Chang-Kyu Lee

Ammonia (NH₃) emissions from swine manure pits contribute significantly to odor nuisance, health risks, and secondary PM_2.5 formation. This study assessed the pilot-scale performance of three source-control technologies: surface sealing with surfactant-based foam system (FOAM SYSTEM), swine manure wiping and removing system (WIPING SYSTEM), and belt-conveyor-based solid–liquid separator system (BELT SYSTEM). Each technology targets a different pathway in the ammonia generation process. The FOAM SYSTEM suppresses volatilization by forming a foam barrier at the air–liquid interface. The WIPING SYSTEM reduces precursor contact time by periodically removing feces. The BELT SYSTEM separates feces and urine upon excretion, inhibiting enzymatic ammonia formation. Among the individual systems, the BELT SYSTEM achieved the highest ammonia reduction efficiency of 91.7%, followed by the FOAM SYSTEM (73.6%) and WIPING SYSTEM (64.4%). The combined FOAM SYSTEM + BELT SYSTEM yielded the best performance with an ammonia reduction efficiency of 94.4%, showing modest synergy without operational interference. In contrast, the FOAM SYSTEM + WIPING SYSTEM configuration achieved 71.1%, slightly lower than the FOAM SYSTEM alone, likely due to foam disruption. Environmental sensitivity tests revealed that higher temperatures and alkaline pH elevated NH₃ emissions, whereas systems that maintained near-neutral pH, like the FOAM SYSTEM, demonstrated greater stability. These findings highlight the importance of integrating physical and source-control mechanisms while considering environmental variability for effective on-farm ammonia mitigation.

Several methods, such as pretreatment, membrane surface modification, feed water chlorination, and chemical cleaning, have recently been applied to control biofouling on reverse osmosis (RO) membranes—with limited success. As an alternative, compounds that inhibit bacterial quorum sensing can be used to disrupt formation of bacterial colonies. In this study, anti-biofouling using vanillin, which is a natural substance among quorum sensing inhibitor compounds, was trialed, by modifying RO membrane surfaces with vanillin, at various concentrations. We then reviewed consequential changes to membrane surface characteristics and vanillin anti-biofouling properties. A long-term RO membrane simulator was used to analyze permeability, contact angle was measured for hydrophilicity evaluation, and membrane surface morphology was analyzed, through atomic force microscopy and scanning electron microscopy. A quorum quenching effect was confirmed by utilizing Petrifilm to count bacteria on the surface of a modified membrane. As a result, the permeability of the surface modified membranes was slightly decreased compared to the pristine membrane, but the hydrophilicity was increased, and the number of colonies decreased remarkably, the membrane modified with 0.5 M vanillin outperforming that modified with 0.25 M vanillin.