Aneta Sapińska-Śliwa

The article presents an analysis of the thermal conductivity coefficient determined using three methods. One is based on data taken from the literature, while the other is based on the results obtained from field thermal response tests. Third one is something between this two. The analysis covers the results obtained for five different boreholes of varying depths, in which seals with increased conductivity and different trade names were used. In one location, gravel with a grain size of 8 mm to 16 mm was used as a seal. Each of the boreholes has a different location, which is also related to different geological structures.

The research paper provides an introduction to the deep borehole heat exchanger, its use and completed projects worldwide. The aim of the study is to design a deep borehole heat exchanger at the AGH Student Town campus, more specifically its design, casing and internal heat exchanger pipe concept with a view to minimizing temperature losses. It goes on to describe the location of the project including the geology of the area and the solution to the design problem, i.e. the casing of the borehole and the design concepts for the deep borehole heat exchanger. In the following section, the design of a deep borehole heat exchanger is presented. During the research, the main problem was the low availability of articles on deep borehole heat exchangers. This is due to the continuous development and testing of new engineering ideas and the high implementation costs compared to the energy effects obtained. The publication deals only with technical issues, financial issues were not considered, among other things due to the current global geopolitical situation in 2023.

Demulgatory przyspieszają separację wody od ropy naftowej podczas jej wydobycia. Te bardziej powszechne często zawierają substancje niebezpieczne (rozpuszczalniki aromatyczne, czy słabo biodegradowalne składniki aktywne), które mogą działać negatywnie na zdrowie ludzi (szczególnie układ oddechowy) oraz na środowisko. Artykuł ocenia możliwość zastosowania środków nietoksycznych, o wysokim stopniu biodegradacji, przyjaznych środowisku, podczas badań przeprowadzanych dla ropy naftowej pochodzącej z kopalni znajdujących się w Basenie Paryskim. Powszechne, komercyjne demulgatory były testowane wraz z czterema nietoksycznymi i biodegradowalnymi. Badanie polegało na przeprowadzeniu testu butelkowego demulgatora oraz testu badającego zawartość wody w wirówce. Analizowane były cztery próbki ropy naftowej wraz z piątą próbką, będącą mieszaniną tychże czterech, mieszaną w stosunku znanym z procesu produkcyjnego dla danej instalacji. Miejscem pracy były cztery kopalnie ropy naftowej w Basenie Paryskim, we Francji. Na podstawie badania udowodniono, iż dla wszystkich czterech próbek nowy, wysoce biodegradowalny, rozpuszczalny w ropie demulgator, zawierający pochodne poliiminowe wraz z polimerami EO/PO (o RSN = 10) w rozpuszczalniku nietoksycznym, skutecznie może być użyty w celu poprawienia separacji podczas eksploatacji ropy. Nie tylko zapewnił najlepsze właściwości separacji dla wszystkich analizowanych próbek, ale również najniższą zawartość wody w ropie po separacji spośród wszystkich analizowanych produktów. Rozwiązanie to ma potencjał w wyeliminowaniu wielu problemów związanych z logistyką produktu, składowaniem oraz aspektami środowiskowymi. Jest również bardziej bezpieczne pod kątem pracy z produktem. Wnioski te w zupełności spełniają aktualny trend dotyczący użycia jak najbardziej ekologicznych rozwiązań w każdej możliwej pracy przemysłowej.

