Brahim Arhoun
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The organizations/institutes from the scholar's latest article
Previous Organizations / Institutes
The organizations / institutes from the scholar's other articles in the past ten years
Research Subjects
Brahim Arhoun has a total of 17 co-authors. Here are the top co-authors by number of shared publications:
- José Miguel Rodríguez Maroto
Department of Chemical Engineering, University of Malaga, 29071 Malaga, Spain
6 shared publications - Cesar Gomez-Lahoz
Chemical Engineering Department, Faculty of Sciences, University of Málaga, 29071 Málaga, Spain
5 shared publications - Maria Villen-Guzman
Department of Chemical Engineering, University of Malaga, 29071 Malaga, Spain
5 shared publications - Carlos Vereda-Alonso
Department of Chemical Engineering, University of Malaga, 29071 Malaga, Spain
4 shared publications - Francisco Garcia-Herruzo
A Chemical Engineering Department, Faculty of Sciences , University of Malaga , Malaga , Spain
3 shared publications Jose Miguel Rodriguez-Maroto
3 shared publications
Latest Publications
- Open Access
- 15 September 2023
- Published by IWA Publishing
- p. 153-194
Electrochemical treatment of landfill leachate
A significant municipal solid waste is managed by disposition in a landfill. This kind of management system makes producing leachate with toxic characteristics
- 15 September 2023
- Published by IWA Publishing
- p. 153-194
Open AccessElectrochemical treatment of landfill leachate
A significant municipal solid waste is managed by disposition in a landfill. This kind of management system makes producing leachate with toxic characteristics
- Open Access
- 15 September 2023
- Published by IWA Publishing
- p. 297-326
Separation treatment of landfill leachate
Landfilling municipal waste is the most common way to manage waste in the world. An important problem associated with landfills is the production of leachates. Landfill leachate is heterogeneous wastewater and often possesses potential pollution with high concentrations of organic and inorganic contaminants. The generated leachate must be appropriately collected and treated before being discharged into the environment. Several technologies have been used for leachate treatment which can be classified as biological, chemical, and physical processes. Among physical processes, membrane separation including microfiltration, ultrafiltration, nanofiltration, and reverse osmosis has been used for landfill leachate treatment. However, single-membrane processes are not very effective unless they are combined with biological and physicochemical treatment processes. This is because membrane separation presents two main drawbacks: membrane concentrates (MCs) and fouling. Here, we briefly review the main processes currently used for MC treatment. Finally, the fouling membrane is also discussed.
- 15 September 2023
- Published by IWA Publishing
- p. 297-326
Open AccessSeparation treatment of landfill leachate
Landfilling municipal waste is the most common way to manage waste in the world. An important problem associated with landfills is the production of leachates. Landfill leachate is heterogeneous wastewater and often possesses potential pollution with high concentrations of organic and inorganic contaminants. The generated leachate must be appropriately collected and treated before being discharged into the environment. Several technologies have been used for leachate treatment which can be classified as biological, chemical, and physical processes. Among physical processes, membrane separation including microfiltration, ultrafiltration, nanofiltration, and reverse osmosis has been used for landfill leachate treatment. However, single-membrane processes are not very effective unless they are combined with biological and physicochemical treatment processes. This is because membrane separation presents two main drawbacks: membrane concentrates (MCs) and fouling. Here, we briefly review the main processes currently used for MC treatment. Finally, the fouling membrane is also discussed.
- 1 April 2021
- Published by Wiley in Water and Environment Journal
- Vol. 35 (3) , 1147-1157
Effect of pretreatment and co‐substrate addition on biogas production from pig slurry
The anaerobic digestion of pig slurry samples collected from different points of a farm and raw pig slurry pretreated by centrifugation and decantation was first studied. The specific methane production of raw pig slurry and after centrifugation and decantation pretreatment was 158, 24 and 42.34 L kgVS−1, respectively. Second, the anaerobic digestion of the mixture of raw pig slurry and decanted solid fraction at different organic loading rate (1.364–3.41 gVS·L−1·d−1) results in a specific methane production of 249 ± 37·L kgVS −1. The concentration of ammonium ion in the digester increased to 2500 mg L−1 without inhibition. Lastly, the co‐digestion of pear waste and raw pig slurry was also analysed, which enhanced the specific methane production (243 L kgVS−1). This work deals with the integral management of pig slurry and points out the possibility of revalorization of other wastes in the same digester.
