Gijsbert D. Breedveld

We present an automated tool for long-term sampling of nano and microplastics (NMP) and associated chemicals in remote areas, addressing a critical need for cost-effective, high-temporal-resolution data collection. A major challenge in NMP research is overcoming the financial and time constraints of intensive sampling campaigns.To address this, we deployed two devices in the Arctic at the Ny-Ålesund research base, focusing on enhancing understanding of polar NMP distribution and transport mechanisms. The auto-sampling system utilises active air sample containers, NanoTank’s, to collect airborne particles through percolation in a liquid trap. Stepper motors, linear actuators, and controllers enable the movement of NanoTanks for automated collection of time-series samples at set intervals.The first systems were deployed in October 2024, and the collected samples will be analysed by pyrolysis gas chromatography mass spectrometry (pyGC/MS) for nanoplastics, Raman spectroscopy for microplastics, and Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS) for persistent organic pollutant analysis (PFAS focus).This setup alleviates the need for porous filters that can clog given varied exposure levels. Our system will help to expand the capabilities of atmospheric research and allow us to increase our datasets and understanding of temporal and spatial distributions of NMP.

The extensive use of per- and polyfluorinated alkyl substances (PFAS) has resulted in many environmental point and diffuse sources. Identifying the source responsible for a pollution hot spot is vital for assessing remediation measures, however, as there are many possible sources of environmental PFAS pollution, this can be challenging. Chemical fingerprinting has been proposed as an approach to identify contamination sources. Here, concentrations and profiles (relative distribution profiles) of routinely targeted PFAS in freshwater fish from eight sites in Norway, representing three different sources: (1) production of paper products, (2) the use of aqueous film forming foams (AFFF), and (3) long-range atmospheric transport, were investigated. The data were retrieved from published studies. Results showed that fingerprinting of PFAS in fish can be used to identify the dominant exposure source(s), and the profiles associated with the different sources were described in detail. Based on the results, the liver was concluded to be better suited for source tracking compared to muscle. PFAS fingerprints originating from AFFF were dominated by perfluorooctanesulfonate (PFOS) and other perfluoroalkanesulfonic acids (PFSA). Fingerprints originating from both long-range atmospheric transport and production of paper products were associated with high percentages of long chained perfluoroalkyl carboxylic acids (PFCA). However, there were differences between the two latter sources with respect to the ∑PFAS concentrations and ratios of specific PFCA pairs (PFUnDA/PFDA and PFTrDA/PFDoDA). Low ∑PFAS concentrations were detected in fish exposed mainly to PFAS via long-range atmospheric transport. In contrast, ∑PFAS concentrations were high and high percentages of PFOS were detected in fish exposed to pollution from production of paper products. The source-specific fingerprints described here can be used for source tracking.

The reclamation of acid-generating mine tailings typically involves building cover systems to limit interactions with water or oxygen. The choice of cover materials is critical to ensure long-term performance, and partly determines the environmental footprint of the reclamation strategy. The objective of this research was to evaluate if tailings pre-oxidized on-site could be used in cover systems. Column experiments were performed to assess the effectiveness of a cover with capillary barrier effects (CCBE), where the moisture retention layer (MRL) was made of pre-oxidized tailings with little to no remaining sulfides (LS tailings). The columns were submitted to regular wetting and drying cycles, and their hydrological and geochemical behaviour was monitored for 510 days. The LS tailings showed satisfying hydrological properties as an MRL and remained saturated throughout the test. The concentrations of Cu in the drainage decreased by more than two orders of magnitude compared to non-covered tailings. In addition, the pH increased by nearly one unit compared to the control column, and Fe and S concentrations decreased by around 50%. Despite these improvements, the leachate water remained acidic and contaminated, indicating that acid drainage continued to be generated despite a hydrologically efficient CCBE.

Urbanization has resulted in increased contaminant run-off in densely populated areas. Climate change is expected to result in a higher frequency of extreme weather events including torrential rainfall and storms. The contaminant levels of polycyclic aromatic hydrocarbons (PAH), chlorinated paraffins (CPF) and selected metals, in a small urban river were monitored during snow-melting and rainfall events to quantify the contribution to the contamination load of receiving waters of the inner Oslo fjord, Norway. Suspended particulate matter (SPM) was characterized with respect to levels of contaminants as well as toxic response using a battery of bioassays. The contaminant flux from the river to the fjord was quantified and assessed relative to sediment data. Historic data for near-shore sediment samples from the fjord were used to document urban input. The results show a clear episodic response in contaminant load emitted from the river to the fjord. The main historic input to the fjord was found to be PAH from pyrogenic sources like coal and wood burning as well as traffic. A significant reduction in the level of PAH was observed since the 1980s. The measured flux of CPF is consistent with on-going societal use despite a ban on the use of short chain CPF imposed in Norway from 2002.

The environmental behaviour of perfluorinated alkyl acids (PFAA) and their precursors was investigated in lake Tyrifjorden, downstream a factory producing paper products coated with per- and polyfluorinated alkyl substances (PFAS). Low water concentrations (max 0.18 ng L^-1 linear perfluorooctanesulfonic acid, L-PFOS) compared to biota (mean 149 µg kg^-1 L-PFOS in perch livers) resulted in high bioaccumulation factors (L-PFOS BAF_{Perch liver}: 8.05x10⁵-5.14x10⁶). Sediment concentrations were high, particularly for the PFOS precursor SAmPAP diester (max 1 872 µg kg^-1). Biota-sediment accumulation factors (L-PFOS BSAF_{Perch liver}: 22-559) were comparable to elsewhere, and concentrations of PFAA precursors and long chained PFAA in biota were positively correlated to the ratio of carbon isotopes (¹²C/¹³C), indicating positive correlations to dietary intake of benthic organisms. The sum fluorine from targeted analyses accounted for 54% of the extractable organic fluorine in sediment, and 9-108% in biota. This, and high trophic magnification factors (TMF, 3.7-9.3 for L-PFOS), suggests that hydrophobic precursors in sediments undergo transformation and are a main source of PFAA accumulation in top predator fish. Due to the combination of water exchange and dilution, transformation of larger hydrophobic precursors in sediments can be a source to PFAA, some of which are normally associated with uptake from water.

The use of aqueous film-forming foams (AFFFs) has resulted in hot spots polluted with poly- and perfluorinated alkyl substances (PFASs). The phase out of long-chained perfluoroalkyl acids (PFAAs) from AFFFs resulted in the necessity for alternatives, and short-chained PFAAs and fluorotelomer-based surfactants have been used. Here, the distribution of PFAS contamination in the marine environment surrounding a military site in Norway was investigated. Up to 30 PFASs were analyzed in storm, leachate, and fjord water; marine sediments; marine invertebrates (snails, green shore crab, great spider crab, and edible crab); and teleost fish (Atlantic cod, European place, and Lemon sole). Perfluorooctanesulfonic acid (PFOS) was the most abundantly detected PFAS. Differences in PFAS accumulation levels were observed among species, likely reflecting different exposure routes among trophic levels and different capabilities for depuration and/or enzymatic degradation. In agreement with previous literature, almost no 6:2 fluorotelomer sulfonate (6:2 FTS) was detected in teleost fish. However, this study is one of the first to report considerable concentrations of 6:2 FTS in marine invertebrates, suggesting bioaccumulation. Biota monitoring and risk assessments of sites contaminated with fluorotelomer sulfonates (FTSs) and related compounds should not be limited to fish, but should also include invertebrates.