Bin Zhang

Underground coal gasification (UCG) is a controlled combustion process of in situ coal that produces combustible gases through thermal and chemical reactions. In order to investigate the UCG induced multi-physical field evolution and overlying strata fracture propagation of deep steeply inclined coal seam (SICS), which play a vital role in safety and sustainable UCG project, this study established a finite element model based on the actual geological conditions of SICS and the controlled retracting injection point (CRIP) technology. The results are listed as follows: (1) the temperature field influence ranges of the shallow and deep parts of SICS expanded from 15.56 m to 17.78 m and from 26.67 m to 28.89 m, respectively, when the burnout cavity length increased from 100 m to 400 m along the dip direction; (2) the floor mudstone exhibited uplift displacement as a result of thermal expansion, while the roof and overlying strata showed stepwise-increasing subsidence displacement over time, which was caused by stress concentration and fracture propagation, reaching a maximum subsidence of 3.29 m when gasification ended; (3) overlying strata rock damages occurred with induced fractures developing and propagating during UCG. These overlying strata fractures can reach a maximum height of 204.44 m that may result in groundwater influx and gasification failure; (4) considering the significant asymmetry in the evolution of multi-physical fields of SICS, it is suggested that the dip-direction length of a single UCG channel be limited to 200 m. The conclusions of this study can provide theoretical guidance and technical support for the design of UCG of SICS.

The Lower-Middle Jurassic Xishanyao Formation in the Nileke Sag of the Yili Basin contains substantial reserves of coal and coalbed methane (CBM). Elucidating its depositional evolution and the controlling factors of coal accumulation within a sequence-stratigraphic framework is crucial for guiding future exploration. This study integrates regional geological surveys, core observations, well-log analysis, and quantitative lithofacies statistics of the lower member to establish a sequence-stratigraphic framework and reconstruct the sedimentary paleogeography. Eleven minable coal seams are identified, exhibiting a depositionally controlled spatial thickness distribution. The coal is classified as low-rank bituminous (Rank I–II), characterized by high inertinite, low ash, medium-high volatile matter, and ultra-low sulfur content, indicating formation in a freshwater swamp influenced by seasonal droughts and floods. Three third-order sequences (SQ1–SQ3) are recognized. SQ2, deposited during peak transgression as a braided-river delta plain, provided the optimal environment for peat accumulation. In contrast, SQ3 is dominated by progradational deltas with coarser sediments, where coal accumulation weakened. The results demonstrate that coal accumulation was jointly controlled by tectonic subsidence (providing accommodation space), climate (causing peat oxidation and fine-clastic input), and sedimentation (with interdistributary bays on the delta plain being the most favorable sites). Coal accumulation in the Lower Xishanyao Member resulted from the coupling of tectonic, climatic, and sedimentary processes. This genetic model provides a theoretical basis for regional coal and CBM exploration.

To evaluate lignite degradation efficiency and the enhancement of biogas production by different microbial treatments, lignite was pre-treated with Streptomyces viridosporus (actinomycete), Phanerochaete chrysosporium (fungus), and Pseudomonas sp. (bacterium), followed by biogasification experiments. Among the three, Phanerochaete chrysosporium exhibited the highest lignite degradation rate. All microbial treatments improved both cumulative biogas yield and methane conversion, with Phanerochaete chrysosporium again demonstrating the most significant enhancement. Ultimate analysis after degradation showed the following consistent trends across all treatments: increases in carbon, hydrogen, and nitrogen contents, and reductions in sulfur and oxygen contents. A linear correlation was observed between the H/C atomic ratio and total biogas yield. Functional group analysis revealed the greatest reductions in key functional groups with Phanerochaete chrysosporium, followed by moderate changes with Pseudomonas and Streptomyces viridosporus. Pore structure characterization indicated that all microorganisms influenced lignite porosity, particularly in mesopore and micropore regions. Increases in pore volume and connectivity were associated with improved biogas production efficiency.

The influence of clay mineral content on biogenic gas production in coal seams remains insufficiently understood. This study systematically investigated the mechanisms by which clay minerals affect biogas production in low- and medium-rank coals by integrating simulated biogas production experiments with multidimensional analytical techniques, including infrared spectroscopy, X-ray diffraction, scanning electron microscopy, gas chromatography–mass spectrometry, fluorescence spectroscopy, and metagenomic analysis. The results demonstrated that in low-rank coal, increasing the clay content from 2.78 to 4.75 g per 20 g of coal reduced the biogas yield from 6.30 to 3.47 mL/g. Conversely, in medium-rank coal, increasing the clay content from 1.66 to 2.65 g per 20 g of coal enhanced the biogas yield from 3.45 to 5.28 mL/g. These contrasting outcomes are primarily attributed to the distinct mechanistic roles of clay minerals across coal ranks. In low-rank coal, the hydration-induced swelling of clay minerals intensified pore blockage, impeded gas diffusion, decreased the abundance of genes involved in propionate degradation, and suppressed microbial metabolic activity, ultimately limiting methane production. In contrast, in medium-rank coal, clay minerals facilitated the enrichment of key functional microbial taxa, such as Acetobacteroides and Methanoculleus, promoted the degradation of fatty acids, hydroxyls, and amines, and enhanced the activity of acidogenic and methanogenic pathways, thereby increasing methane yield. This study elucidates the microbial mechanisms underlying the regulatory role of clay minerals in biogas production, offering new theoretical insights into the origin of coalbed methane (CBM) and providing a scientific foundation for optimizing biogenic CBM recovery.

