Iván Vargas-Cordero

Along the Chilean continental margin, where the active Nazca plate subducts under the South American plate, large deposits of gas hydrates trapped in marine sediments can be observed in seismic profiles (from Valparaíso to Patagonia), which may be affected by the increase in deep-water temperature due to climate change. This could trigger a massive release of methane gas into the marine environment and the atmosphere with negative effects on the environment, mainly through dissociation of the hydrates and/or direct migration to the seafloor through faults.In this study, new multichannel seismic data located off Chiloé Island (∼42°S) are presented, and for the first time a BSR parallel to the continental margin (north-south) is analysed. Here, an efficient sediment subduction occurs where the young oceanic Nazca plate (5-25 Ma) subducts beneath the continental plate along Chiloé Island. In addition, an integrated analysis to better understand the hydrological and hydrothermal system in this area included previous geophysical and geological datasets, such as a) bathymetry, b) geothermal gradient calculated from gas hydrate distribution boundaries, and c) thermal conductivities. The results show a continuous and strong BSR along the entire seismic profile MGL1701-27 (approximately 27 km long), where large deformations, fractures and faults occur, favouring the flow of carbon-rich fluids from the depths, which subsequently form the gas hydrate layer. The large amount of gas hydrate present in the marine sediments off the coast of Chiloé Island is impressive. Velocity analysis of seismic profile MGL1701-27 indicates gas hydrate concentration values of up to 25% of the total rock volume, the highest estimates obtained at the Chilean margin. In addition, a peak in the geothermal gradient is related to deep faults that allow the passage of hot fluids from deeper strata to the seafloor. Finally, a large amount of free gas is estimated beneath the BSR, which enhances its intensity and continuity in the seismic profile.Our results provide valuable information for current and future studies related to climate change (methane storage), hydrothermal circulation, seismicity, gas hydrate stability and fluid venting in this natural laboratory, since Chiloé Island is located at the southern boundary of the rupture zone of the largest earthquake in recorded history (the Mw 9.5 Valdivia earthquake), the implications of which have yet to be fully elucidated.

The Chile Triple Junction, where the hot active spreading centre of the Chile Rise system subducts beneath the South American plate, offers a unique opportunity to understand the influence of the anomalous thermal regime on an otherwise cold continental margin. Integrated analysis of various geophysical and geological datasets, such as bathymetry, heat flow measured directly by thermal probes and calculated from gas hydrate distribution limits, thermal conductivities, and piston cores, have improved the knowledge about the hydrogeological system. In addition, rock dredging has evidenced the volcanism associated with ridge subduction. Here, we argue that the localized high heat flow over the toe of the accretionary prism results from fluid advection promoted by pressure-driven discharge (i.e., dewatering/discharge caused by horizontal compression of accreted sediments) as reported previously. However, by computing the new heat flow values with legacy data in the study area, we raise the assumption that these anomalous heat flow values are also promoted by the eastern flank of the currently subducting Chile Rise. Part of the rift axis is located just below the toe of the wedge, where active deformation and vigorous fluid advection are most intense, enhanced by the proximity of the young volcanic chain. Our results provide valuable information to current and future studies related to hydrothermal circulation, seismicity, volcanism, gas hydrate stability, and fluid venting in this natural laboratory.

Natural gas hydrate is an important energy source. Therefore, it is extremely important to provide a clear imaging profile to determine its distribution for energy exploration. In view of the problems existing in conventional migration methods, e.g., the limited imaging angles, we proposed to utilize an amplitude-preserved one-way wave equation migration based on matrix decomposition to deal with primary and multiple waves. With respect to seismic data gathered at the Chilean continental margin, a conventional processing flow to obtain seismic records with a high signal-to-noise ratio is introduced. Then, the imaging results of the conventional and amplitude-preserved one-way wave equation migration methods based on primary waves are compared, to demonstrate the necessity of implementing amplitude-preserving migration. Moreover, a simple two-layer model is imaged by using primary and multiple waves, which proves the superiority of multiple waves in imaging compared with primary waves and lays the foundation for further application. For the real data, the imaging sections of primary and multiple waves are compared. We found that multiple waves are able to provide a wider imaging illumination while primary waves fail to illuminate, especially for the imaging of bottom simulating reflections (BSRs), because multiple waves have a longer travelling path and carry more information. By imaging the actual seismic data, we can make a conclusion that the imaging result generated by multiple waves can be viewed as a supplementary for the imaging result of primary waves, and it has some guiding values for further hydrate and in general shallow gas exploration.

In recent decades, the Chilean margin has been extensively investigated to better characterize the complex geological setting through the geophysical data. The analysis of seismic lines allowed us to identify the occurrence of gas hydrates and free gas in many places along the margin and the change of the pore fluid due to the potential hydrate dissociation. The porosity reduction due to the hydrate presence is linked to the slope to identify the area more sensitive in case of natural phenomena or induced by human activities that could determine gas hydrate dissociations and/or leakage of the free gas trapped below the gas-hydrate stability zone. Clearly, the gas hydrate reservoir could be a strategic energy reserve for Chile. The steady-state modelling pointed out that the climate change could determine gas hydrate dissociation, triggering slope failure. This hypothesis is supported by the presence of high concentrations of gas hydrate in correspondence of important seafloor slope. The dissociation of gas hydrate could change the petrophysical characteristics of the subsoil triggering slopes, which already occurred in the past. Consequently, it is required to improve knowledge about the behavior of the gas hydrate system in a function of complex natural phenomena before the exploitation of this important resource.

