Ulrich Ulmer

Water electrolysis is a key technology for sustainable hydrogen production and a cornerstone of future low-carbon energy systems. However, large-scale deployment is constrained not only by efficiency and cost, but increasingly by the sustainability and availability of materials used in electrocatalysts and membranes. This review provides a materials-centric assessment of state-of-the-art and emerging electrocatalysts for alkaline (AEL), proton exchange membrane (PEM), and solid oxide electrolysis (SOEC) technologies, emphasizing the interdependence of performance, durability, cost, and sustainability. Electrocatalyst activity and stability are linked to cell- and stack-level efficiency, energy demand, and the levelized cost of hydrogen. Life cycle assessment (LCA) and resource criticality analyses are integrated to quantify environmental impacts, supply risks, and recycling potential of key materials, including platinum group metals, nickel, rare earth elements, and ceramic oxides. Particular attention is given to recycling and circularity strategies, which are essential for mitigating material scarcity and reducing upstream emissions, especially in PEM electrolyzers. Emerging catalyst concepts such as single-atom catalysts, high-entropy alloys, and noble-metal-free systems are discussed as promising pathways to reduce critical material dependence. The review concludes by highlighting the need for integrated material–technology–system approaches to enable efficient, scalable, and truly sustainable hydrogen production.

The transition to hydrogen is an important element of the sustainable transition of Germany’s industry. Regional German municipal utilities play a key role in this transition, as they are at the core position between local demand and regional supply. They play an important role when it comes to planned infrastructure development on the regional level. As energy infrastructure development is a long-term project, they need to deal with the hydrogen transition at a very early stage, including pilot projects, organizational changes, and business model adaptations. Yet, not much is known about how these entities organize the transition to hydrogen. Using a qualitative research approach, this study takes a dynamic-capability perspective to shed light on the hydrogen transition activities of German municipal utilities. Industry and other energy sector participants can learn from these insights on how to organize the transition path towards hydrogen. Findings indicate that strong partnerships play a key role in identifying new opportunities and that balancing risk and benefit is a key challenge when it comes to realizing new technological hydrogen projects.

Hydrogen storage technologies are key enablers for the development of low-emission, sustainable energy supply chains, primarily due to the versatility of hydrogen as a clean energy carrier. Hydrogen can be utilized in both stationary and mobile power applications, and as a low-environmental-impact energy source for various industrial sectors, provided it is produced from renewable resources. However, efficient hydrogen storage remains a significant technical challenge. Conventional storage methods, such as compressed and liquefied hydrogen, suffer from energy losses and limited gravimetric and volumetric energy densities, highlighting the need for innovative storage solutions. One promising approach is hydrogen storage in metal hydrides, which offers advantages such as high storage capacities and flexibility in the temperature and pressure conditions required for hydrogen uptake and release, depending on the chosen material. However, these systems necessitate the careful management of the heat generated and absorbed during hydrogen absorption and desorption processes. Thermal energy storage (TES) systems provide a means to enhance the energy efficiency and cost-effectiveness of metal hydride-based storage by effectively coupling thermal management with hydrogen storage processes. This review introduces metal hydride materials for hydrogen storage, focusing on their thermophysical, thermodynamic, and kinetic properties. Additionally, it explores TES materials, including sensible, latent, and thermochemical energy storage options, with emphasis on those that operate at temperatures compatible with widely studied hydride systems. A detailed analysis of notable metal hydride–TES coupled systems from the literature is provided. Finally, the review assesses potential future developments in the field, offering guidance for researchers and engineers in advancing innovative and efficient hydrogen energy systems.

Catalytic reduction of carbon dioxide is a promising strategy for mitigating global carbon emissions. In particular, the abundant and nontoxic material hydroxyapatite demonstrates high activity at a low cost when its constituent cations are replaced with transition metals, which also enables its catalytic properties to be tailored. Using this method, the facile and scalable synthesis of a copper-substituted hydroxyapatite catalyst is presented, demonstrating its high activity in the reverse water gas shift reaction. Thorough in situ characterization using X-ray absorption and Fourier transform infrared spectroscopic methods provides unrivaled insight into both the structure of the active catalyst and the speciation of reaction intermediates. It is thus shown that this copper-substituted hydroxyapatite catalyst is an exemplary candidate for use in large-scale carbon dioxide reduction systems.

