Federico Artoni

Polymeric materials typically present a complex response to mechanical actions; in fact, their behavior is often characterized by viscous time-dependent phenomena due to the network rearrangement and damage induced by chains’ bond scission, chains sliding, chains uncoiling, etc. A simple yet reliable model—possibly formulated on the basis of few physically-based parameters—accounting for the main micro-scale micromechanisms taking place in such a class of materials is required to properly describe their response. In the present paper, we propose a theoretical micromechanical approach rooted in the network’s chains statistics which allows us to account for the time-dependent response and for the chains failure of polymer networks through a micromechanics formulation. The model is up-scaled to the mesoscale level by integrating the main field quantities over the so-called ‘chains configuration space’. After presenting the relevant theory, its reliability is verified through the analysis of some representative tests, and some final considerations are drawn.

Soft matter denotes a large category of materials showing unique properties, resulting from a low elastic modulus, a very high deformation capability, time-dependent mechanical behavior, and a peculiar mechanics of damage and fracture. The flaw tolerance, commonly understood as the ability of a given material to withstand external loading in the presence of a defect, is certainly one of the most noticeable attributes. This feature results from a complex and highly entangled microstructure, where the mechanical response to external loading is mainly governed by entropic-related effects. In the present paper, the flaw tolerance of soft elastomeric polymers, subjected to large deformation, is investigated experimentally. In particular, we consider the tensile response of thin plates made of different silicone rubbers, containing defects of various severity at different scales. Full-field strain maps are acquired by means of the Digital Image Correlation (DIC) technique. The experimental results are interpreted by accounting for the blunting of the defects due to large deformation in the material. The effect of blunting is interpreted in terms of reduction of the stress concentration factor generated by the defect, and failure is compared to that of traditional crystalline brittle materials.

Highly deformable materials, such as elastomers and gels, can withstand very large deformation without failure, and this response is usually insensitive to the presence of macroscopic defects. These polymer‐based materials, different from the traditional ones which are usually characterized by an enthalpic elasticity, show a mechanical response which is governed by the state of internal entropy of their molecular network. If fracture energy is large, the noticeable ability of soft materials to rearrange their network at the microscale, to display large deformation and to dissipate energy thanks to their viscoelasticity, allows the minimization of the local detrimental effect of existing flaws. In the present paper, the mechanical behavior of silicone‐based edge cracked plates with different crack sizes and severity of the intrinsic flaws embedded in the material is examined by taking into account the time‐dependent effects. Experimental and theoretical aspects are discussed to explain the defect tolerance of such materials. The detrimental effect of intrinsic voids is quantified, and the beneficial effect due to strain at low rates is analysed. The critical distance is related to the ultimate stretch value, the quality of the material, and the crack size.