Qiaoling Zhang

The cross-flow rotating packed bed (RPB) has attracted wide attention in recent years because of its advantages of large gas capacity, low pressure drop and lack of flooding limitation. However, the complex structure of the packing makes it difficult to obtain the gas flow characteristics in the cross-flow RPB by experiments. In this study, the dry pressure drop in the cross-flow RPB was investigated by computational fluid dynamics (CFD). The packing was modeled by the porous media model and the rotation of the packing was simulated by the sliding mesh model. The simulation results obtained by three turbulence models were compared with experimental results, and the RNG k-ε model was found to best describe the turbulence behaviors in the cross-flow RPB. Then, the effects of gas flow rate and rotating speed on dry pressure drop in different parts of the cross-flow RPB were analyzed. The results of this study can provide important insights into the design and scale-up of cross-flow RPB.

In this study, the impinging stream-rotating packed bed and precipitation method were used to continuously prepare Fe and Co co-doped Titanium Dioxide by in-situ modification. With TiOSO₄ solution containing Fe and Co₂₊ and NH_3·H₂O were sprayed on the packing and sheared by the packing that rotated at a high speed, resulting in improvement of microscopic mixing. The prepared catalyst is anatase with a particle size of 14 nm and a specific surface area of 194.34 m²/g. The photoresponse range is extended to 550 nm with a band gap of 2.5 eV. The photoluminescence results show that doping of Fe and Co can effectively inhibit the recombination of photogenerated electron-hole pairs. The percentage decomposition of 100 mg/L phenol under UV and visible light irradiation for 2.5 h is 88.71% and 24.58%, which is 1.59 and 2.07 times that for pure TiO₂.

Nano-TiO₂ has always been one of the most important topics in the research of photocatalysts due to its special activity and stability. However, it has always been difficult to obtain nano-TiO₂ with high dispersion, a small particle size and high photocatalytic activity. In this paper, nano-TiO₂ powder was prepared by combining the high-gravity technique and direct precipitation method in an impinging stream-rotating packed bed (IS-RPB) reactor followed by Fe³⁺ in-situ doping. TiOSO₄ and NH₃·H₂O solutions were cut into very small liquid microelements by high-speed rotating packing, and the mass transfer and microscopic mixing of the nucleation and growth processes of nano-TiO₂ were strengthened in IS-RPB, which was beneficial to the continuous production of high quality nano-TiO₂. Pure TiO₂ and iron-doped nano-TiO₂ (Fe-TiO₂) were obtained in IS-RPB and were investigated by means of X-ray diffraction (XRD), Raman, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS) and Brunauer–Emmett–Teller (BET) analysis, which found that pure TiO₂ had a particle size of about 12.5 nm, good dispersibility and a complete anatase crystal at the rotating speed of packing of 800 rpm and calcination temperature of 500 °C. The addition of Fe³⁺ did not change the crystalline structure of TiO₂. Iron was highly dispersed in TiO₂ without the detection of aggregates and was found to exist in a positive trivalent form by XPS. With the increase of iron doping, the photoresponse range of TiO₂ to visible light was broadened from 3.06 eV to 2.26 eV. The degradation efficiency of gaseous toluene by Fe-TiO₂ under ultraviolet light was higher than that of pure TiO₂ and commercial P25 due to Fe³⁺ effectively suppressing the recombination of TiO₂ electrons and holes; the highest efficiency produced by 1.0% Fe-TiO₂ was 95.7%.