Heterogenous thermal catalytic processes are vital for industrial production of fuels, fertilizers and other chemicals necessary for sustaining human life. However, these processes are highly energy-intensive, requiring a vast consumption of fossil fuels. An emerging class of heterogeneous catalysts that are thermally driven but also exhibit a photochemically enhanced rate can potentially reduce process energy intensity by partially substituting conventional heat (where fossil fuels are needed) with solar energy. Such catalyst systems have yet to be practically utilized. Here, we demonstrate a compact electrically heated photo- and thermal annular reactor module to reduce CO2 to CO, via the reverse water gas shift reaction. A first principles-based design approach was taken in developing a SiO2 on Al photo- thermal catalyst system for the model photo- and thermal indium oxide hydroxide (In2O3-x(OH)y) catalyst. A five-fold light enhancement in the CO production rate and over 70 hours of stable CO production was achieved. This represents the highest light enhancement effect reported for this model photocatalyst to date. The reactor presented herein allows continuous operation and a significant reduction of 31% in heater power consumption when provided with an additional 2 suns of irradiation, demonstrating the strong photo- and thermal harvesting performance of the catalyst system developed in this work.

Nanowire hydrogen bronzes of WO₃ nanowires decorated with Pd (Pd/H_yWO_3–x) were previously demonstrated to effectively capture broadband radiation across the ultraviolet to near-infrared wavelength range and catalyze the reverse water gas shift reaction (RWGS). Herein, we report a synthetic strategy to enhance the performance of this class of photocatalysts by conformally coating Cu atoms onto the surface of Pd/H_yWO_3–x by anchoring Cu(I)O^tBu to the Brønsted acidic protons of the bronze. The resulting materials are characterized by a suite of analytical methods, including electron microscopy and X-ray absorption spectroscopy. In addition, in situ diffuse reflectance infrared Fourier transform spectroscopy demonstrated that for the light-driven RWGS reaction, as little as 0.2 at. % Cu facilitates the formation of surface carboxylate species from CO₂, resulting in a 300–500% enhancement in the rate of CO production. This metal anchoring method enables atom precise modification of the surfaces of metal oxide nanomaterials for catalytic applications, circumventing the need for complex and expensive atomic layer deposition processes.

The extraction and combustion of fossil natural gas, consisting primarily of methane, generates vast amounts of greenhouse gases that contribute to climate change. However, as a result of recent research efforts, “solar methane” can now be produced through the photocatalytic conversion of carbon dioxide and water to methane and oxygen. This approach could play an integral role in realizing a sustainable energy economy by closing the carbon cycle and enabling the efficient storage and transportation of intermittent solar energy within the chemical bonds of methane molecules. In this article, we explore the latest research and development activities involving the light-assisted conversion of carbon dioxide to methane.

The design of photocatalysts able to reduce CO₂ to value-added chemicals and fuels could enable a closed carbon circular economy. A common theme running through the design of photocatalysts for CO₂ reduction is the utilization of semiconductor materials with high-energy conduction bands able to generate highly reducing electrons. Far less explored in this respect are low-energy conduction band materials such as WO₃. Specifically, we focus attention on the use of Pd nanocrystal decorated WO₃ nanowires as a heretofore-unexplored photocatalyst for the hydrogenation of CO₂. Powder X-ray diffraction, thermogravimetric analysis, ultraviolet–visible-near infrared, and in situ X-ray photoelectron spectroscopy analytical techniques elucidate the hydrogen tungsten bronze, H_yWO_3–x, as the catalytically active species formed via the H₂ spillover effect by Pd. The existence in H_yWO_3–x of Brønsted acid hydroxyls OH, W(V) sites, and oxygen vacancies (V_O) facilitate CO₂ capture and reduction reactions. Under solar irradiation, CO₂ reduction attains CO production rates as high as 3.0 mmol g_cat^–1 hr^–1 with a selectivity exceeding 99%. A combination of reaction kinetic studies and in situ diffuse reflectance infrared Fourier transform spectroscopy measurements provide a valuable insight into thermochemical compared to photochemical surface reaction pathways, considered responsible for the hydrogenation of CO₂ by Pd@H_yWO_3–x.

Two approaches of engineering surface structures of V-Ti-based solid solution hydrogen storage alloys are presented, which enable improved tolerance towards gaseous oxygen (O2) impurities in hydrogen (H2) gas. Surface modification is achieved through engineering lanthanum (La)- or nickel (Ni)-rich surface layers with enhanced cyclic stability in a H2/O2 mixture. The formation of a Ni-rich surface layer does not improve the cycling stability in H2/O2 mixtures. Mischmetal (Mm, a mixture of La and Ce) agglomerates are observed within the bulk and surface of the alloy when small amounts of this material are added during arc melting synthesis. These agglomerates provide hydrogen-transparent diffusion pathways into the bulk of the V-Ti-Cr-Fe hydrogen storage alloy when the remaining oxidized surface is already intransparent for hydrogen. Thus, the cycling stability of the alloy is improved in an O2-containing hydrogen environment as compared to the same alloy without addition of Mm. The obtained surface-engineered storage material still absorbs hydrogen after 20 cycles in a hydrogen-oxygen mixture, while the original material is already deactivated after 4 cycles.