Microbial-Enhanced Coalbed Methane (MECBM) is a technology that generates new methane gas in coal seams through the action of microorganisms, thereby improving the efficiency of coalbed methane development. In this study, low-temperature CO₂ adsorption, low-temperature N₂ adsorption, and isothermal adsorption experiments were conducted to systematically characterize the changes in the pore characteristics of low-rank coals in Xinjiang before and after degradation. The results show that microbial action increases the average pore diameter and enhances pore connectivity. Meanwhile, it reduces the fractal dimension of the pore surface and simplifies the complexity of the pore structure. The modification of the pore structure effectively promotes the efficiency of methane desorption and migration, thus improving the exploitation potential of coalbed methane. Microbial degradation avoids the risk of deterioration of reservoir physical properties through biological modification, and reduces carbon emissions and environmental pollution. This study provides an environmentally friendly solution for the low-carbon development of coal resources, and has important scientific significance for promoting the transformation of energy structures and achieving the goal of carbon neutrality.

The pore fluid distribution in nanosized pores in shale cannot be observed directly with the current observation equipment which makes it difficult to study the fluid behavior in the shale pore system. To better understand pore fluid evolution and distribution in shale and its effect on pore structure with increasing maturity from immature to oil windows, a serial of samples with different maturity have been collected from the Lower Triassic lacustrine clay-rich Chang 7 shale in the Ordos Basin and treated with oven drying and sequential extraction to remove water, mobile oil, and asphaltene. We have measured the pore-size distributions in the presence of different pore fluids by using the mercury intrusion and N2 adsorption and desorption testing. The results indicate that (1) the pores in the clay-rich samples are mostly slit-shaped mineral pores, consist of a small number of macropores (pore size >50 nm) and a large number of mesopores (pore sizes between 7 and 36 nm), and also including a small amount of poorly developed organic matter-hosted pores. (2) Different types of pore fluids appear to occupy different pore-size ranges. Water prefers to occupy the mineral mesopores. Mobile oil (extracted by n-hexane) is mostly distributed in 2–10 nm-sized organic-matter-hosted mesopores. Asphaltenes are mostly distributed in mesopores in the range of 25–36 nm. (3) The presence of pore fluid significantly impacts the pore structures of shale. The pore volume and specific surface area decrease due to pore fluid occupation, even for low-maturity samples in which the organic matter pores also are developed but cannot be observed under a scanning electron microscope. (4) Organic matter abundance and thermal maturity have significant effects on the pore fluid composition and distribution. With increasing maturity, water is gradually displaced by oil due to hydrocarbon generation and accumulation in large mineral pores.

The Cambrian system in the Ordos Basin has a similar development degree of carbonate strata to that in the Sichuan and the Tarim Basins; however, no significant oil and gas breakthroughs similar to those in the latter two basins have been made in the Ordos Basin yet, and the characteristics, genesis, and differences in the reservoir need to be explored. Field outcrop observations reveal that the oil and gas shows are common in the Upper Cambrian Sanshanzi Formation in the eastern Ordos Basin, indicating important oil and gas exploration potential. Analysis of the characteristics and genesis of dolomite reservoirs can greatly support the exploration and development of the Cambrian carbonate oil reservoirs in the Ordos Basin. Based on the field outcrop observations and comprehensive laboratory tests and analyses, the reservoir characteristics and main control factors are systematically discussed. This study reveals that the reservoir lithology mainly comprises crystalline dolomite, from fine crystalline dolomite to coarse crystalline dolomite; this results in reservoirs with low porosity, extreme-low porosity, and ultralow permeability dominated by intergranular denudation, caves, and microfractures. They can be further divided into two types of reservoirs: type I reservoirs that have low porosity, ultralow permeability, and medium pore-throat radii, and type II reservoirs that have extreme-low porosity, ultralow permeability, and small pore-throat radii. The physical properties of fine-medium crystalline and medium crystalline dolomite reservoirs are slightly better, and the throats tend to be larger with increasing grain size. The reservoirs have not experienced deep burial processes; dolomitization mainly occurs in the marine-sourced fluid environment with weak oxidation and weak reduction, influenced by the atmospheric fresh water and thermal fluid transformation during the late period to some extent, whereas the hydrocarbons mainly charged during the late period. The crystalline dolomite in residual grains superimposes the denudation and cataclasis in the epigenetic karst stage that are the main controlling factors of the reservoirs. The crystalline cataclasis of dolomite can aid in the formation and reconstruction of the reservoirs. The spatial and temporal distribution laws of the reservoirs and key formation periods need to be studied further.

We systematically analyze the geochemical characteristics of source rocks of the Yan Chang Formation in the Ordos Basin to reveal the influence mechanisms of the volcano on lacustrine organic matter enrichment. Organic matter enrichment is not synchronous with the volcanic eruption in time, but it has a “hysteresis” effect. The evidence of volcanic activity mainly includes two aspects: one is a large amount of volcanic ash in black shale, and the other is a negative shift of organic carbon isotopes of source rocks and finding that black shale was affected by climate events caused by the volcano. The climate event caused by the volcano has three effects on organic matter enrichment in black shale: (1) it brought nutrients for the growth of organisms and released a large amount of greenhouse gases, such as CO2, to accelerate photosynthesis and promote the growth of organisms; (2) a large amount of toxic gases, such as SO2 and H2S, were released and O2 was consumed and diluted in the air, forming a severe anoxic environment and accelerating the preservation of organic matter; and (3) it caused extremely hot weather, resulting in long-time surface runoff and other climate events, increasing input of terrestrial organic matter, and forming light components of hydrocarbons.