Mahmoud M. Saleh

Developing and manipulating new biomaterials is an ongoing topic for their needs in medical uses. The evolution and development of new biomaterials, in both the academic and industrial sectors, have been encouraged due to the dramatic improvement in medicine and medical-related technologies. Due to the drawbacks associated with natural biomaterials, the use of synthetic biomaterials is preferential due to basic and applied aspects. Various techniques are involved in fabricating biomaterials. Among them are the electrochemical-based methods, which include electrodeposition and electrophoretic methods. Although electrospinning and electrospraying are not typical electrochemical methods, they are also reviewed in this article due to their importance. Many remarkable features can be acquired from this technique. Electrodeposition and electrophoretic deposition are exceptional and valuable processes for fabricating thin or thick coated films on a surface of metallic implants. Electrodeposition and electrophoretic deposition have some common positive features. They can be used at low temperatures, do not affect the structure of the implant, and can be applied to complex shapes, and they can produce superior properties, such as quick and uniform coating. Furthermore, they can possibly control the thickness and chemical composition of the coatings. Electrospinning is a potentially emerging and efficient process for producing materials with nanofibrous structures, which have exceptional characteristics such as mechanical properties, pore size, and superior surface area. These specialized characteristics induce these nanostructured materials to be used in different technologies.

Reticulated vitreous carbon (RVC), a high surface area electrode (40 cm²/cm³), has been modified with nickel oxide nanoparticles (nano-NiO _x ) and used for electrochemical oxidation of urea from alkaline solution. For the cyclic voltammetry measurements, the used dimensions are 0.8 cm × 0.8 cm × 0.3 cm. The purpose was to offer high specific surface area using a porous open network structure to accelerate the electrochemical conversion. NiO _x nanoparticles have been synthesized via an electrochemical route at some experimental conditions. The morphological, structural, and electrochemical properties of the RVC/nano-NiO _x are characterized by using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), cyclic voltammetry (CV), and potentiostatic measurements. The fabricated electrode, RVC/nano-NiO _x , demonstrates high electrocatalytic activity towards urea oxidation in an alkaline electrolyte. The onset potential of the RVC/nano-NiO _x compared to that of the planar GC/NiO _x is shifted to more negative value with higher specific activity. The different loadings of the NiO _x have a substantial influence on the conversion of urea which has been evaluated from concentration-time curves. The urea concentration decreases with time to a limit dependent on the loading extent. Maximum conversion is obtained at 0.86 mg of NiO _x per cm³ of the RVC matrix.