Diego Perugini

Understanding how the glass/crystal ratio influences the spectral response of volcanic rocks is crucial for interpreting planetary remote sensing data. Here, four mafic rocks simulating a possible Martian composition were synthesized with identical bulk chemistry but different mineralogical assemblages, from fully amorphous to ∼70 wt.% crystal content, to investigate how crystal content affects Visible and Near‐Infrared (VNIR) reflectance spectra. Bi‐directional VNIR reflectance was collected at room temperature across a range of incidence (0°, 30°, 60°) and emergence (−70° to +70°) angles. The diagnostic absorptions of the two most abundant phases, pyroxene and glass, are not distinguishable in the spectra and can even reproduce the spectral fingerprint of olivine, absent from the samples; only minor iron oxides (magnetite and hematite, ∼1–7 wt.%) produce clearly identifiable absorptions. Instead, spectral slope emerges as the primary proxy for the glass/crystal ratio: NIR/VNIR slope decreases systematically with increasing crystal content, driven jointly by the incorporation of iron oxides and the loss of the positive‐slope contribution of residual glass. Principal Component Analysis and k‐means clustering independently confirm this control, identifying three clusters that map onto the glass/crystal ratio. This decoupling indicates that the crystal content of a mafic terrain cannot be inferred from pyroxene‐ or glass‐related absorptions alone, but rather from spectral slope and iron‐oxide features. These results experimentally support previous hypotheses linking the spectral diversity of Martian mafic terrains to their degree of crystal content and oxidation state and highlight variable glass abundance as an under‐considered contributor to the spectral interpretation of the Martian surface.

In planetary science, visible (Vis) and near-infrared (NIR) reflectance spectra allow deciphering the chemical/mineralogical composition of celestial bodies’ surfaces by comparison between remotely acquired data and laboratory references. This paper presents the design of an automated test rig named Exoland Simulator equipped with two reflectance spectrometers covering the 0.38–2.2 µm range. It is designed to collect data of natural/synthetic rocks and minerals prepared in the laboratory that simulate the composition of planetary surfaces. The structure of the test rig is conceived as a Cartesian robot to automatize the acquisition. The test rig is also tested by simulating some project trajectories, and results are presented in terms of its ability to reproduce the programmed trajectories. Furthermore, preliminary spectral data are shown to demonstrate how the soil analogs’ spectra could allow an accurate remote identification of materials, enabling the creation of libraries to study the effect of multiple chemical–physical component variations on individual spectral bands. Despite the primary scope of Exoland, it can be advantageously used also for tribological purposes, to correlate the wear behavior of soils and materials with their composition by also analyzing the wear scars.

Experiments were performed at 500 MPa, 1080 °C and water activities ( a H 2 O) from 0.0 to 1.0, in fluid-present and fluid-absent conditions, with the aim of constraining the effect of volatiles on phase equilibrium assemblages of a shoshonite from Vulcanello (Aeolian Islands, Italy). Experiments were run both under reducing and oxidizing conditions and results show that proportions, shapes and size of crystals vary as a function of the volatile composition ( X H 2 O and X CO 2 ) and volatile content. Clinopyroxene (Cpx) is the main crystallising phase and is compositionally analogous to Cpx crystals found in the natural rock. Plagioclase (Pl) is stable only for water activity lower than 0.1, whereas Fe–Ti oxides are present in all experimental runs, except for those where log f O 2 was lower than - 9, ( Δ NNO - 0.11) irrespective of the presence of CO 2 . The addition of CO 2 (2.8 wt%) in nominally dry experimental charges substantially reduces the crystallinity by ca. 1/3 compared to volatile free experiments. This result has important consequences upon the physical properties of the magma because it influences its viscosity and, as a consequence, velocity during its travel to the Earth surface. Assuming that the widths of Vulcanello conduits vary from 0.5 to 1.5 m, estimates of the ascent velocity vary in the range 1.5 × 10 - 4 –3.5 × 10 - 2 m · s - 1 for CO 2 free systems and from 5.7 × 10 - 4 –1.3 × 10 - 1 m · s - 1 for CO 2 bearing systems. Since shoshonitic magmas are common not only in the Italian volcanic provinces (Aeolian Arc, Campi Flegrei, Ischia Island, Pontine Islands, Monti Cimini, Monte Amiata, Capraia Island, Radicofani, Roccamonfina) but also in different volcanoes worldwide (Yellowstone, Mariana Arc, Kurile Arc, Tonga Arc, Andean Arc, Kamchatka Arc), we suggest that the new data will be useful to better understand shoshonitic magma behaviour under relevant geological scenarios. As such, we also suggest that hazard evaluation should incorporate the probability of very rapid ascent of poorly-evolved melts from depth.