The authors studied the problem of naphthenate deposits in the oil and gas industry. Currently, there are few ways available to inhibit or dissolve naphthenate deposits in oil facilities. Naphthenate deposits can block pipelines and aggregate in other parts of the installation, i.e., in the separators. In Europe, the issue of deposition on oil rigs is commonly encountered in Norway and the United Kingdom, as well as in some African countries, i.e., Angola and Nigeria. Many tons of chemicals are used to combat naphthenate deposition, usually through inhibition, but also via the dissolution of the scale that precipitates over time. The presented work examines the characteristics of naphthenate fouling, historical ways to inhibit it, and current approaches to the problem, as well as the results of the laboratory testing of naphthenate inhibitors and solvents. The process of the naphthenate creation is as follows. When oil exhibits a high TAN (total acid number) and high content of salty water, naphthenate deposits can emerge via the reaction of naphthenic acids and metal salts (mostly calcium ones). Naphthenates are partially insoluble in water, and they usually float below the oil/water interface. The standard methods of naphthenate inhibition involve lowering the pH of the production water, which can result in serious problems, especially related to corrosion. This study addresses experiments conducted in the laboratory in Poland and on oil rigs in Angola and is based on contemporary knowledge and standards. The objective of this paper was to investigate the most suitable naphthenate inhibitors and solvents, as well as to undertake bottle tests of naphthenate inhibitors with a focus on the main indicators (water clarity, quality of separation surface, and clarity of oil). The use of citric and formic acids in this paper is a novelty, and it is compared with the results obtained with the more commonly used acetic acid, hydrochloric acid, and ABS acid. It was proven that formic acid can effectively inhibit and dissolve naphthenic deposits (99% efficiency of inhibition and 100% efficiency of dissolution). It was found that some acids used in naphthenate inhibition create more deposits than were originally present. Formic acid and ABS acid yielded significantly better results than other types. It is also here hypothesized that there are substances other than acids that can effectively remove naphthenate deposits, and the other novelty of this study is in the use of mutual solvents in the removal of naphthenate salts. Another important outcome is the finding that not only acids but also mutual solvents (EGMBE and isopropyl alcohol) can effectively remove naphthenate deposits. The test results show that formic acid dissolved all of the naphthenates, while citric acid had 97% efficacy, isopropyl alcohol had 95% efficacy, and EGMBE showed 94% efficacy. The impacts of commercial naphthenate inhibitors on the bottle test results and interfacial tension measurements were also investigated. It was shown that commercial naphthenate inhibitors can decrease the interfacial tension between oil and water by more than 30% when used at dosages of 400 ppm.

Research on the utilization of the Earth’s heat focuses mainly on effective sourcing of energy accumulated in rock mass. One of the most important parameters is thermal conductivity, which can be modified using various compositions of cement grouts. Hardened cement slurry is intended to improve thermal conductivity. It should function as a sort of extension of the rock mass to the outer diameter of heat exchanger tubes. Regardless of the thermal conductivity of the rock, high conductivity of the grout increases the energy efficiency of the BHE. Heat accumulated in the rock mass can be extracted using borehole heat exchangers (BHE), in which high thermal conductivity of cement slurry is wanted over the entire length of the exchanger. Generally, in case of deep borehole heat exchangers (DBHE), it is recommended to use two types of cement slurry, one with reduced thermal conductivity in the upper part of the exchanger and grout with increased thermal conductivity in its lower part. When cementing geothermal wells, cement grout with decreased thermal conductivity along the entire length of the borehole is most commonly used. Geothermal boreholes extract geothermal water which, at the surface, is used for heating, for example. Then, after use, the cooled water is injected through injection holes. In this article, two different basalt dusts are examined. These dusts were obtained by crushing basalt boulders in open-pit mines. They were examined for their effect on thermal conductivity when added to grout. According to the Polish Ordinance of the Minister of Environment dated 9 December 2014 regarding the waste catalogue, they were classified as waste. The materials, named basalt dust A and basalt dust B, were used to create cement slurries with a water–cement ratio of 0.5–0.7 with a wide range of percentage concentration of basalt dust. The test results show that as concentrations in the slurry increase, the values of thermal conductivity and strength decrease. This correlation occurred for both tested additives.

The reduction of CO₂ emissions has become a global concern. In this regard, the EU intends to cut CO₂ emissions by 55% by 2030 compared to those of 1990. The utilization of shallow geothermal energy (SGE) in EU countries is considered the most effective measure for decarbonizing heating and cooling. SGE systems utilize heat energy collected from the earth’s crust to provide secure, clean, and ubiquitous energy. This paper provides a literature review on the use of SGE for heating and cooling purposes. The latest advances in materials, new innovative structures, and techno-economic optimization approaches have been discussed in detail. Shallow geothermal energy’s potential is first introduced, and the innovative borehole structures to improve performance and reduce installation cost is outlined. This is followed by an extensive survey of different types of conventional and thermally enhanced collectors and grouts. Attention is mainly given to the techno-economic analysis and optimization approaches. In published case studies, the least economic break-even point against fossil fuel-based heating systems occurs within 2.5 to 17 years, depending on the local geological conditions, installation efficiency, energy prices, and subsidy. Ground source heat pumps’ cost-effectiveness could be improved through market maturity, increased efficiency, cheap electricity, and good subsidy programs.

