Feizhou He

A hallmark of many unconventional superconductors is the presence of many-body interactions that give rise to broken-symmetry states intertwined with superconductivity. Recent resonant soft X-ray scattering experiments report commensurate 3a₀ charge density wave order in infinite-layer nickelates, which has important implications regarding the universal interplay between charge order and superconductivity in both cuprates and nickelates. Here we present X-ray scattering and spectroscopy measurements on a series of NdNiO_2+x samples, which reveal that the signatures of charge density wave order are absent in fully reduced, single-phase NdNiO₂. The 3a₀ superlattice peak instead originates from a partially reduced impurity phase where excess apical oxygens form ordered rows with three-unit-cell periodicity. The absence of any observable charge density wave order in NdNiO₂ highlights a crucial difference between the phase diagrams of cuprate and nickelate superconductors.

Superconductivity and charge density waves (CDWs) are competitive, yet coexisting, orders in cuprate superconductors. To understand their microscopic interdependence, a probe capable of discerning their interaction on its natural length and time scale is necessary. We use ultrafast resonant soft x-ray scattering to track the transient evolution of CDW correlations in YBa ₂ Cu ₃ O _{6+ x} after the quench of superconductivity by an infrared laser pulse. We observe a nonthermal response of the CDW order characterized by a near doubling of the correlation length within ≈1 picosecond of the superconducting quench. Our results are consistent with a model in which the interaction between superconductivity and CDWs manifests inhomogeneously through disruption of spatial coherence, with superconductivity playing the dominant role in stabilizing CDW topological defects, such as discommensurations.

Significance: Understanding the character of the enigmatic pseudogap phase is a fundamental problem in the physics of the cuprate superconductors. Key to this problem is identifying what types of order, if any, are associated with pseudogap. Here, we establish using resonant X-ray scattering that electronic nematicity—a rotational symmetry breaking of the electronic structure—is linked to the onset of the pseudogap phase in the cuprate La 1.6 − x Nd 0.4 Sr x CuO 4 (Nd-LSCO). We report vanishing of electronic nematicity either by raising the temperature through the onset of the pseudogap phase or by increasing hole doping through the pseudogap critical point, indicating that electronic nematic order is intimately tied to the pseudogap.

In strongly correlated systems the strength of Coulomb interactions between electrons, relative to their kinetic energy, plays a central role in determining their emergent quantum mechanical phases. We perform resonant x-ray scattering on Bi₂Sr₂CaCu₂O_8+δ, a prototypical cuprate superconductor, to probe electronic correlations within the CuO₂ plane. We discover a dynamic quasi-circular pattern in the x-y scattering plane with a radius that matches the wave vector magnitude of the well-known static charge order. Along with doping- and temperature-dependent measurements, our experiments reveal a picture of charge order competing with superconductivity where short-range domains along x and y can dynamically rotate into any other in-plane direction. This quasi-circular spectrum, a hallmark of Brazovskii-type fluctuations, has immediate consequences to our understanding of rotational and translational symmetry breaking in the cuprates. We discuss how the combination of short- and long-range Coulomb interactions results in an effective non-monotonic potential that may determine the quasi-circular pattern.

Titanium monoxide (TiO), an important member of the rock salt 3d transition-metal monoxides, has not been studied in the stoichiometric single-crystal form. It has been challenging to prepare stoichiometric TiO due to the highly reactive Ti²⁺. We adapt a closely lattice-matched MgO(001) substrate and report the successful growth of single-crystalline TiO(001) film using molecular beam epitaxy. This enables a first-time study of stoichiometric TiO thin films, showing that TiO is metal but in proximity to Mott insulating state. We observe a transition to the superconducting phase below 0.5 K close to that of Ti metal. Density functional theory (DFT) and a DFT-based tight-binding model demonstrate the extreme importance of direct Ti–Ti bonding in TiO, suggesting that similar superconductivity exists in TiO and Ti metal. Our work introduces the new concept that TiO behaves more similar to its metal counterpart, distinguishing it from other 3d transition-metal monoxides.

Resonant x-ray scattering in YBCO reveals s -symmetry charge order along the b axis but charge/orbital order along the a axis.

Point defects, such as oxygen vacancies, control the physical properties of complex oxides, relevant in active areas of research from superconductivity to resistive memory to catalysis. In most oxide semiconductors, electrons that are associated with oxygen vacancies occupy the conduction band, leading to an increase in the electrical conductivity. Here we demonstrate, in contrast, that in the correlated-electron perovskite rare-earth nickelates, RNiO₃ (R is a rare-earth element such as Sm or Nd), electrons associated with oxygen vacancies strongly localize, leading to a dramatic decrease in the electrical conductivity by several orders of magnitude. This unusual behavior is found to stem from the combination of crystal field splitting and filling-controlled Mott–Hubbard electron–electron correlations in the Ni 3d orbitals. Furthermore, we show the distribution of oxygen vacancies in NdNiO₃ can be controlled via an electric field, leading to analog resistance switching behavior. This study demonstrates the potential of nickelates as testbeds to better understand emergent physics in oxide heterostructures as well as candidate systems in the emerging fields of artificial intelligence. Significance Oxygen vacancies and their associated electrons, ubiquitous in oxide materials, can lead to emergent phenomena. Control of these vacancies allows the manipulation and exploitation of such properties. Using an ultralow oxygen partial pressure environment, we are able to systematically control the oxygen vacancy concentration in thin films of rare-earth nickelates. We find that oxygen vacancies lead to strong carrier localization arising from Ni valence reduction to 2+, resulting in an increase of room-temperature electrical resistivity by several orders of magnitude while maintaining the perovskite structure throughout. The oxygen vacancies can be redistributed by electric fields, leading to analog resistance behavior.