Marek Dziubiński

The subject of the research was limestone hydromixture consisting of particles of a mean size of 45.5 μm conveyed by water in a pipeline of a total length of 632 m. In the paper, the results of rheological measurements of tested hydromixtures after the application of deflocculant consisting of waste product from the lime production process in the form of mineral particles and commonly known dispersant were presented. Calculations of pressure drop including hydromixtures with volume concentrations in the range of 21.30–50.00%, and density ranging from 1140–1410 kg/m³ in a pipeline of 200 mm diameter are presented. A decrease in friction losses in the flow in the pipeline of hydromixtures with different mass concentrations after the addition of deflocculant was observed. The study revealed that the addition of deflocculant resulted in a reduction of friction in the pipeline, enabling the pumping of hydromixtures with twice higher solids concentrations than originated from industrial installation, with a lower volumetric flow rate. This resulted in a decrease of the power consumption of the motor driving the pump, and obtained significant energy savings in the hydromixture transport process. The maximum energy saving achieved was equal to 58%.

The task of fire pressure differential systems in a building is to prevent smoke from entering protected spaces such as stairwells and areas that should remain smoke-free in the event of fire. The required overpressure must consider leakage within the protected space. This article presents the results of testing to determine the impact of leakage of the protected space on the conditions for maintaining overpressure. The research was conducted in accordance with draft standard N161-prEN12101-6. The pressure distribution as a function of time was obtained for stairwells with different levels of leakage, using a constant flow aeration fan as well as systems with a variable airflow. Practical application: Designers of differential pressure smoke control systems are required to calculate aeration fan airflow volume. The leakage level of protected spaces should be taken into consideration given that European Standard EN12101-6 suggests that gap areas should be minimal. Consequently, modern building design and construction requires estimation of the leakage area in such protected spaces. The objective is to improve safety of buildings and reduce the system reaction time during a fire.

The presented work describes the method of preparation of thermosensitive chitosan hydrogels using calcium β-glycerophosphate salt as the only pH neutralizing agent and supporting the crosslinking process. The presence of calcium ions instead of sodium ions is particularly important in the case of scaffolds in bone tissue engineering. Rheological and physicochemical properties of low concentrated chitosan solutions with the addition of calcium β-glycerophosphate were investigated using rotational rheometry techniques, Zeta potential (by electrophoresis), XPS, and SEM analysis together with an EDS detector. It was found to be possible to prepare colloidal solutions of chitosan containing only calcium β-glycerophosphate (without sodium ions) undergoing a sol-gel phase transition at the physiological temperature of the human body. It has also been shown that it is possible to further enrich the obtained cellular scaffolds with calcium ions. Using the addition of calcium carbonate, hydrogels with a physiological ratio of calcium to phosphorus (1.6–1.8):1 were obtained.

In the recent studies on chitosan hydrogels, it was found that understanding both rheological and structural properties plays an important role in their application. Therefore, a combination of two independent techniques was applied to investigate micro- and macroscopic properties of chitosan colloidal system. Studies on viscous properties, as well as the sol-gel phase transition process, were performed using rheological methods coupled with the small angle light scattering (SALS) technique. Based on the anisotropy of scattering patterns obtained during rotational shear tests, it was found that the chitosan solution reveals two different behaviors delimited by the critical value of the shear rate. Below a critical value, chitosan clusters are deformed without breaking up aggregates, whereas after exceeding a critical value, chitosan clusters apart from deformation also breakup into smaller aggregates. The values of the radius of gyration determined by applying the Debye function allow one to state that with an increase of chitosan concentration, molecule size decreases. An analysis of the light scattering data from the temperature ramp test showed that with an increase of temperature, the level of polymer coil swelling increases. Simultaneously, the supply of thermal energy leads to a neutralization of the charge of chitosan chains. As a consequence, the formation of intermolecular links occurs and a gel structure is formed.

Chitosan colloidal systems, created by dispersing in aqueous solutions of hydrochloric acid, with and without the addition of disodium β-glycerophosphate (β-NaGP), were prepared for the investigation of forming mechanisms of chitosan hydrogels. Three types of chitosan were used in varying molecular weights. The impacts of the charge and shape of the macromolecules on the phase transition process were assessed. The chitosan system without the addition of β-NaGP was characterized by stiff and entangled molecules, in contrast to the chitosan system with the addition of β-NaGP, wherein the molecules adopt a more flexible and disentangled form. Differences in molecules shapes were confirmed using the Zeta potential and thixotropy experiments. The chitosan system without β-NaGP revealed a rapid nature of phase transition—consistent with diffusion-limited aggregation (DLA). The chitosan system with β-NaGP revealed a two-step nature of phase transition, wherein the first step was consistent with reaction-limited aggregation (RLA), while the second step complied with diffusion-limited aggregation (DLA).