Gabriel Búrdalo-Salcedo

Rainfall simulators are crucial devices in erosion research, enabling the controlled reproduction of precipitation characteristics for both laboratory and field investigations. This study presents a comprehensive characterization of a rainfall simulator originally designed to assess the erosive effects of precipitation on heritage surfaces. The simulator, installed at the University of León, was evaluated using volumetric methods and disdrometric techniques, employing a Parsivel² optical disdrometer. Simulations were conducted with a falling height of 10 m and high-intensity rainfalls. Spatial uniformity was assessed through thematic mapping and the Christiansen Uniformity (CU) coefficient, revealing limited uniformity across the full wetted area, but an improved performance within the central zone (CU up to 80%). Disdrometric data provided detailed insights into drop size and velocity distributions, enabling the estimation of rainfall intensity, kinetic energy, and momentum, as well as the spatial uniformity of the energetic parameters. Empirical models to estimate the raindrop’s fall velocity were tested against disdrometric measurements, confirming the simulator’s ability to generate rainfall with velocity characteristics comparable to those of natural precipitation. Moreover, the findings underscore the importance of integrating multiple measurement approaches to enhance the reliability and accuracy of rainfall simulator characterization.

Given the urgent need to decarbonize the global energy system, green hydrogen has emerged as a key alternative in the transition to renewables. However, its production via electrolysis demands high water quality and raises environmental concerns, particularly regarding reject water discharge. This study employs an experimental and analytical approach to define optimal water characteristics for electrolysis, focusing on conductivity as a key parameter. A pilot water treatment plant with reverse osmosis and electrodeionization (EDI) was designed to simulate industrial-scale pretreatment. Twenty water samples from diverse natural sources (surface and groundwater) were tested, selected for geographical and geological variability. A predictive algorithm was developed and validated to estimate useful versus reject water based on input quality. Three conductivity-based categories were defined: optimal (0–410 µS/cm), moderate (411–900 µS/cm), and restricted (>900 µS/cm). Results show that water quality significantly affects process efficiency, energy use, waste generation, and operating costs. This work offers a technical and regulatory framework for assessing potential sites for green hydrogen plants, recommending avoidance of high-conductivity sources. It also underscores the current regulatory gap regarding reject water treatment, stressing the need for clear environmental guidelines to ensure project sustainability.

The development of sustainable cementitious materials is crucial to reduce the environmental footprint of the construction industry. Alkali-activated materials (AAMs) have emerged as promising environmentally friendly alternatives; however, their compatibility with natural stone in heritage structures remains poorly understood, especially regarding salt migration and related damage to stones. This study presents a novel methodology for assessing salt movement in solid materials between two types of stones—Boñar and Silos—and two types of binders: blended Portland cement (BPC) and an AAM. The samples underwent capillarity and immersion tests to evaluate water absorption, salt transport, and efflorescence behavior. The capillarity of the Silos stone was 0.148 kg·m⁻²·t^−0.5, whereas this was 0.0166 kg·m⁻²·t^−0.5 for the Boñar stone, a ninefold difference. Conductivity mapping and XRD analysis revealed that AAM-based mortars exhibit a significantly higher release of salts, primarily sodium sulfate, which may pose a risk to adjacent porous stones. In contrast, BPC showed lower salt mobility and different salt compositions. These findings highlight the importance of evaluating the compatibility between alternative binders and heritage stones. The use of AAMs may pose significant risks due to their tendency to release soluble salts. Although, in the current experiments, no pore damage or mechanical degradation was observed, additional studies are required to confirm this. A thorough understanding of salt transport mechanisms is therefore essential to ensure that sustainable restoration materials do not inadvertently accelerate the deterioration of structures, a process more problematic when the deterioration affects heritage monuments.

The historical stone heritage that we inherit must be passed on to future generations, not only in the same conditions that we found it but, if possible, in better ones. Construction also demands better and more durable materials, often stone. The protection of these materials requires knowledge of the types of rocks and their physical properties. The characterization of these properties is often standardized to ensure the quality and reproducibility of the protocols. These must be approved by entities whose purpose is to improve the quality and competitiveness of companies and to protect the environment. Standardized water absorption tests could be envisaged to test the effectiveness of certain coatings in protecting natural stone against water penetration, but we found that some steps of these protocols neglect any surface modification of the stones, and hence may not be completely effective when a hydrophilic protective coating (i.e., graphene oxide) is present. In this work, we analyze the UNE 13755/2008 standard for water absorption and propose alternative steps to adapt the norm for use with coated stones. The properties of coated stones may invalidate the interpretation of the results if the standard protocol is applied as is, so here we pay special attention to the characteristics of the coating applied, the type of water used for the test, the materials used, and the intrinsic heterogeneity of the specimens.