- 1 April 2021
- Published by Wiley in Water and Environment Journal
- Vol. 35 (3) , 1147-1157
Effect of pretreatment and co‐substrate addition on biogas production from pig slurry
The anaerobic digestion of pig slurry samples collected from different points of a farm and raw pig slurry pretreated by centrifugation and decantation was first studied. The specific methane production of raw pig slurry and after centrifugation and decantation pretreatment was 158, 24 and 42.34 L kgVS−1, respectively. Second, the anaerobic digestion of the mixture of raw pig slurry and decanted solid fraction at different organic loading rate (1.364–3.41 gVS·L−1·d−1) results in a specific methane production of 249 ± 37·L kgVS −1. The concentration of ammonium ion in the digester increased to 2500 mg L−1 without inhibition. Lastly, the co‐digestion of pear waste and raw pig slurry was also analysed, which enhanced the specific methane production (243 L kgVS−1). This work deals with the integral management of pig slurry and points out the possibility of revalorization of other wastes in the same digester.
- Open Access
- 14 February 2020
- Published by MDPI AG in International Journal of Environmental Research and Public Health
- Vol. 17 (4) , 1241
Chemical Reduction of Nitrate by Zero-Valent Iron: Shrinking-Core versus Surface Kinetics Models
Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of kinetics. Here we present a study of the kinetics of nitrate reduction under relatively low values of pH, from 2 to 4.5. We use a particle size of 0.42 mm, which is within the recommended size for PRBs (0.2 mm to 2.0 mm). In order to avoid possible mass-transfer limitations, a well-stirred reactor coupled with a fluidized bed reactor was used. The experiments were performed at constant pH values using a pH controller that allows to accurately track the amount of acid added. Since the reduction of to by the oxidation of ZVI will always be present for these pH values, blank experiments (without nitrate) were performed and the rate of this reduction obtained. This rate of reduction was studied using three kinetic models: a regular empirical one, the Shrinking-Core Model (SCM), and the Surface Kinetics Model (SKM). The best performance was obtained from the SKM model. Therefore, this model was also used to study the results for the nitrate reduction, also with satisfactory results. In both cases, some assumptions are introduced to maintain a moderate number of fitting parameters.- 14 February 2020
- Published by MDPI AG in International Journal of Environmental Research and Public Health
- Vol. 17 (4) , 1241
Open AccessChemical Reduction of Nitrate by Zero-Valent Iron: Shrinking-Core versus Surface Kinetics Models
Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of kinetics. Here we present a study of the kinetics of nitrate reduction under relatively low values of pH, from 2 to 4.5. We use a particle size of 0.42 mm, which is within the recommended size for PRBs (0.2 mm to 2.0 mm). In order to avoid possible mass-transfer limitations, a well-stirred reactor coupled with a fluidized bed reactor was used. The experiments were performed at constant pH values using a pH controller that allows to accurately track the amount of acid added. Since the reduction of to by the oxidation of ZVI will always be present for these pH values, blank experiments (without nitrate) were performed and the rate of this reduction obtained. This rate of reduction was studied using three kinetic models: a regular empirical one, the Shrinking-Core Model (SCM), and the Surface Kinetics Model (SKM). The best performance was obtained from the SKM model. Therefore, this model was also used to study the results for the nitrate reduction, also with satisfactory results. In both cases, some assumptions are introduced to maintain a moderate number of fitting parameters. - 27 February 2019
- Published by Taylor & Francis in Journal of Environmental Science and Health, Part A
- Vol. 54 (7) , 628-634
Anaerobic co-digestion of municipal sewage sludge and fruit/vegetable waste: effect of different mixtures on digester stability and methane yield
