Gege He

Fucoidan is used to make a PAM-Fuc hydrogel electrolyte. Its sulfate anchors and hydroxyl-rich backbone enable multidentate adsorption on Zn, displacing interfacial water and creating a locally water-deficient Zn anode interface.

Transition metal and nitrogen codoped graphitic carbon materials with Co-N bonds serve as key non-noble-metal catalysts for the oxygen evolution reaction (OER). To enhance catalytic efficiency, we explore the anchoring of Co-N bonds on nitrogen-doped graphitic carbon (NC) substrates with varied phosphorus content. The catalyst is synthesized through a straightforward sintering and phosphating process of ZIF@DCA in a tube furnace. X-ray photoelectron spectroscopy (XPS) demonstrated that the Co-N bonds effectively formed an efficient charge transfer channel, removing the barrier that separated the Co-N active site from the work electrode surface. Phosphorus is uniformly distributed across the Co-N substrate, ensuring the exposure of most Co-N active sites during the electrochemical reaction. With favorable structural and electronic attributes, P/Co-N-2 showcases the lowest overpotentials at 10 and 300 mA cm^-2, which are 200 and 300 mV, respectively. Additionally, it demonstrates stable performance over 100 h in 1 M KOH, outperforming other similar materials and RuO₂. This study offers critical insights for the rational design of Co-N structures, exploring the interplay between structure, composition, and activity in electrochemical reactions.

To enhance the electrocatalytic performance of a flexible Pd@CFs catalyst for methanol oxidation, deep cryogenic treatment in liquid nitrogen was introduced. The effects of the frequency and time of the deep cryogenic treatment on the surface crystal orientation, microstructure morphology, mechanical performance, and electrocatalytic performance for methanol oxidation were studied. The results showed that when the frequency of the deep cryogenic treatment was 2 times and the deep cryogenic time was 24 h, the electrocatalytic performance of the catalyst was the best. Compared with the catalyst without deep cryogenic treatment, the activity and stability of the catalyst increased by about 33% and 41%, respectively. The activity and stability of the catalyst were about 43.4 times and 6.3 times that of the commercial Pd/C catalyst, respectively. After 500 cycles of CV testing, the performance of the catalyst decay rate was only 3.9%. Compared to the CFs, the tensile strength and the elongation rates of the catalyst increased by 24.6% and 57%, respectively. This is due to deep cryogenic treatment causing Pd grains to rotate from a disordered arrangement to an ordered arrangement, making the metal particles more dispersed and exposing more active sites, ultimately improving the electrocatalytic oxidation ability of methanol. The excellent electrocatalytic efficiency of Pd@CFs-24-2 coupled with its simple and easy preparation method has great potential for promoting the development of DMFCs.

A PdO/CeO2 composite with a rod-like nanoporous skeletal structure was prepared by combining the dealloying of Al-Ce-Pd alloy ribbons with calcination. For CO oxidation and CH4 combustion, the nanoporous PdO/CeO2 composite exhibits excellent catalytic activity, and the complete reaction temperatures of CO and CH4 are 80 °C and 380 °C, respectively. In addition, the composite possesses excellent cycle stability, CO2 toxicity, and water resistance, and the catalytic activity hardly decreases after 100 h of long-term stability testing in the presence of water vapour (2 × 105 ppm). The results of a series of characterizations indicate that the enhanced catalytic activity can be attributed to the good dispersion of the PdO nanoparticles, large specific surface area, strong redox capacity, interaction between PdO and CeO2, and more surface active oxygen on PdO. The results of the characterization and experiments also indicate that the PdO nanoparticles, prepared by combining dealloying and calcination, have a stronger catalytic activity than do Pd nanoparticles. Finally, a simple model is used to summarize the catalytic mechanism of the PdO/CeO2 composite. It is hoped that this work will provide insights into the development of high-activity catalysts.

Ni(OH)2 electrocatalysts have acquired lots of research attentions as ideal substitutes for noble metals. However, their electrocatalytic performance still cannot meet the demands for applications due to the difficulties in electron transfer and mass transport. According to kinetics principle, the construction of hollow structure is regarded as an effective method to achieve outstanding electrocatalytic performance. In this work, Ni(OH)2 hollow porous architecture (Ni(OH)2 HPA) was simply synthesized through a coordinating etching and precipitating (CEP) method for the building of enzymatic-free glucose sensors. Ni(OH)2 HPA presents large specific surface area (SSA), ordered diffusion channels, and structure stability. As a detection electrode for glucose, Ni(OH)2 HPA exhibits eminent electroactivity in terms of high sensitivity (1843 μA mM−1 cm−2), lower detection limit (0.23 μM), and short response time (1.4 s). The results demonstrate that Ni(OH)2 HPA has practical applications for construction of enzymatic-free electrochemical sensors. The design of hollow structure also provides an effective engineering method for high-performance sensors.