Roberto Menezes Serra

Allowing the order of quantum operations to exist in superposition is known to open new routes for thermodynamic tasks. We investigate a quantum heat engine where energy exchanges are driven by generalized measurements, and the sequence of these operations is coherently controlled in a superposition of causal orders. Our analysis explores how initial correlations between the working medium and the controller affect the engine's performance. Considering uncorrelated, classically correlated, and entangled initial states, we show that entanglement enables the superposed causal order to generate coherence in the working medium, thereby enhancing work extraction and efficiency beyond the separable and uncorrelated cases. Finally, we present a proof-of-principle simulation on the IBM Quantum Experience platform, realizing a quantum switch of two measurement channels with tunable strengths and experimentally confirming the predicted efficiency enhancement enabled by correlation-assisted superposed causal order.

Coherence is an inherently quantum property that deeply affects microscopic processes, including thermalization phenomena. A striking example is the quantum Mpemba effect (QME), in which a system can exhibit anomalous relaxation, thermalizing faster from a state initially farther from equilibrium than from one closer. Here, we experimentally investigate the genuine QME and observe how the dynamics of a spin-1/2 system interacting with a heat sink can be sped-up to equilibrium. Furthermore, we apply the QME in a quantum Otto refrigerator, thereby increasing its cooling power. This proof-of-concept experiment unveils new practical paths for improving quantum thermal tasks.

The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2 quantum Otto cycle in a nuclear magnetic resonance setup. We first study the correlations between work and heat within a cycle by extracting their joint distribution for different driving times. We show that near perfect correlation, corresponding to the tight-coupling condition between work and heat, can be achieved. In this limit, the reconstructed efficiency distribution is peaked at the deterministic thermodynamic efficiency, and fluctuations are strongly suppressed. We further successfully test the second law in the form of a joint fluctuation relation for work and heat in the quantum cycle. Our results characterize the statistical features of a small-scale thermal machine in the quantum domain, and provide means to control them.

Employing currently available quantum technology, we design and implement a nonclassically correlated SWAP heat engine that allows to achieve an efficiency above the standard Carnot limit. Such an engine also boosts the amount of extractable work, in a wider parameter window, with respect to engine's cycle in the absence of initial quantum correlations in the working substance. The boosted efficiency arises from a trade-off between the entropy production and the consumption of quantum correlations during the full thermodynamic cycle. We derive a generalized second-law limit for the correlated cycle and implement a proof-of-principle demonstration of the engine efficiency enhancement by effectively tailoring the thermal engine on a cloud quantum processor.

Employing currently available quantum technology, we design and implement a non-classically correlated SWAP heat engine that allows to achieve an efficiency above the standard Carnot limit. Such an engine also boosts the amount of extractable work, in a wider parameter window, with respect to engine's cycle in the absence of initial quantum correlations in the working substance. The boosted efficiency arises from a trade-off between the entropy production and the consumption of quantum correlations during the full thermodynamic cycle. We derive a generalized second-law limit for the correlated cycle and implement a proof-of-principle demonstration of the engine efficiency enhancement by effectively tailoring the thermal engine on a cloud quantum processor.

Quantum thermodynamics seeks to extend non-equilibrium stochastic thermodynamics to small quantum systems where non-classical features are essential to its description. Such a research area has recently provided meaningful theoretical and experimental advances by exploring the wealth and the power of quantum features along with informational aspects of a system's thermodynamics. The relevance of such investigations is related to the fact that quantum technological devices are currently at the forefront of science and engineering applications. This short review article provides an overview of some concepts in quantum thermodynamics highlighting test-of-principles experiments using nuclear magnetic resonance techniques.

A quantum-controlled device may produce a scenario in which two general quantum operations can be performed in such a way that it is not possible to associate a definite order for the operations application. Such an indefinite causal order can be explored to produce nontrivial effects in quantum thermal devices. We investigate a measurement-powered thermal device that consists of generalized measurement channels with adjustable intensity parameters, where energy is exchanged with the apparatus in the form of work or heat. The measurement-based device can operate as a heat engine, a thermal accelerator, or a refrigerator, according to a measurement intensity setting. By employing a quantum switch of two measurement channels, we explore a thermal device fueled by an indefinite causal order. We also discuss how a coherent control over an indefinite causal order structure can change the operating regimes of the measurement-powered thermal device to produce an advantage when compared to a scenario with an incoherent control of the order switch.

A quantum-controlled device may produce a scenario in which two general quantum operations can be performed in such a way that it is not possible to associate a definite order for the operation's application. Such an indefinite causal order can be explored to produce nontrivial effects in quantum thermal devices. We investigate a measurement-powered thermal device that consists of generalized measurement channels with adjustable intensity parameters, where energy is exchanged with the apparatus in the form of work or heat. The measurement-based device can operate as a heat engine, a thermal accelerator, or a refrigerator, according to a measurement intensity setting. By employing a quantum switch of two measurement channels, we explore a thermal device fueled by an indefinite causal order. We also discuss how a coherent control over an indefinite causal order structure can change the operating regimes of the measurement-powered thermal device to produce an advantage when compared to a scenario with an incoherent control of the order switch.

Generalized measurements may allow the control of its back-action on the quantum system by interpolating from a very weak to strong projective action. Such a measurement can fuel a quantum heat engine or extract work depending on the system-meter interaction. Here, we performed a proof-of-concept experiment using nuclear magnetic resonance techniques to investigate a spin quantum heat engine driven by non-selective generalized (weak) measurements without feedback control. Our prototype of a quantum thermal device operates with a measurement protocol and a single heat bath. The protocol is composed of two non-selective measurement channels with variable measurement strengths, one dedicated to fueling the device (analogous to a hot heat source) and the other committed to work extraction. The experimental results highlight that this kind of quantum thermal device can reach unit efficiency with maximum extracted power by fine-tuning of the measurement strengths.