The anaerobic co-digestion of fruit and vegetable waste (FVW) and municipal sewage sludge (MSS) is investigated under mesophilic conditions. This was done at a constant hydraulic retention time (HRT) similar to that typically used at waste water treatment plant digesters, 20 days. The effects on digester performance of the FVW:MSS ratio and the organic loading rate (OLR) were examined. Initially the digester was fed with MSS from wastewater treatment plants (WWTP) with an average OLR of 1.03 kgVS (m3 d)−1. The co-digestion of MSS and FVW was performed at various ratios of FVW in the mixture, while increasing the OLRs, from 1.03 to 4.78 kgVS (m3 d)−1. The experimental specific methane production (SMP) was 0.303 m3 (kgVS)−1 for MSS and 0.403 m3 (kgVS)−1 for FVW as single substrate. This value varied for co-digestion with a maximum of 0.445 m3 (kgVS)−1 for a FVW:MSS ratio of 40:60. Alkalinity and pH values remain relatively constant regardless the different FVW:MSS ratios fed. As this ratio increases, the removal of the volatile solids (VS) increased from 38.7% to 82%. The average methane content of digester biogas was about 62–64%.- 27 February 2019
- Published by Taylor & Francis in Journal of Environmental Science and Health, Part A
- Vol. 54 (7) , 628-634
Anaerobic co-digestion of municipal sewage sludge and fruit/vegetable waste: effect of different mixtures on digester stability and methane yield
The anaerobic co-digestion of fruit and vegetable waste (FVW) and municipal sewage sludge (MSS) is investigated under mesophilic conditions. This was done at a constant hydraulic retention time (HRT) similar to that typically used at waste water treatment plant digesters, 20 days. The effects on digester performance of the FVW:MSS ratio and the organic loading rate (OLR) were examined. Initially the digester was fed with MSS from wastewater treatment plants (WWTP) with an average OLR of 1.03 kgVS (m3 d)−1. The co-digestion of MSS and FVW was performed at various ratios of FVW in the mixture, while increasing the OLRs, from 1.03 to 4.78 kgVS (m3 d)−1. The experimental specific methane production (SMP) was 0.303 m3 (kgVS)−1 for MSS and 0.403 m3 (kgVS)−1 for FVW as single substrate. This value varied for co-digestion with a maximum of 0.445 m3 (kgVS)−1 for a FVW:MSS ratio of 40:60. Alkalinity and pH values remain relatively constant regardless the different FVW:MSS ratios fed. As this ratio increases, the removal of the volatile solids (VS) increased from 38.7% to 82%. The average methane content of digester biogas was about 62–64%.- Open Access
- 22 January 2019
- Published by Wiley in Journal of Chemical Technology & Biotechnology
- Vol. 94 (6) , 1727-1738
Electrodialytic processes in solid matrices. New insights into battery recycling. A review
Electrodialytic remediation has been widely applied to the recovery of different contaminants from numerous solid matrices, solving emerging issues of environmental concern. Results and conclusions reported in studies about real contaminated matrices are summarized in this work. The influence of pH value on the treatment effectiveness has been widely proved, highlighting the phenomenon of ‘water splitting’ in the membrane surface. This dissociation of water molecules is related to the ‘limiting current’ which it is desirable to exceed at the anion exchange membrane in order to produce the entering of protons toward the solid matrix. Other important parameters for the optimization of the technique, such as the current density and the liquid/solid ratio, are also discussed through the revision of studies using real solid matrices.This work also focuses on the pioneer proposal of electrokinetic technologies for the recycling of lithium ion batteries, considering the relevance of waste properties in the design and optimization of the technique. From a thorough literature revision, it could be concluded that further experimental results are needed to allow an optimal application of the technique to the rising problem of residues from batteries. The main aim of this work is to take the first steps in the recovery of valuable metals such as Li and Co from spent batteries, incorporating principles of green chemistry. © 2019 Society of Chemical Industry
- 22 January 2019
- Published by Wiley in Journal of Chemical Technology & Biotechnology
- Vol. 94 (6) , 1727-1738
Open AccessElectrodialytic processes in solid matrices. New insights into battery recycling. A review