Acid rain is a problem that despite efforts to reduce atmospheric pollution, continues to impact not only countries where there is a high production of pollutants, but also transboundary areas to which the pollutants are transported. In addition to its effects on human health, there are also the effects on infrastructure and the consequences that this entails. This study on the effect of rain and acid rain on calcareous materials highlights the need for protection of buildings constructed from these materials, many of which are part of the cultural heritage. The effects caused by rain and acid rain were studied using a rain simulator whose features allow the simulation of natural conditions as realistically as possible. In the same way, the effect of a coating synthesized from nanomaterials, which has been shown to serve as protection against the degradation caused by rain, was analyzed. In addition to a long-lasting protection of the stone material, this type of coating avoids the need for the replacement of elements and the recurrent cleaning of degraded parts. It also avoids the accumulation of parts on the ground, the transport of personnel, work materials and raw materials, thereby contributing to the reduction of the carbon footprint and water savings, which in turn reduces the production of pollutants that cause acid rain.

The importance of understanding the effects of rainfall on different materials over time makes it essential to carry out controlled tests to reduce analysis time. Rainfall simulators have been in use for decades and have been implemented as technology and knowledge of the physical behavior of water advanced. There are two main types of rainfall simulators: gravity simulators and pressure simulators. In the former, the drop velocity is normally smaller than the terminal velocity reached by natural droplets; in the latter, the drop size is too small to be representative and has far more speed than the natural speed for those sizes. To solve this problem, a simulator has been developed where the terminal velocity of the raindrops is reached and the drop size can be varied by different nozzles of variable sizes, adapting it to the conditions of a given region. In this study, conditions similar to the rainfall conditions of the city of León have been achieved. This paper presents the design of a rainfall simulator that recreates different rainfall conditions and rainwater composition and its calibration process.

University education in times of COVID-19 was forced to seek alternative teaching/learning methods to the traditional ones, having to abruptly migrate to the online modality, changes that have repercussions on student satisfaction. That is why this study aims to compare the level of student satisfaction in face-to-face and “forced” online modalities under COVID-19. A quantitative, cross-sectional methodology was applied to two groups of students: Under a face-to-face modality (n = 116) and under an online modality (n = 120), to which a questionnaire was applied under a Likert scale, with four dimensions: Course design structure, content, resources, and instructor. Non-parametric statistics, specifically the Mann–Whitney U-test, were used to compare the groups. The results showed that there are significant differences in the level of satisfaction of students in the face-to-face and online “forced” modalities (p = 0.01984 < 0.05), and the dimensions of the level of satisfaction that presented significant differences were course design structure (p = 0.04523 < 0.05) and content (p = 0.00841 < 0.05). The research shows that students in the face-to-face modality express a higher level of satisfaction, which is reflected in the dimension design structure of the course, specifically in its workload indicator, as well as in the dimension content, in its indicators, overlapping with other courses and materials.

Most concrete studies are concentrated on mechanical properties especially strength properties either directly or indirectly (fresh and durability properties). Hence, the ratio of split tensile strength to compressive strength plays a vital role in defining the concrete properties. In this review, the impact of design parameters on the strength ratio of various grades of Self-Compacting Concrete (SCC) with recycled aggregate is assessed. The design parameters considered for the study are Water to Cement (W/C) ratio, Water to Binder (W/B) ratio, Total Aggregates to Cement (TA/C) ratio, Fine Aggregate to Coarse Aggregate (FA/CA) ratio, Water to Solid (W/S) ratio in percentage, superplasticizer (SP) content (kg/cu.m), replacement percentage of recycled coarse aggregates (RCA), replacement percentage of recycled fine aggregates (RFA), fresh density and loading area of the specimen. It is observed that the strength ratio of SCC with recycled aggregates is affected by design parameters.