Investigating the constructions of borehole heat exchangers with high efficiency (unit heat transfer between the heat carrier and ground) is important. One of the means to improve efficiency is the use of the most efficient construction of the borehole heat exchanger. The paper describes research on borehole heat exchangers’ thermal efficiency, which is mainly characterized by parameters obtained from a thermal response test: effective thermal conductivity and borehole thermal resistivity. The borehole heat exchangers of the Laboratory of Geoenergetics in Poland were studied. Based on thermal response test interpretation and empirical equations, one of which is proprietary, the heat transfer is calculated independent of the duration of the thermal response test. Other conditions for using borehole heat exchangers in downtowns are discussed. The research aims to determine the best borehole heat exchanger design from five basic possibilities studied. A lack of unequivocal statements regarding this matter in the literature was observed. The influence of the interpretation method on the research results is determined. A single U-tube system filled with gravel is shown to be the most advantageous design by a very small margin. The applied interpretation methods, however, confirm the hitherto ambiguity in the selection of the best construction. The maximum heat carrier temperature at the end of thermal response tests was 32 °C for a geological profile mostly made up of clay (low thermal conductivity) and 23 °C for Carpathian flysch (sandstones and shales, with a higher value of conductivity).

Currently, renewable energy is increasingly important in the energy sector. One of the so-called renewable energy sources is geothermal energy. The most popular solution implemented by both small and large customers is the consumption of low-temperature geothermal energy using borehole heat exchanger (BHE) systems assisted by geothermal heat pumps. Such an installation can operate regardless of geological conditions, which makes it extremely universal. Borehole heat exchangers are the most important elements of this system, as their design determines the efficiency of the entire heating or heating-and-cooling system. Filling/sealing slurry is amongst the crucial structural elements. In borehole exchangers, reaching the highest possible thermal conductivity of the cement slurry endeavors to improve heat transfer between the rock mass and the heat carrier. The article presents a proposed design for such a sealing slurry. Powdered magnesium was used as an additive to the cement. The approximate cost of powdered magnesium is PLN 70–90 per kg (EUR 15–20/kg). Six different slurry formulations were tested. Magnesium flakes were used in designs A, B, C, and magnesium shavings in D, E and F. The samples differed in the powdered magnesium content BWOC (by weight of cement). The parameters of fresh and hardened sealing slurries were tested, focusing mainly on the thermal conductivity parameter. The highest thermal conductivity values were obtained in design C with the 45% addition of magnesium flakes BWOC.

Geothermal energy can be useful after extraction from geothermal wells, borehole heat exchangers and/or natural sources. Types of geothermal boreholes are geothermal wells (for geothermal water production and injection) and borehole heat exchangers (for heat exchange with the ground without mass transfer). The purpose of geothermal production wells is to harvest the geothermal water present in the aquifer. They often involve a pumping chamber. Geothermal injection wells are used for injecting back the produced geothermal water into the aquifer, having harvested the energy contained within. The paper presents the parameters of geothermal boreholes in Poland (geothermal wells and borehole heat exchangers). The definitions of geothermal boreholes, geothermal wells and borehole heat exchangers were ordered. The dates of construction, depth, purposes, spatial orientation, materials used in the construction of geothermal boreholes for casing pipes, method of water production and type of closure for the boreholes are presented. Additionally, production boreholes are presented along with their efficiency and the temperature of produced water measured at the head. Borehole heat exchangers of different designs are presented in the paper. Only 19 boreholes were created at the Laboratory of Geoenergetics at the Faculty of Drilling, Oil and Gas, AGH University of Science and Technology in Krakow; however, it is a globally unique collection of borehole heat exchangers, each of which has a different design for identical geological conditions: heat exchanger pipe configuration, seal/filling and shank spacing are variable. Using these boreholes, the operating parameters for different designs are tested. The laboratory system is also used to provide heat and cold for two university buildings. Two coefficients, which separately characterize geothermal boreholes (wells and borehole heat exchangers) are described in the paper.

The rotary-percussion drilling method is a prospective way to decrease drilling costs. It is obvious, based on literature analyses and finished geothermal drilling, that the Lublin Basin can be perceived as the one where rotary-percussion drilling can be used to drill an overburden of shale rocks. The paper explained the geology of the Lublin Basin, its’ geological structures, and the possibility of the use of drilling with a down-the-hole hammer, which could significantly decrease the cost of the whole shale gas drilling investment. Data collected from the wells drilled in the Lublin Basin were compared and analyzed to determine the viability of rotary-percussion drilling. Provided analyses showed that using the rotary-percussion drilling method in the Lublin Basin had a greater possibility of application than in other Polish shale basins (Baltic and Podlasie).