals. The preservation of the complete alteration sequence and pseudomorph textures showing tochilinite–cronstedtite intergrowths are replacing carbonates suggest that CMs may be initially more carbonate rich than previously thought. This heterogeneity in aqueous alteration extent is likely due to a combination of microscale variability in permeability and water/rock ratio generating local microenvironments as has been established previously. Nevertheless, some of the disequilibrium mineral assemblages observed, such as hydrous minerals juxtaposed with surviving phases that are typically more fluid susceptible, can only be reconciled by multiple generations of alteration, disruption, and reaccretion of the CM parent body at the grain scale.

We have determined the global inventory of surface and near‐surface water on Mars by tracking the amounts of water lost to each of the significant sinks for water. The sinks include loss to space, formation of hydrated minerals, possible remnants of an ancient ocean, water present within the crust, and the present‐day polar caps and near‐surface ice deposits; we utilize both previous analyses and new analyses of the amount of water in the sinks. Summed up, they total 380–970 m H₂O (as a global equivalent layer), and possibly up to 685–1,970 m if possible crustal liquid water or ice is included. For comparison, the Earth's surface and near‐surface inventory, scaled to Mars, would be 1,400 m. This value for an Earth‐like Mars falls within the range of possible values for Mars, suggesting that Mars had a similar surface inventory of surface and near‐surface water. This abundance of water on early Mars is able to produce the observed water‐related geological features and suggests the presence of an early habitable environment capable of supporting life.

CM carbonaceous chondrites can be used to constrain the abundance and H isotopic composition of water and OH in C‐complex asteroids. Previous measurements of the water/OH content of the CMs are at the higher end of the compositional range of asteroids as determined by remote sensing. One possible explanation is that the indigenous water/OH content of meteorites has been overestimated due to contamination during their time on Earth. Here we have sought to better understand the magnitude and rate of terrestrial contamination through quantifying the concentration and H isotopic composition of telluric and indigenous water in CM falls by stepwise pyrolysis. These measurements have been integrated with published pyrolysis data from CM falls and finds. Once exposed to Earth's atmosphere CM falls are contaminated rapidly, with some acquiring weight percent concentrations of water within days. The amount of water added does not progressively increase with time because CM falls have a similar range of adsorbed water contents to finds. Instead, the petrologic types of CMs strongly influence the amount of terrestrial water that they can acquire. This relationship is probably controlled by mineralogical and/or petrophysical properties of the meteorites that affect their hygroscopicity. Irrespective of the quantity of water that a sample adsorbs or its terrestrial age, there is minimal exchange of H in indigenous phyllosilicates with the terrestrial environment. The falls and finds discussed here contain 1.9–10.5 wt% indigenous water (average 7.0 wt%) that is consistent with recent measurements of C‐complex asteroids including Bennu.

The Mars 2020/Mars Sample Return (MSR) Sample Depot Science Community Workshop was held on September 28 and 30, 2022, to assess the Scientifically‐Return Worthy (SRW) value of the full collection of samples acquired by the rover Perseverance at Jezero Crater, and of a proposed subset of samples to be left as a First Depot at a location within Jezero Crater called Three Forks. The primary outcome of the workshop was that the community is in consensus on the following statement: The proposed set of ten sample tubes that includes seven rock samples, one regolith sample, one atmospheric sample, and one witness tube constitutes a SRW collection that: (1) represents the diversity of the explored region around the landing site, (2) covers partially or fully, in a balanced way, all of the International MSR Objectives and Samples Team scientific objectives that are applicable to Jezero Crater, and (3) the analyses of samples in this First Depot on Earth would be of fundamental importance, providing a substantial improvement in our understanding of Mars. At the conclusion of the meeting, there was overall community support for forming the First Depot as described at the workshop and placing it at the Three Forks site. The community also recognized that the diversity of the Rover Cache (the sample collection that remains on the rover after placing the First Depot) will significantly improve with the samples that are planned to be obtained in the future by the Perseverance rover and that the Rover Cache is the primary target for MSR to return to Earth.