Gas-hydrate occurrences along the Chilean margin have been widely documented, but the processes associated with fluid escapes caused by the dissociation of gas hydrates are still unknown. We report a seabed morphology growth related to fluid migration offshore Lebu associated with mud cones by analysing oxygen and deuterium stable water isotopes in pore water, bathymetric, biological and sedimentological data. A relief was observed at − 127 m water depth with five peaks. Enrichment values of δ¹⁸O (0.0–1.8‰) and δD (0.0–5.6‰) evidenced past hydrate melting. The orientation of the relief could be associated with faults and fractures, which constitute pathways for fluid migration. The benthic foraminifera observed can be associated with cold seep areas. We model that the mud cones correspond to mud growing processes related to past gas-hydrate dissociation. The integration of (i) the seismic data analysis performed in the surrounding area, (ii) the orientation of our studied relief, (iii) the infaunal foraminifera observed, (iv) the grain size and (v) the total organic matter and isotope values revealed that this area was formerly characterised by the presence of gas hydrates. Hence, this part of the Chilean margin represents a suitable area for investigating fluid-migration processes.

This Special Issue reports research spanning from the analysis of indirect data, modelling, laboratory and geological data confirming the intrinsic multidisciplinarity of the gas hydrate studies. The study areas are (1) Arctic, (2) Brazil, (3) Chile and (4) the Mediterranean region. The results furnished an important tessera of the knowledge about the relationship of a gas hydrate system with other complex natural phenomena such as climate change, slope stability and earthquakes, and human activities.

In the last few years, interest in the offshore Chilean margin has increased rapidly due to the presence of gas hydrates. We have modelled the gas hydrate stability zone off Chilean shores (from 33° S to 46° S) using a steady state approach to evaluate the effects of climate change on gas hydrate stability. Present day conditions were modelled using published literature and compared with available measurements. Then, we simulated the effects of climate change on gas hydrate stability in 50 and 100 years on the basis of Intergovernmental Panel on Climate Change and National Aeronautics and Space Administration forecasts. An increase in temperature might cause the dissociation of gas hydrate that could strongly affect gas hydrate stability. Moreover, we found that the high seismicity of this area could have a strong effect on gas hydrate stability. Clearly, the Chilean margin should be considered as a natural laboratory for understanding the relationship between gas hydrate systems and complex natural phenomena, such as climate change, slope stability and earthquakes.

Large amounts of gas hydrate are present in marine sediments offshore Taitao Peninsula, near the Chile Triple Junction. Here, marine sediments on the forearc contain carbon that is converted to methane in a regime of very high heat flow and intense rock deformation above the downgoing oceanic spreading ridge separating the Nazca and Antarctic plates. This regime enables vigorous fluid migration. Here, we present an analysis of the spatial distribution, concentration, estimate of gas-phases (gas hydrate and free gas) and geothermal gradients in the accretionary prism, and forearc sediments offshore Taitao (45.5°–47° S). Velocity analysis of Seismic Profile RC2901-751 indicates gas hydrate concentration values −1). Gas hydrates are located in shallow sediments (90–280 m below the seafloor). The large amount of hydrate and free gas estimated (7.21 × 10¹¹ m³ and 4.1 × 10¹⁰ m³; respectively), the high seismicity, the mechanically unstable nature of the sediments, and the anomalous conditions of the geothermal gradient set the stage for potentially massive releases of methane to the ocean, mainly through hydrate dissociation and/or migration directly to the seabed through faults. We conclude that the Chile Triple Junction is an important methane seepage area and should be the focus of novel geological, oceanographic, and ecological research.

Recent studies have reported cold seeps offshore of Mocha Island. Gas hydrate occurrences along the Chilean margin could explain seeps presence. Gas-phase (gas hydrate and free gas) and geothermal gradients were estimated analysing two seismic sections. Close to Mocha Island (up to 20 km) were detected high (up to 1900 m/s) and low (1260 m/s) velocities associated with high gas hydrate (up to 20% of total volume) and free gas (up to 1.1% of total volume) concentrations, respectively. A variable and high geothermal gradient (65–110 °C/km) was obtained. These results are related to high supply of deep fluids canalised by faults and fractures. Faraway from Mocha Island (>60 km), free gas concentrations decrease to 0.3% of total volume and low geothermal gradient (from 35 to 60 °C/km) are associated with low fluids supply. Finally, we propose gas hydrate dissociation processes as the main supply source for seeps in the vicinity of Mocha Island. These processes can be caused by: (a) active faults and seismic activity; and (b) warm fluid expulsion from deeper zones altering hydrate stability conditions. In both cases, gas hydrate dissociation could generate slope instability and landslides, as occurred in the past in this region and reported in the literature.