The stratovolcano Mt. Pelée, Martinique, exhibits eruptive styles ranging from dome formation to sustained, highly violent explosive activity. Historical eruptions have produced lava domes and pyroclastic density currents, collectively termed Peléan activity. In pre-colonial times, several Plinian eruptions took place. Here, we explore physical controls on the proportions of fine particles produced—i.e., the fragmentation efficiency—during primary fragmentation. Samples were collected from ignimbrites from the 1929–1932 and 1902–1905 Peléan eruptions and the P1 (1300 CE), P2 (280 CE), and P3 (79 CE) Plinian eruptions. All samples are andesitic in bulk composition and contain a rhyolitic groundmass glass. The Peléan materials are more crystalline and less porous than their Plinian counterparts, a consequence of more extensive outgassing during dome formation. Representative blocks were cored and experimentally fragmented following rapid decompression (> 1 GPa·s⁻¹ from initial pressure between 5 and 20 MPa). Dry sieving allowed for determining grain size distributions, from which the fractal dimensions, D_f, were calculated as a quantification of fragmentation efficiency. Our results indicate different behaviors for Peléan and Plinian samples. While fragmentation efficiency is positively correlated with applied potential energy for Peléan samples, this relationship is not observed for the Plinian samples, possibly due to syn-fragmentation gas escape above a certain porosity. The rapid decompression experiments were designed to minimize secondary fragmentation by shear along the walls or impact while preserving the entirety of produced materials. Thus, our experimental grainsize data are physically linked to sample textures and overpressure. By comparison with natural pyroclastic products—commonly incompletely preserved—we can approach quantitatively constraining the energetic conditions underlying individual eruptions.

The 22-23 April 2015 eruption of the Calbuco volcano (Southern Andes, Chile) led to extensive pyroclastic density currents (PDCs) interactions with vegetation. We seek to describe the PDCs which affected both Tepu and Frío rivers, northern Calbuco, from their timing and deposition to cooling and erosion, as well as their impacts on forests. Our investigation is based on field stratigraphy, forest disturbance assessment, and geothermometry from degassing pipes and charcoal. These PDCs reached at least ~540-603 °C, as estimated from fumaroles, and consisted of both concentrated and dilute PDCs during the first pulse (22 April) at Tepu and mainly during the second pulse (23 April) at Frío. Effects of PDCs on forest vegetation recorded in Tepu consisted of heating, abrasion, burial, and impact force. On the valley floor, trees were buried with up to 4 m of deposits from the concentrated PDCs, and all trees in this deposition zone died with no subsequent sprouting. Conversely, in the margins of the valley, defoliated fallen trees and standing shrubs indicate scorching due to the passage of dilute PDCs, and some of them were later sprouting. Estimated impact forces required to produce toppling range from 1.5 to 3.7 kPa, and PDC velocities reached up to 36 m s-1. Charring of the buried wood involved an emplacement temperature of 400-550 °C within PDC deposits. The rapid watershed formation may have facilitated infiltration, decreasing the temperature in the basal part within the deposits at the Tepu river. Runoff during the subsequent months triggered lahars and caused the rivers to incise the deposits and transport sediment downstream. This set of observations provides valuable insights into how the interaction between volcanic phenomena and margine forest on the valley floors informs eruptive processes, dynamics, and impacts. Our study is also relevant to interpret the thermal history and potential hazards of PDCs.

Volcanic products are widely present on Mercury: they occur as low-viscosity lava flows, but traces of ash deriving from explosive volcanism are also observed. Silicate glasses represent a major component in volcanic products, and it is likely that the fine-powdered regolith on Mercury contains a non-negligible fraction of glassy material. In the laboratory, we have reproduced a Mercury-like silicate glass, from which we have obtained 14 powdered samples with different granulometric characteristics: 8 samples are extremely sorted with grain sizes ranging from 25 to 425 µm, and 6 samples consist of less sorted powders with normal distributions, varying mean values (30, 95, and 160 µm) and standard deviation (40 and 80 µm). The reflectance of samples was investigated in the mid-infrared (MIR) region: we observe how the reflectance intensity increases with grain size, and the presence of extremely fine material defines the emergence of the transparency feature (TF). We provide reference data with qualitative observations and quantitative parameterization of spectral characteristics; in particular, we observe how a small fraction of fine material can greatly influence the spectral response of coarser powders. Results of this work will be crucial for the interpretation of data collected by the BepiColombo mission, but need to be integrated with other possible Mercurian compositions.

This review highlights the rheological and phase proportions variation induced by cooling events from superliquidus temperature (melt) to subliquidus temperatures. It provides a comprehensive view of the rheological response of magmatic systems undergoing dynamic cooling and shear deformation. The two main parameters which are of importance to model the rheological properties of such crystallizing systems and which are simultaneously poorly investigated so far are crystallization and strain rates. The response to relatively high deformation rates results in shear thinning behavior in partly crystallized systems under variable shear rate and it should be considered in magmatic processes. Due to the sluggish crystallization of SiO 2 -rich melts, data are mainly available for mafic systems, which does not allow a general reappraisal. An attempt to model available literature data for less evolved systems in dynamic scenarios and a comparison with MELTS algorithm approach (thermodynamic equilibrium conditions) is provided. Since there are difficulties in comparing experimental data gained using different methodologies, we focus mainly on data obtained with the concentric cylinder technique. This highlights the fact that a general experimental protocol is needed in order to compare and model viscosity data to predict the dynamic rheological evolution for volcanic rocks.