Electrodialytic remediation has been widely applied to the recovery of different contaminants from numerous solid matrices, solving emerging issues of environmental concern. Results and conclusions reported in studies about real contaminated matrices are summarized in this work. The influence of pH value on the treatment effectiveness has been widely proved, highlighting the phenomenon of ‘water splitting’ in the membrane surface. This dissociation of water molecules is related to the ‘limiting current’ which it is desirable to exceed at the anion exchange membrane in order to produce the entering of protons toward the solid matrix. Other important parameters for the optimization of the technique, such as the current density and the liquid/solid ratio, are also discussed through the revision of studies using real solid matrices.This work also focuses on the pioneer proposal of electrokinetic technologies for the recycling of lithium ion batteries, considering the relevance of waste properties in the design and optimization of the technique. From a thorough literature revision, it could be concluded that further experimental results are needed to allow an optimal application of the technique to the rising problem of residues from batteries. The main aim of this work is to take the first steps in the recovery of valuable metals such as Li and Co from spent batteries, incorporating principles of green chemistry. © 2019 Society of Chemical Industry
- 9 January 2019
- Published by Springer Nature in Water, Air, & Soil Pollution
- Vol. 230 (1) , 19
Immobilization of Brown Seaweeds Sargassum vulgare for Fe3+ Removal in Batch and Fixed-Bed Column
- 9 January 2019
- Published by Springer Nature in Water, Air, & Soil Pollution
- Vol. 230 (1) , 19
Immobilization of Brown Seaweeds Sargassum vulgare for Fe3+ Removal in Batch and Fixed-Bed Column
- 27 April 2017
- Published by Taylor & Francis in Journal of Environmental Science and Health, Part A
- Vol. 52 (9) , 856-861
Production of biogas from co-digestion of livestock and agricultural residues: A case study
This study was undertaken to determine the possible changes in the digester yield and performance for the anaerobic co-digestion under mesophilic conditions of strawberry residues (SRs) together with pig manure (PM). The first part of this paper deals with the digestion of SR as a single substrate. For organic loading rates (OLRs) of 4.4 (g L−1 d−1) or less, the experimental specific biogas and methane productions are 0.588 and 0.231 L g−1, respectively. When higher OLRs (5.5 g L−1 d−1) are used the digester fails due to acidification. In the second part, the co-digestion of both residues is explored using a wide variety of SR:PM ratios and OLRs of 5.5 g L−1 d−1 with good stability. Therefore, it is demonstrated that co-digestion allows the improvement of the treatment capacity as compared with SR as a single residue. The methane and biogas productions increase as the SR:PM ratio increases. It may be concluded that, when a digester works with a certain OLR, the performance for co-digestion is always better than for single substrates because the presence of PM provides a better stability and the presence of SR improves the biogas and methane production.
- 27 April 2017
- Published by Taylor & Francis in Journal of Environmental Science and Health, Part A
- Vol. 52 (9) , 856-861
Production of biogas from co-digestion of livestock and agricultural residues: A case study
This study was undertaken to determine the possible changes in the digester yield and performance for the anaerobic co-digestion under mesophilic conditions of strawberry residues (SRs) together with pig manure (PM). The first part of this paper deals with the digestion of SR as a single substrate. For organic loading rates (OLRs) of 4.4 (g L−1 d−1) or less, the experimental specific biogas and methane productions are 0.588 and 0.231 L g−1, respectively. When higher OLRs (5.5 g L−1 d−1) are used the digester fails due to acidification. In the second part, the co-digestion of both residues is explored using a wide variety of SR:PM ratios and OLRs of 5.5 g L−1 d−1 with good stability. Therefore, it is demonstrated that co-digestion allows the improvement of the treatment capacity as compared with SR as a single residue. The methane and biogas productions increase as the SR:PM ratio increases. It may be concluded that, when a digester works with a certain OLR, the performance for co-digestion is always better than for single substrates because the presence of PM provides a better stability and the presence of SR improves the biogas and methane production.
- 1 January 2013
- Published by Elsevier in Bioresource Technology
- Vol. 127, 242-247
Biogas production from pear residues using sludge from a wastewater treatment plant digester. Influence of the feed delivery procedure
- 1 January 2013
- Published by Elsevier in Bioresource Technology
- Vol. 127, 242-247
Biogas production from pear residues using sludge from a wastewater treatment plant digester. Influence of the feed delivery procedure