Gui-E Chen

Novel polyvinylidene fluoride/TiO2/UiO-66-NH2 (PVDF/TiUN) membranes were produced by the delay phase separation method via introducing the TiO2/UiO-66-NH2 (TiUN) nanocomposite into PVDF casting solution. Interconnection of TiO2 and UiO-66-NH2 improved photocatalysis capacity and endowed PVDF/TiUN membranes with self-cleaning capability. Quantitative measurements showed that, firstly, PVDF/TiUN membranes exhibited improved photodegradation kinetics and efficiency (up to 88.1%) to Rhodamine B (RhB). Secondly, the performances of bovine serum albumin (BSA) rejection and permeation of PVDF/TiUN membranes outperformed those of other check samples, indicating enhanced hydrophilicity. Thirdly, rejection rate of BSA reached a breathtaking 98.14% and flux recovery ratio (FRR) of BSA reached a breathtaking 95.37%. Thus, given their excellent anti-contamination property and separation performance, the PVDF/TiUN membrane is very likely to be a novel water treatment membrane.

Drawing self-cleaning technology into polymer membranes offers an extensive solution to overcome the membrane fouling obstacle. Herein, the GO-ZnO-Ag nano-hybrid particles with photocatalytic activity prepared via the microwave hydrothermal method were immobilized in poly(m-phenylene isophthalamide) (PMIA) membranes. Not only was the thorny issue in catalyst recovery avoided, but also the satisfactory photocatalytic self-cleaning performance of the polymer membrane was awarded. GO and noble metal silver nanoparticles (AgNPs) acted as a conductive electron transfer carrier and an electron host, respectively, which hindered the recombination rate of excited electrons and holes on ZnO under UV light. The UV-driven PMIA membrane photodegradation rates of MB and Cr(VI) were up to 97.2% and 94.3%, respectively, at 150 min on photodegradation kinetics. Also, MB was completely degraded at 180 min. For MB and Cr(VI) mix solutions, their degradation efficiencies were 78.1% and 71%, respectively. The BSA rejection rate of the modified polymer membrane was 93.8%, and the water flux was 408.8 (L·m⁻²·h⁻¹). Permeability was maintained at a high level after repeated use. Therefore, the newly designed PMIA/GO-ZnO-Ag series membranes could expand the application of polymers in wastewater disposal industry.