The Winchcombe meteorite fell on February 28, 2021 and was the first recovered meteorite fall in the UK for 30 years, and the first UK carbonaceous chondrite. The meteorite was widely observed by meteor camera networks, doorbell cameras, and eyewitnesses, and 213.5 g (around 35% of the final recovered mass) was collected quickly—within 12 h—of its fall. It, therefore, represents an opportunity to study very pristine extra‐terrestrial material and requires appropriate careful curation. The meteorite fell in a narrow (600 m across) strewn field ~8.5 km long and oriented approximately east–west, with the largest single fragment at the farthest (east) end in the town of Winchcombe, Gloucestershire. Of the total known mass of 602 g, around 525 g is curated at the Natural History Museum, London. A sample analysis plan was devised within a month of the fall to enable scientists in the UK and beyond to quickly access and analyze fresh material. The sample is stored long term in a nitrogen atmosphere glove box. Preliminary macroscopic and electron microscopic examinations show it to be a CM2 chondrite, and despite an early search, no fragile minerals, such as halite, sulfur, etc., were observed.

The rapid recovery of the Winchcombe meteorite offers a valuable opportunity to study the soluble organic matter (SOM) profile in pristine carbonaceous astromaterials. Our interests in the biologically relevant molecules, amino acids—monomers of protein, and the most prevalent meteoritic organics—polycyclic aromatic hydrocarbons (PAHs) are addressed by analyzing the solvent extracts of a Winchcombe meteorite stone using gas chromatography mass spectrometry. The Winchcombe sample contains an amino acid abundance of ~1132 parts‐per‐billion that is about 10 times lower than other CM2 meteorites. The detection of terrestrially rare amino acids, including α‐aminoisobutyric acid (AIB); isovaline; β‐alanine; α‐, β‐, and γ‐amino‐n‐butyric acids; and 5‐aminopentanoic acid, and the racemic enantiomeric ratios (D/L = 1) observed for alanine and isovaline indicate that these amino acids are indigenous to the meteorite and not terrestrial contaminants. The presence of predominantly α‐AIB and isovaline is consistent with their formation via the Strecker‐cyanohydrin synthetic pathway. The L‐enantiomeric excesses in isovaline previously observed for aqueously altered meteorites were viewed as an indicator of parent body aqueous processing; thus, the racemic ratio of isovaline observed for Winchcombe, alongside the overall high free:total amino acid ratio, and the low amino acid concentration suggest that the analyzed stone is derived from a lithology that has experienced brief episode(s) of aqueous alteration. Winchcombe also contains 2‐ to 6‐ring alkylated and nonalkylated PAHs. The low total PAHs abundance (6177 ppb) and high nonalkylated:alkylated ratio are distinct from that observed for heavily aqueously altered CMs. The weak petrographic properties of Winchcombe, as well as the discrepancies observed for the Winchcombe SOM content—a low total amino acid abundance comparable to heavily altered CMs, and yet the high free:total amino acid and nonalkylated:alkylated PAH ratios are on par with the less altered CMs—suggest that Winchcombe could represent a class of weak, poorly lithified meteorite not been previously studied.

Direct links between carbonaceous chondrites and their parent bodies in the solar system are rare. The Winchcombe meteorite is the most accurately recorded carbonaceous chondrite fall. Its pre-atmospheric orbit and cosmic-ray exposure age confirm that it arrived on Earth shortly after ejection from a primitive asteroid. Recovered only hours after falling, the composition of the Winchcombe meteorite is largely unmodified by the terrestrial environment. It contains abundant hydrated silicates formed during fluid-rock reactions, and carbon- and nitrogen-bearing organic matter including soluble protein amino acids. The near-pristine hydrogen isotopic composition of the Winchcombe meteorite is comparable to the terrestrial hydrosphere, providing further evidence that volatile-rich carbonaceous asteroids played an important role in the origin of Earth’s water.

Abiotic formation of organic molecules: Mars rovers have found complex organic molecules in the ancient rocks exposed on the planet’s surface and methane in the modern atmosphere. It is unclear what processes produced these organics, with proposals including both biotic and abiotic sources. Steele et al . analyzed the nanoscale mineralogy of the Mars meteorite ALH 84001 and found evidence of organic synthesis driven by serpentinization and carbonation reactions that occurred during the aqueous alteration of basalt rock by hydrothermal fluids. The results demonstrate that abiotic production of organic molecules operated on Mars 4 billion years ago. —KTS