Miroslawa Prochon

This work introduces a circular biopolymer-based strategy for valorizing keratin-rich industrial residues through the fabrication of biodegradable cotton agrotextiles functionalized with latex–hydrogel coatings. Keratin hydrolysates and gelatin-derived biofertilizer capsules were incorporated into polymer–hydrogel matrices and applied onto cotton substrates to enhance soil moisture regulation and controlled nutrient release. The composite coatings were characterized in terms of water absorption capacity, mechanical performance, biodegradation profiles, and their impact on plant growth using Phaseolus vulgaris as a model species. Hydrogel-rich formulations (LH20 and LH40Z) provided the most favorable balance of tensile strength and controlled degradation while significantly increasing soil moisture availability and overall plant biomass compared with uncoated controls. The gelatin–keratin microcapsules enabled sustained nutrient release and induced a slight increase in soil pH, further supporting plant development. These findings demonstrate the dual functionality of the developed latex–hydrogel coatings as water-management and nutrient-delivery systems and highlight the potential of keratin biowaste upcycling toward high-value, biodegradable agricultural materials aligned with circular economy principles.

Precipitated silica was subjected to a sustainable strategy of surface modification with l-cysteine or functional silanes: 3-aminopropyltriethoxysilane or 3-mercaptopropyltrimethoxysilane (as a reference way), and the effects were compared from the point of view of the degree of coverage and the number of functional groups present on the filler surface. Because the silane coupling agent requires relatively high doses, being additionally hazardous, flammable, susceptible to failure during storage, and has to be incorporated into the organic dispersants and prehydrolysis treatment, the application of more convenient and green modifiers is sought. Infrared spectra and thermogravimetric analysis confirm the effective grafting of silica surface, with the greatest extent observed in the case of l-cysteine. The presence of both amino and thiol groups in the amino acid molecule is likely to be responsible for its much greater degree of adsorption on the filler surface. A greater degree of modification of the silica surface with l-cysteine comes together with better compatibility of the amino acid with natural rubber (NR). Unlike silanes, l-cysteine does not seem to interfere with the sulfur vulcanization process. The proposed modification of silica resulted in an increase in the cross-link density of vulcanizates and a change in the cross-link structure. The replacement of silica-coupling agents with l-cysteine resulted in an improvement in the macrodispersion of filler, represented by the dispersion index and indicated by the Payne effect. The changes in the cross-link density and structure, as well as improved filler dispersion and unchanged bound rubber content, result in an increase in the tensile strength and elongation at break, but contrary to silanization, decreasing stiffness of the vulcanizates. The presented results confirm the possibility of replacing conventional silane compatibilizers with l-cysteine in rubber technology, opening a new direction of research on the application of cheap protein derivatives obtained from recycled natural products.

Elastomers such as acrylonitrile–butadiene rubber (NBR) are widely used in high-performance applications, yet their intrinsic flammability poses serious safety challenges. This study introduces hybrid nano-additive systems designed to enhance the fire resistance of NBR-based elastomers through the synergistic action of organic, inorganic, and biopolymeric components. The developed formulations incorporate melamine (M), melamine polyphosphate (PM), casein (K), and keratin recovered from industrial waste (P), combined via conventional and hybrid compounding methods. Vulcanization was carried out at 160°C, with optimal curing determined rheometrically. The composites were extensively characterized using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), microcalorimetry, Fourier-transform infrared spectroscopy (FTIR), optical microscopy, and mechanical testing (tensile strength, hardness, aging resistance). The results revealed that hybrid systems, particularly melamine polyphosphate or casein combined with keratin (PPM or PK), reduced heat release rate and combustion efficiency by more than 20% compared to single-component systems. The addition of nanoscale fillers further delayed thermal degradation and improved char stability. This work demonstrates a synergistic flame-retardant mechanism in NBR elastomers, integrating thermal shielding, char formation, and endothermic decomposition pathways. Moreover, the use of biodegradable waste-derived additives enhances the sustainability profile of the materials. The developed hybrid nano-additive systems offer a promising pathway toward eco-efficient, flame-retardant elastomers for applications in sectors with elevated fire hazard, such as automotive, aerospace, and electronics.

