Manojit Pusty

Photo-actuators coupled with mechanical energy harvesting systems feature a promising approach to solar energy conversion in the broad field of innovative energy harvesting technologies. In this study, we present a novel device capable of generating a 0.2 V peak-to-peak signal by sustaining the continuous oscillation of photomobile polymer (PMP) films in the range of 5-8 Hz when exposed to continuous steady illumination by effectively transferring mechanical motion to a piezoelectric transducer (PZL). An optomechanical energy-harvesting prototype based on PMPs was fabricated and experimentally characterized utilizing Xenon arc-lamp that closely mimics natural sunlight electromagnetic radiation. The analyzed harvesting system exhibits a distinctive dual-stage energy conversion process, from light to mechanical and subsequently from mechanical to electrical energy, highlighting its potential for diverse applications in next-generation solar energy systems.

W₁₈O₄₉ nanostructures, previously used for electrocatalysis, energy storage, electrochromic, and gas sensing applications, are incorporated in poly(vinylidene fluoride) (PVDF) in this work for mechanical energy-harvesting applications. X-ray diffraction spectroscopy (XRD), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, differential scanning calorimetry (DSC), and the polarization-electric (P-E) field loop test prompts the addition of W₁₈O₄₉ nanorods in PVDF nucleates and stabilizes the piezoelectric polar γ-phase in the nanocomposite. Electrochemical experiments were employed for the first time to relate the event of the evolution of crystalline phases in PVDF to the transfer of electrons to the electrolyte from PVDF using the data from cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). High dielectric constant (ε') and low dielectric loss (ε″) values were obtained proportionately for different weight percentage additions of W₁₈O₄₉ nanorods in PVDF. DSC was employed to study the crystallization kinetics of γ-phase evolution. Piezoresponse force microscopy (PFM) was used to compare the piezoelectric responses from the PVDF nanocomposites. The W₁₈O₄₉/PVDF nanocomposite could generate a peak open circuit voltage of ∼6 V and a peak short circuit current of ∼700 nA. The W₁₈O₄₉/PVDF nanocomposite could light two commercial blue-light-emitting diodes (LEDs) with hand impulse imparting.

Zinc oxide (ZnO) nanogenerators have attracted increasing interest in the scientific community for use in energy harvesting and mechanical sensing applications. Understanding the interplay between piezoelectricity and semiconductor physics is fundamental to enhancing these devices’ performances, although direct characterization at the nanoscale is challenging. With this work, we present a new strategy to improve piezoresponse force microscopy (PFM) measurements and analysis. This strategy was applied to study the piezoelectric performances of ZnO nanowires grown on seed layers deposited by gravure printing onto flexible substrates. We demonstrate the influence of nanowire diameter and atomic force microscope (AFM) tip position on the piezoresponse amplitude. We also explain our results with simulations showing the importance of considering semiconducting properties in the analysis.

Zinc oxide (ZnO) nanowires (NWs) are excellent candidates for the fabrication of energy harvesters, mechanical sensors, and piezotronic and piezophototronic devices. In order to integrate ZnO NWs into flexible devices, low-temperature fabrication methods are required that do not damage the plastic substrate. To date, the deposition of patterned ceramic thin films on flexible substrates is a difficult task to perform under vacuum-free conditions. Printing methods to deposit functional thin films offer many advantages, such as a low cost, low temperature, high throughput, and patterning at the same stage of deposition. Among printing techniques, gravure-based techniques are among the most attractive due to their ability to produce high quality results at high speeds and perform deposition over a large area. In this paper, we explore gravure printing as a cost-effective high-quality method to deposit thin ZnO seed layers on flexible polymer substrates. For the first time, we show that by following a chemical bath deposition (CBD) process, ZnO nanowires may be grown over gravure-printed ZnO nanoparticle seed layers. Piezo-response force microscopy (PFM) reveals the presence of a homogeneous distribution of Zn-polar domains in the NWs, and, by use of the data, the piezoelectric coefficient is estimated to be close to 4 pm/V. The overall results demonstrate that gravure printing is an appropriate method to deposit seed layers at a low temperature and to undertake the direct fabrication of flexible piezoelectric transducers that are based on ZnO nanowires. This work opens the possibility of manufacturing completely vacuum-free solution-based flexible piezoelectric devices.

Cellulose is an abundant natural piezoelectric polymer and is also a renewable resource of significant importance. Here in this work we realize an enhanced piezoelectric response with cellulose in a polydimethylsiloxane (PDMS) matrix by forming a nanocomposite with the incorporation of gold nanoparticles (Au NPs). In the Au NP–cellulose/PDMS nanocomposite an enhancement in the dielectric constant is recorded due to the presence of cellulose alone and a reduction of dielectric loss is found owing to the presence of Au NPs. This opens the possibility of realizing a nanodielectric material from the nanocomposite under current study. This also indicates the significant potential of the nanocomposite towards energy conversion applications. Subsequently, a mechanical energy harvesting device was fabricated using the Au NP–cellulose/PDMS nanocomposite, which is named as a piezoelectric nanogenerator (PNG). The PNG delivered an enhanced open circuit voltage of ∼6 V, short circuit current of ∼700 nA and a peak power density of 8.34 mW m⁻² without performing any electrical poling steps. The PNG could charge a 10 μF capacitor to 6.3 V in 677 s and could light two commercial blue light emitting diodes (LEDs) simultaneously. The PNG exhibited a good energy conversion efficiency of 1.8%. A touch sensor application of the PNG is also shown.

Here we demonstrate the mechanical energy harvesting performance of a poly(vinylidene-fluoride) (PVDF) device which is loaded with reduced graphene oxide–silver nanoparticles (rGO–Ag). The current results show that the addition of rGO–Ag enhances the polar beta and gamma piezoelectric phases in PVDF, which is capable of generating a greater piezoelectric output, thereby eliminating the requirement of any external poling process. X-ray diffraction (XRD) and Fourier transform infra-red spectroscopy (FT-IR) characterizations were employed for the identification and quantification of the piezoelectric polar phases of the nanocomposite films. Raman spectroscopy confirmed the interactions between rGO–Ag and PVDF. Polarization vs. electric field (P–E) loop testing was performed and it was found that on the application of an external electric field of 148 kV cm⁻¹ the nanocomposite showed an energy density value of ∼0.26 J cm⁻¹, which indicates its potential for energy storage applications. The fabricated energy harvesting device, a piezoelectric nanogenerator (PNG), could charge up capacitors and light up to 20 commercial blue light-emitting diodes. The PNG was tested to harvest biomechanical energy from pulsing mechanical energy by fixing it to fingers on the human palm. The PNG was also fixed to flip-flops in order to demonstrate its footwear connected energy harvesting application. The PNG showed a peak output open circuit voltage of ∼18 V and a short circuit current of ∼1.05 μA, with a peak power density of 28 W m⁻³ across a 1 MΩ resistor. The PNG shows a moderate efficiency of 0.65%.