The objective of this study was to investigate the influence of the lignocellulose filler originating in wood and non-wood raw materials, alone or together with collagen hydrolysate, on the properties and biodegradation ability of natural rubber latex. The different hydrophobicity of the polymer matrix and natural filler makes it difficult to obtain a homogenous structure of the composite. However, the easy biodegradation of the natural filler is a sufficient reason to seek a compromise between its useful properties and the environmental safety of the material. The composites were filled with lignocellulose filler: pine, spruce, and birch wood flour or willow, raspberry, and mallow non-wood flour. Collagen hydrolysate was used as a substitute for lignocellulosic filler, together or alone. The mechanical properties of the composites, their hardness, and equilibrium swelling were studied. In order to determine the morphology and interactions between filler and latex, scanning electron microscopy together with infrared spectroscopy were engaged. The results revealed that after the incorporation of 4 phr of the filler, the increase in mechanical strength was observed even despite the lack of compatibility between the filler and polymer matrix. The lignocellulose filler is a promising agent because its biodegradability contributes to the overall environmental safety of the polymer material.

This study aimed to develop and optimize polyvinyl alcohol (PVA)-based polymeric films containing resveratrol (RSV) and to evaluate their applicability as oral mucosal wound dressings. Given the dynamic and complex nature of the oral environment, physicochemical parameters such as elasticity, mucoadhesive strength, and the release profile of the RSV were systematically investigated. The therapeutic performance of pure resveratrol was compared with that of an extract derived from Reynoutria japonica. Films were fabricated using a solvent casting method and characterized in terms of thickness uniformity, weight, color consistency, and flexibility, all of which met the required pharmaceutical criteria. Two tested formulations, FR2 (RSV/PVA/PVP/MCA15C/NaCMC/W/PGE), FE2 (extract/PVA/PVP/MCA15C/NaCMC/W/PGE), showed the best mucoadhesive properties (261.11 ± 0.5 g for FR2 and 299.43 ± 0.38 g for FE2) and a favorable release profile both in water (72.42% for FR2, 77.23% for FE2) and in saliva (49.74% for FR2, 49.70% for FE2). Moreover, the optimized films are characterized by hydrophilicity (contact angle < 90°) and the pH value of the extract after their blurring is close to physiological, which promotes better tolerance and reduces the risk of irritation. Obtained results for polymeric films with resveratrol and R. japonica extract confirmed their great potential for use in dentistry as modern, mucoadhesive dressings, improving the effectiveness of local therapies.

Biopolymer blends (GGs) derived from renewable plant or animal‐based raw materials, hold significant potential for competing in the packaging industry by offering environmentally biodegradable and bioresorbable alternatives. One of the main challenges lies in optimizing the mechanical properties to enhance stress transfer between active additives and the gelatin matrices reinforced with modified SiO₂ compounds. In this study, a 5 °C increase in the glass transition temperature and a fourfold improvement in tensile strength (reaching 12 MPa) were achieved by incorporating hydrophilic SiO₂ nanoclay. Ion distribution maps visualized the interactions between silicon derivatives and polypeptide domains within the gel matrix, revealing increased stability attributed to ions such as Si+, SiO+, SiH+, and SiHO+. The absence of heavy metals in the blends underscores their potential as environmentally friendly and sustainable packaging solutions, with promising applications in sectors such as medical packaging.

The study explores innovative crosslinking processes for biopolymer gel materials using amino acids and ion-redox initiators to significantly enhance their structural and functional properties. Advanced analytical techniques, including FTIR, Raman spectroscopy, XRD, TEM, TGA, DSC, ToF-SIMS, SEM/EDS, GPC/SEC, and elemental analysis, were employed for comprehensive material characterization. The synthesized materials show potential applications in packaging and medicine, particularly for single-use products with short life cycles. Two crosslinking strategies were developed. The first combines gelatin with polyvinyl alcohol (PVA); keratin hydrolysate; and amino acids such as cysteine, hydroxyproline, proline, and histidine. The second employs endogenous cysteine, activated by ion-redox initiators, leveraging its trans-sulfuration ability to form highly stable polymer networks with optimized mechanical and thermal properties. Notably, the synergy between cysteine and potassium persulfate redox initiators proved particularly effective, making this approach attractive for industrial applications. This study introduces novel crosslinking methods and highlights the potential of amino acid-based strategies for designing advanced biopolymer gels with enhanced properties.

Non-degradable plastics of petrochemical origin are a contemporary problem of society. Due to the large amount of plastic waste, there are problems with their disposal or storage, where the most common types of plastic waste are disposable tableware, bags, packaging, bottles, and containers, and not all of them can be recycled. Due to growing ecological awareness, interest in the topics of biodegradable materials suitable for disposable items has begun to reduce the consumption of non-degradable plastics. An example of such materials are biodegradable biopolymers and their derivatives, which can be used to create the so-called bioplastics and biopolymer blends. In this article, gelatine blends modified with polysaccharides (e.g., agarose or carrageenan) were created and tested in order to obtain a stable biopolymer coating. Various techniques were used to characterize the resulting bioplastics, including Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA)/differential scanning calorimetry (DSC), contact angle measurements, and surface energy characterization. The influence of thermal and microbiological degradation on the properties of the blends was also investigated. From the analysis, it can be observed that the addition of agarose increased the hardness of the mixture by 27% compared to the control sample without the addition of polysaccharides. In addition, there was an increase in the surface energy (24%), softening point (15%), and glass transition temperature (14%) compared to the control sample. The addition of starch to the gelatine matrix increased the softening point by 15% and the glass transition temperature by 6%. After aging, both compounds showed an increase in hardness of 26% and a decrease in tensile strength of 60%. This offers an opportunity as application materials in the form of biopolymer coatings, dietary supplements, skin care products, short-term and single-contact decorative elements, food, medical, floriculture, and decorative industries.

Plastic waste is a serious problem in modern society. Every day, mankind produces tons of waste that must be disposed of or recycled. The most common types of plastic waste are disposable tableware, bags, packaging, bottles, and containers, and not all are recycled. Therefore, there is a great interest in producing environmentally friendly disposable materials. In this study, modified gelatin blends using polysaccharides (e.g., agarose, starch) were produced to obtain a stable coating. Various techniques were used to characterize the obtained bioplastics, including FTIR spectroscopy (Fourier-transform infrared spectroscopy), TGA (thermogravimetric analysis)/DSC (differential scanning calorimetry), contact angle measurements, and surface energy characterization. We also investigated the influence of thermal and microbiological degradation on the properties of the biocomposite. The addition of agarose increased the hardness of the blend by 27% compared to the control sample without added polysaccharides. Increases were also observed in the surface energy (24%), softening point (15%), and glass transition temperature (14%) compared to the control sample. The addition of starch to the biopolymer increased the softening point by 15% and the glass transition temperature by 6%. After aging, both blends showed an increase in hardness of 26% and a decrease in tensile strength of 60%.

Due to the growing demand for sustainable hygiene products (that will exhibit biodegradability and compostability properties), the challenge of developing a superabsorbent polymer that absorbs significant amounts of liquid has been raised so that it can be used in the hygiene sector in the future. The work covers the study of the swelling and dehydration kinetics of hydrogels formed by grafting polymerization of carboxymethyl starch (CMS) and chitosan (Ch). Vanillin (Van) was used as the crosslinking agent. The swelling and dehydration kinetics of the polymers were measured in various solutes including deionized water buffers with pH from 1 to 12 and in aqueous solutions of sodium chloride at 298 and 311 K. The surface morphology and texture properties of the analyzed hydrogels were observed by scanning electron microscopy (SEM). The influence of this structure on swelling and dehydration is discussed. Fourier transform infrared (FTIR) analyses confirmed the interaction between the carboxymethyl starch carbonyl groups and the chitosan amino groups in the resulting hydrogels. Additionally, spectroscopic analyses confirmed the formation of acetal crosslink bridges including vanillin molecules. The chemical dynamics studies revealed that new hydrogel dehydration kinetics strongly depend on the vanillin content. The main significance of the study concerns the positive results of the survey for the new superabsorbent polymer material, coupling high fluid absorbance with biodegradability. The studies on biodegradability indicated that resulting materials show good environmental degradability characteristics and can be considered true biodegradable superabsorbent polymers.